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Mixing Properties for Binary Liquid Mixtures of Methyl tert-Butyl Ether with Propylamine and Dipropylamine at Temperatures from (288.15 to 308.15) K

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Department of Chemistry, Kurukshetra University, Kurukshetra 136119, Haryana, India, Department of Chemistry, Dr. B. R. Ambedkar National Institute of Technology, Jalandhar 144011, Punjab, India, National Institute of Technology, Kurukshetra 136119, Haryana, India, and Department of Chemistry, M. M. University, Mullana, Ambala, Haryana, India
* Corresponding author. E-mail: [email protected] and [email protected]
†Kurukshetra University.
‡Dr. B. R. Ambedkar National Institute of Technology, Jalandhar.
§National Institute of Technology, Kurukshetra.
∥M. M. University.
Cite this: J. Chem. Eng. Data 2010, 55, 3, 1424–1429
Publication Date (Web):December 18, 2009
https://doi.org/10.1021/je900597n
Copyright © 2009 American Chemical Society

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    Abstract

    Densities and sound velocity have been measured over the whole composition range for the binary liquid mixtures of methyl tert-butyl ether with propylamine and dipropylamine using an Anton Paar DSA 5000 density and sound analyzer at temperatures of (288.15, 293.15, 298.15, 303.15, and 308.15) K and atmospheric pressure. From these densities and speeds of sound, excess molar volumes and excess isentropic compressibility were calculated. All of the properties were fitted to Redlich−Kister equation. The variation of these properties with composition and temperature of the mixture is discussed in terms of molecular interactions.

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