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Vapor−Liquid Equilibria in Binary Systems Formed by Cyclohexane with Alcohols

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Radom Technical University, Department of Material Science, Technology and Design, Chrobrego 27, 26-600 Radom, Poland
* To whom correspondence should be addressed. E-mail: [email protected]. Phone: +48 22 343 3307.
Cite this: J. Chem. Eng. Data 2009, 54, 11, 2996–3001
Publication Date (Web):June 22, 2009
https://doi.org/10.1021/je900050z
Copyright © 2009 American Chemical Society

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    Abstract

    The modified Świȩtosławski ebulliometer was used for the accurate determination of vapor−liquid equilibria in binary isothermal systems formed by cyclohexane with: 2-butanol at 313.15 K, 323.15 K, 333.15 K, and 343.15 K, 2-pentanol at 333.15 K, 343.15 K, and 353.15 K, 2-methyl-2-butanol at 313.15 K, 323.15 K, 333.15 K, and 343.15 K, and 1-hexanol at 323.15 K, 333.15 K, 343.15 K, and 353.15 K. The vapor pressures of the pure substances are also given. The experimental data have been compared with literature data (if available) of those systems and correlated by means of the Redlich−Kister, NRTL, and Wilson equations.

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    Cited By

    This article is cited by 14 publications.

    1. Luciano Lepori, Enrico Matteoli, and Paolo Gianni . Vapor Pressure and Its Temperature Dependence of 28 Organic Compounds: Cyclic Amines, Cyclic Ethers, and Cyclic and Open Chain Secondary Alcohols. Journal of Chemical & Engineering Data 2017, 62 (1) , 194-203. https://doi.org/10.1021/acs.jced.6b00576
    2. Aouicha Belabbaci, Rosa M. Villamañán, Latifa Negadi, and M. Carmen Martín . Vapor–Liquid Equilibria of Binary Mixtures Containing 2-Butanol and Hydrocarbons at 313.15 K. Journal of Chemical & Engineering Data 2012, 57 (3) , 982-987. https://doi.org/10.1021/je201284y
    3. Jing-jing Li, Sheng-wei Tang, and Bin Liang. Vapor−Liquid Equilibrium for Binary Systems of Cyclohexane + Cyclohexanone and + Cyclohexanol at Temperatures from (414.0 to 433.7) K. Journal of Chemical & Engineering Data 2010, 55 (9) , 3418-3421. https://doi.org/10.1021/je100028s
    4. Paweł Gierycz, Andrzej Kosowski and Ryszard Swietlik. Vapor−Liquid Equilibria in Binary Systems Formed by n-Hexane with Alcohols. Journal of Chemical & Engineering Data 2010, 55 (2) , 937-940. https://doi.org/10.1021/je900530f
    5. Aouicha Belabbaci, Chahrazed Ghezouali, Rosa M. Villamañán, Alejandro Moreau, Latifa Negadi, Miguel A. Villamañán. P-x isothermal equilibrium data for two ternary systems containing long-chain bioalcohols: (1-butanol or 2-butanol + cyclohexane + methylbenzene) at 313.15 K. The Journal of Chemical Thermodynamics 2020, 141 , 105984. https://doi.org/10.1016/j.jct.2019.105984
    6. Mohammad Almasi. Study of molecular interactions and preferential solvation in binary mixtures of cyclohexane and (C5–C10) 1-alkanol by Kirkwood-Buff integrals. Fluid Phase Equilibria 2019, 489 , 1-7. https://doi.org/10.1016/j.fluid.2019.02.006
    7. Torben Egger, Georg Fieg. Enzymatic catalyzed reactive dividing wall column: Experiments and model validation. AIChE Journal 2017, 63 (6) , 2198-2211. https://doi.org/10.1002/aic.15598
    8. William Acree, James S. Chickos. Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2015. Part 1. C 1 − C 10. Journal of Physical and Chemical Reference Data 2016, 45 (3) , 033101. https://doi.org/10.1063/1.4948363
    9. Alejandro Moreau, José J. Segovia, Jorge Rubio, M. Carmen Martín. Thermodynamics properties, VLE and H E , of the systems 2-pentanol and cyclohexane or methylbenzene for contributing to the knowledge of new biofuels. Fluid Phase Equilibria 2016, 409 , 92-97. https://doi.org/10.1016/j.fluid.2015.09.035
    10. Vojtěch Štejfa, Michal Fulem, Květoslav Růžička, Pavel Matějka. Vapor pressures and thermophysical properties of selected hexenols and recommended vapor pressure for hexan-1-ol. Fluid Phase Equilibria 2015, 402 , 18-29. https://doi.org/10.1016/j.fluid.2015.05.026
    11. Yong Zhou, Jun Liu, Steven G. Penoncello, Eric W. Lemmon. An Equation of State for the Thermodynamic Properties of Cyclohexane. Journal of Physical and Chemical Reference Data 2014, 43 (4) https://doi.org/10.1063/1.4900538
    12. Miroslav Čenský, Vladislav Roháč, Květoslav Růžička, Michal Fulem, Karel Aim. Vapor pressure of selected aliphatic alcohols by ebulliometry. Part 1. Fluid Phase Equilibria 2010, 298 (2) , 192-198. https://doi.org/10.1016/j.fluid.2010.06.019
    13. Miroslav Čenský, Pavel Vrbka, Květoslav Růžička, Michal Fulem. Vapor pressure of selected aliphatic alcohols by ebulliometry. Part 2. Fluid Phase Equilibria 2010, 298 (2) , 199-205. https://doi.org/10.1016/j.fluid.2010.06.020
    14. M. Fattahi, H. Iloukhani. Excess molar volume, viscosity, and refractive index study for the ternary mixture {2-methyl-2-butanol (1)+tetrahydrofuran (2)+propylamine (3)} at different temperatures. Application of the ERAS-model and Peng–Robinson–Stryjek–Vera equation of state. The Journal of Chemical Thermodynamics 2010, 42 (11) , 1335-1345. https://doi.org/10.1016/j.jct.2010.05.009

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