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Isobaric Vapor−Liquid Equilibria at 101.32 kPa and Densities, Speeds of Sound, and Refractive Indices at 298.15 K for MTBE or DIPE or TAME + 1-Propanol Binary Systems

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Chemical Engineering Department, University of Santiago de Compostela, E-15782 Santiago de Compostela, Spain
* Corresponding author. Tel.: +34981563100 ext. 16790. Fax: +34981528050. E-mail: [email protected]
†Present address: Departamento de Física, Facultad de Ciencias Exactas y Tecnología, Universidad Nacional de Tucumán, Avenida Independencia 1800, 4000 San Miguel de Tucumán, Argentina.
Cite this: J. Chem. Eng. Data 2010, 55, 1, 92–97
Publication Date (Web):May 27, 2009
https://doi.org/10.1021/je900274n
Copyright © 2009 American Chemical Society

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    Abstract

    The isobaric vapor−liquid equilibria (VLE) at 101.32 kPa and densities, speeds of sound, and refractive indices at 298.15 K have been measured for binary liquid mixtures of 2-methoxy-2-methylpropane (MTBE) or 2-isopropoxypropane (DIPE) or 2-methoxy-2-methylbutane (TAME) and 1-propanol. The molar volumes, molar refractions, and isentropic compressibilities have been calculated from these experimental data. The excess molar volumes and the deviations in molar refraction and isentropic compressibility upon mixing have been satisfactorily correlated by the Redlich−Kister polynomial. The vapor−liquid equilibrium data have been found thermodynamically consistent and have been adequately correlated by means of Wilson, NRTL, and UNIQUAC equations. The ASOG and the original and modified UNIFAC group contribution methods have not afforded very adequate predictions of data involved in this study.

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