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Adsorption Thermodynamics of Silica Gel−Water Systems

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Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Chem. Eng. Data 2009, 54, 2, 448-452
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    Adsorption Thermodynamics of Silica Gel−Water Systems†
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    Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, 6-1 Kasuga-koen, Kasuga-shi, Fukuoka 816-8580, Japan
    Department of Mechanical Engineering, National University of Singapore, 10 Kent Ridge Crescent, Singapore 119260, Singapore
    Frigrite Refrigeration Pty Ltd., 27 Grange Road, Cheltenham, Victoria 3192, Australia
    * Corresponding author. Tel.: 81-92-583-7832. Fax: 81-92-583-7833. E-mail: [email protected]
    †Part of the special issue “Robin H. Stokes Festschrift”.
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    Journal of Chemical & Engineering Data

    Cite this: J. Chem. Eng. Data 2009, 54, 2, 448–452
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    https://doi.org/10.1021/je800458k
    Published December 4, 2008
    Copyright © 2008 American Chemical Society
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    Abstract

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    The thermodynamic property surfaces of silica gel + water systems have been developed and described from the rigor of chemical equilibria between adsorbed and gaseous phases, Maxwell relations, the entropy of the adsorbed phase, and experimentally measured adsorption isotherm data. These property fields compute the entropy, enthalpy, specific heat capacity, and isosteric heat of adsorption as a function of pressure, temperature, and the amount of adsorbate thoroughly, which are essential for calculating the energetic performances of adsorption cooling and desalination processes. In this paper, the properties of enthalpy and entropy data for the silica gel + water system at temperatures from (273 to 373) K and at different equilibrium pressures between (0.5 and 10) kPa are furnished. The specific heat capacity and the isosteric heat of adsorption obtained by the proposed property fields are also compared with experimental data.

    Copyright © 2008 American Chemical Society

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    This article is cited by 52 publications.

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    Cite this: J. Chem. Eng. Data 2009, 54, 2, 448–452
    Click to copy citationCitation copied!
    https://doi.org/10.1021/je800458k
    Published December 4, 2008
    Copyright © 2008 American Chemical Society
    Request reuse permissions

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