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Solubility of Benzoic Acid in Aqueous Solutions Containing Ethanol or N-Propanol

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School of Chemical Engineering, Federal University of Uberlândia, Av. João Naves de Ávila, 2121 - 38 408 100 Uberlândia, Brasil
* Corresponding author. E-mail: [email protected]. Tel.: (55) 34 3239 42 92. Fax: 55 34 3239 4188.
Cite this: J. Chem. Eng. Data 2008, 53, 11, 2704–2706
Publication Date (Web):October 8, 2008
https://doi.org/10.1021/je800507m
Copyright © 2008 American Chemical Society

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    Abstract

    The solubility of benzoic acid in water−ethanol and water−n-propanol mixtures at temperatures between (303.5 and 333.7) K has been measured by using an apparatus in our laboratory. Experiments were carried out employing different concentrations of alcohol. Addition of alcohol in water results in a large increase in acid solubility. Owing to a lack of available literature data, no results comparison could be done for systems containing n-propanol. Furthermore, the predicted results of solubility for the systems studied over a range of temperatures indicated that both modified equations tested can fairly be used to predict solid−liquid equilibrium for alcoholic aqueous solutions at several temperatures.

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