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Low Pressure Solubilities of Vinyl Chloride in Ionic Liquids

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School of Chemical & Environmental Engineering, China University of Mining & Technology, (Beijing), 100083, China, and Department of Chemistry, Renmin University of China, Beijing 100872, China
* Corresponding author. E-mail: [email protected]. Tel: 0086-10-62513162.
†China University of Mining & Technology.
‡Renmin University of China.
Cite this: J. Chem. Eng. Data 2008, 53, 12, 2807–2809
Publication Date (Web):October 31, 2008
https://doi.org/10.1021/je8005166
Copyright © 2008 American Chemical Society

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    Abstract

    The mole fraction solubility of vinyl chloride in 1-butyl-3-methyl imidazolium tetrafluoroborate ([BMIM][BF4]), 1-butyl-3-methyl imidazolium hexafluorophosphate ([BMIM][PF6]), 2,4-bis(2-hydroxypropyl)-1,1,3,3-tetramethyl guanidinium tetrafluoroborate ([TMGHPO2][BF4]), and tetramethyl guanidinelactate (TMGL) is reported as a function of temperature at (293.15, 313.15, and 333.15) K at pressures of up to 2 bar on the basis of a saturation method. The Henry’s law constants and enthalpy of solution of vinyl chloride were calculated from the solubility data. The enthalpy of solution is negative for all mixtures.

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