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Physical Properties of Binary Mixtures of Ethyl Formate with Benzene, Isopropyl Benzene, Isobutyl Benzene, and Butylbenzene at (303.15, 308.15, and 313.15) K

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Physical Chemistry Research Laboratory, B. N. Bandodkar College of Science, Thane-400 601, India, and Zulal Bilajirao Patil College, Deopur, Dhule-424002, India
* Corresponding author. E-mail: [email protected]
†B. N. Bandodkar College of Science.
‡Zulal Bilajirao Patil College.
Cite this: J. Chem. Eng. Data 2010, 55, 4, 1722–1726
Publication Date (Web):December 4, 2009
https://doi.org/10.1021/je900689m
Copyright © 2009 American Chemical Society
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    Abstract

    Densities, viscosities, and speeds of sound of binary mixtures of ethyl formate with benzene, isopropyl benzene, isobutyl benzene, and butylbenzene have been measured over the entire range of composition, at (303.15, 308.15, and 313.15) K and at atmospheric pressure. The excess volume, VE, deviation in viscosity, Δη, and deviation in isentropic compressibility, ΔKs, have been calculated from the experimental values of density, viscosity, and ultrasonic velocity. The excess volumes are positive, while the deviations in viscosities are negative for all of the studied binary systems over the whole composition range. The deviation in isentropic compressibility shows both positive and negative deviations for ethyl formate with benzene and isopropyl benzene, and for the remaining systems they are positive. The ability of some of the empirical models to calculate mixing viscosities was also tested.

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