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Vapor−Liquid Phase Boundaries of Binary Mixtures of Carbon Dioxide with Ethanol and Acetone

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Department of Chemical Engineering, National Taiwan University of Science and Technology, 43 Keelung Road, Section 4, Taipei 106-07, Taiwan
* Corresponding author. E-mail: [email protected]. Tel.: +886-2-2737-6626. Fax: +886-2-2737-6644.
Cite this: J. Chem. Eng. Data 2008, 53, 10, 2393–2402
Publication Date (Web):August 27, 2008
https://doi.org/10.1021/je800371a
Copyright © 2008 American Chemical Society

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    Abstract

    A visual and volume-variable high-pressure phase equilibrium analyzer (PEA) was used for measuring the isothermal vapor−liquid equilibrium (VLE) phase boundaries of CO2 + ethanol and CO2 + acetone at temperatures from (291.15 to 313.15) K over a wide composition range. The isothermal phase equilibrium properties obtained from this work were compared with literature values to clarify the inconsistency of the VLE data taken from different sources. The new VLE data were correlated with the Soave−Redlich−Kwong, the Peng−Robinson, and the Patel−Teja equations of state incorporating with the one-parameter and the two-parameter van der Waals one-fluid mixing rules, respectively.

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