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Solubilities of Amide Compounds in Supercritical Carbon Dioxide

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Key Laboratory of Analytical Chemistry of the State Ethnic Affairs Commission, College of Chemistry and Materials Science, South-Central University for Nationalities, Wuhan, 430074, P. R. China, and Beijing Key Laboratory of Printing & Packaging Material and Technology, Beijing Institute of Graphic Communication, Beijing 102600, P. R. China
* Corresponding author. Email: [email protected]
†South-Central University for Nationalities.
‡Beijing Institute of Graphic Communication.
Cite this: J. Chem. Eng. Data 2008, 53, 9, 2189–2192
Publication Date (Web):August 21, 2008
https://doi.org/10.1021/je800434j
Copyright © 2008 American Chemical Society
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    Abstract

    2,2′-Oxybis(N,N-diethylacetamide), 2,2′-oxybis(N,N-dibutylacetamide), and 2,2′-oxybis(N,N-dihexylacetamide) were synthesized, and their structures were confirmed by IR, NMR, and elemental analysis. The solubilities of compounds were measured at temperatures ranging from (313 to 333) K and pressures from (8.7 to 16.4) MPa in supercritical carbon dioxide. The measured solubilities were correlated using a semiempirical model. The calculated results showed satisfactory agreement with the experimental data and differed from the measured values by between (4.54 and 30.84) %.

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