ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img

Isobaric Vapor−Liquid Equilibria for the Binary Systems Benzene + Methyl Ethanoate, Benzene + Butyl Ethanoate, and Benzene + Methyl Heptanoate at 101.31 kPa

View Author Information
Laboratorio de Fisicoquímica, Departamento de Química, Facultad de Ingeniería, Universidad Nacional del Comahue, Buenos Aires 1400-8300 Neuquén, Argentina
* Corresponding author. E-mail: [email protected]
†Part of the “Gerhard M. Schneider Festschrift”.
‡CONICET member.
Cite this: J. Chem. Eng. Data 2009, 54, 5, 1575–1579
Publication Date (Web):April 22, 2009
https://doi.org/10.1021/je800915d
Copyright © 2009 American Chemical Society

    Article Views

    519

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options
    Supporting Info (1)»

    Abstract

    Isobaric vapor−liquid equilibria for the binary systems benzene + methyl ethanoate, benzene + butyl ethanoate, and benzene + methyl heptanoate, at the pressure of (101.31 ± 0.02) kPa, have been determined using an all-glass recirculation still. From experimental data, the activity coefficients were calculated and satisfactorily correlated as a function of the mole fraction using the excess Gibbs energy model equations proposed by Margules, van Laar, Wilson, NRTL, and UNIQUAC. The predictive group-contribution models UNIFAC and ASOG were applied. The thermodynamic consistency of the data was verified with two point-to-point tests. The binary systems showed positive deviations from Raoult’s law, and no azeotrope was observed at this pressure.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    Experimental densities for the binary mixtures benzene + methyl ethanoate, benzene + butyl ethanoate, and benzene + methyl heptanoate, used to calculate VLE compositions. Figures with experimental and predicted γi values for the binary systems investigated. This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 15 publications.

    1. Simon Boothroyd, Owen C. Madin, David L. Mobley, Lee-Ping Wang, John D. Chodera, Michael R. Shirts. Improving Force Field Accuracy by Training against Condensed-Phase Mixture Properties. Journal of Chemical Theory and Computation 2022, 18 (6) , 3577-3592. https://doi.org/10.1021/acs.jctc.1c01268
    2. Niklas Haarmann, Sabine Enders, Gabriele Sadowski. Heterosegmental Modeling of Long-Chain Molecules and Related Mixtures using PC-SAFT: 1. Polar Compounds. Industrial & Engineering Chemistry Research 2019, 58 (7) , 2551-2574. https://doi.org/10.1021/acs.iecr.8b03799
    3. Nathan S. Evangelista, Frederico R. do Carmo, Hosiberto B. de Sant’Ana. Estimation of Physical Constants of Biodiesel-Related Fatty Acid Alkyl Esters: Normal Boiling Point, Critical Temperature, Critical Pressure, and Acentric Factor. Industrial & Engineering Chemistry Research 2018, 57 (25) , 8552-8565. https://doi.org/10.1021/acs.iecr.8b01310
    4. Nathan S. Evangelista, Frederico R. do Carmo, and Hosiberto B. de Sant’Ana . Estimation of Vapor Pressures and Enthalpies of Vaporization of Biodiesel-Related Fatty Acid Alkyl Esters. Part 1. Evaluation of Group Contribution and Corresponding States Methods. Industrial & Engineering Chemistry Research 2017, 56 (8) , 2298-2309. https://doi.org/10.1021/acs.iecr.6b04772
    5. Sultan S.A. Al Habsi, Saif ZS. Al Ghafri, Rami Bamagain, J.P. Martin Trusler. Experimental and modelling study of the phase behavior of (methyl propanoate + carbon dioxide) at temperatures between (298.15 and 423.15) K and pressures up to 20 MPa. Fluid Phase Equilibria 2020, 519 , 112653. https://doi.org/10.1016/j.fluid.2020.112653
    6. Guanjia Zhao, Zemin Yuan, Jianguo Yin, Suxia Ma. Thermophysical properties of fatty acid methyl and ethyl esters. The Journal of Chemical Thermodynamics 2019, 134 , 195-212. https://doi.org/10.1016/j.jct.2019.02.025
    7. Dzmitry H. Zaitsau, Andrey A. Pimerzin, Sergey P. Verevkin. Fatty acids methyl esters: Complementary measurements and comprehensive analysis of vaporization thermodynamics. The Journal of Chemical Thermodynamics 2019, 132 , 322-340. https://doi.org/10.1016/j.jct.2019.01.007
    8. Xiaopo Wang, Kai Kang, Shanshan Zhu, Bo Gao. High-pressure liquid densities of fatty acid methyl esters: Measurement and prediction with PC-SAFT equation of state. Fluid Phase Equilibria 2018, 471 , 8-16. https://doi.org/10.1016/j.fluid.2018.04.024
    9. Irene del Pozo, Marcela Cartes, Fèlix Llovell, Andrés Mejía. Densities and interfacial tensions for fatty acid methyl esters (from methyl formate to methyl heptanoate) + water demixed mixtures at atmospheric pressure conditions. The Journal of Chemical Thermodynamics 2018, 121 , 121-128. https://doi.org/10.1016/j.jct.2018.02.010
    10. Benjamin Flamme, Gonzalo Rodriguez Garcia, Marcel Weil, Mansour Haddad, Phannarath Phansavath, Virginie Ratovelomanana-Vidal, Alexandre Chagnes. Guidelines to design organic electrolytes for lithium-ion batteries: environmental impact, physicochemical and electrochemical properties. Green Chemistry 2017, 19 (8) , 1828-1849. https://doi.org/10.1039/C7GC00252A
    11. William Acree, James S. Chickos. Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2015. Part 1. C 1 − C 10. Journal of Physical and Chemical Reference Data 2016, 45 (3) , 033101. https://doi.org/10.1063/1.4948363
    12. Alejandra Mariano, Lelia Mussari, Mirtha Orozco, Salvador Canzonieri, Miguel Postigo. Volumetric and transport properties of the ternary mixtures of toluene (1) + benzene (2) + butyl acetate (3) at different temperatures. Physics and Chemistry of Liquids 2015, 53 (5) , 587-598. https://doi.org/10.1080/00319104.2014.937862
    13. Eugene D. Nikitin, Alexander P. Popov. Vapour–liquid critical properties of components of biodiesel. 1. Methyl esters of n -alkanoic acids. Fuel 2015, 153 , 634-639. https://doi.org/10.1016/j.fuel.2015.03.060
    14. Eeva-Maija Turpeinen, Erlin Sapei, Petri Uusi-Kyyny, Kari I. Keskinen, Outi A.I. Krause. Finding a suitable thermodynamic model and phase equilibria for hydrodeoxygenation reactions of methyl heptanoate. Fuel 2011, 90 (11) , 3315-3322. https://doi.org/10.1016/j.fuel.2011.06.050
    15. P. Susial, R. Rios-Santana, A. Sosa-Rosario. Vapor-liquid equilibrium measurements for the binary system methyl acetate+ethanol at 0.3 and 0.7 MPa. Brazilian Journal of Chemical Engineering 2011, 28 (2) , 325-332. https://doi.org/10.1590/S0104-66322011000200017

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect