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PVT Property Measurements for Ethyl Propionate, Ethyl Butyrate, and Ethyl Pentanoate Esters from (298 to 393) K and up to 35 MPa

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    PVT Property Measurements for Ethyl Propionate, Ethyl Butyrate, and Ethyl Pentanoate Esters from (298 to 393) K and up to 35 MPa†
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    Departamento de Engenharia Química, Universidade de Coimbra, Pólo II, Rua Sílvio Lima, 3030-790 Coimbra, Portugal
    * To whom correspondence should be addressed. E-mail: [email protected]. Phone: +351-239798729. Fax: +351-239798703.
    †Part of the special issue “Robin H. Stokes Festschrift”.
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2009, 54, 2, 256–262
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    https://doi.org/10.1021/je800251v
    Published July 9, 2008
    Copyright © 2008 American Chemical Society
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    Abstract

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    The results of PVT measurements of the liquid phase within the temperature range (298 to 393) K and up to 35 MPa are presented for some aliphatic esters. Measurements were made by means of a vibrating tube densimeter, model DMA 512P from Anton Parr. The calibration of the densimeter was performed with water and n-heptane as reference fluids. The experimental PVT data have been correlated by a Tait equation. This equation gives good results when used to predict the density of the esters using the method proposed by Thomson et al. Isothermal compressibilities, isobaric expansivities, thermal pressure coefficients, and changes in the isobaric heat capacity have been calculated from the Tait equation.

    Copyright © 2008 American Chemical Society

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    An additional four tables. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cited By

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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2009, 54, 2, 256–262
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je800251v
    Published July 9, 2008
    Copyright © 2008 American Chemical Society
    Request reuse permissions

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