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Densities and Viscosities of Rubidium Bromide in Dimethyl Sulfoxide + Water Mixtures in the Temperature Range t = (25 to 45) °C

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Department of Chemistry, University of Balochistan, Quetta, Pakistan, Department of Chemistry, Kohat University of Science and Technology, Kohat, Pakistan, and Department of Chemistry, University of Karachi, Karachi-75270, Pakistan
* Corresponding author. E-mail: [email protected]
†University of Balochistan.
‡Kohat University of Science and Technology.
§University of Karachi.
Cite this: J. Chem. Eng. Data 2010, 55, 2, 666–672
Publication Date (Web):January 20, 2010
https://doi.org/10.1021/je9001027
Copyright © 2010 American Chemical Society

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    Abstract

    The viscosities and densities of rubidium bromide were determined in dimethyl sulfoxide (DMSO) + H2O mixtures of different compositions as a function of concentration [(0.01 to 0.06) mol·L−1] and temperatures [(25 to 45) °C] to obtain the Jones−Dole B-coefficient. The positive values indicated that the salt behaved as a structure maker in DMSO, and in DMSO + H2O mixtures, the B-coefficient values were less positive, showing a weak structure-making effect. On the other hand in H2O, B-coefficient values of RbBr were negative, showing the structure-breaking ability.

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