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Solubility of Acetamide, Propionamide, and Butyramide in Water at Temperatures between (278.15 and 333.15) K

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Departamento de Química, Facultad de Ciencias, Universidad Nacional de Colombia, Bogotá, Colombia
* Corresponding author. E-mail: [email protected]. Tel.: (571)3165440. Fax: (571)3165220. Address: Departamento de Química, Facultad de Ciencias, Universidad Nacional de Colombia, Cra 30 # 45-03, Bogotá, Colombia.
†E-mail: [email protected]. Actual address: Departamento de Ciencias Naturales, Facultad de Ingeniería, Universidad Central, Cra 5 # 21-38, Bogotá, Colombia.
Cite this: J. Chem. Eng. Data 2010, 55, 6, 2326–2327
Publication Date (Web):December 3, 2009
https://doi.org/10.1021/je9007475
Copyright © 2009 American Chemical Society

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    Abstract

    The aqueous solubilities of acetamide, propionamide, and butyramide were measured from (278.15 to 333.15) K at intervals of 5.00 K using the gravimetric method. The temperature dependence of the solubility of acetamide, propionamide, and butyramide in water is described by the van’t Hoff equation. Linear van’t Hoff plots were found for amides in water, and the differential enthalpy of solution was calculated.

    Cited By

    This article is cited by 8 publications.

    1. Michael J. Schnieders, Jonas Baltrusaitis, Yue Shi, Gaurav Chattree, Lianqing Zheng, Wei Yang, and Pengyu Ren . The Structure, Thermodynamics, and Solubility of Organic Crystals from Simulation with a Polarizable Force Field. Journal of Chemical Theory and Computation 2012, 8 (5) , 1721-1736. https://doi.org/10.1021/ct300035u
    2. Gennadiy I. Egorov, Arkadiy M. Kolker. The (p-Vm-T-x) properties of {water (1) + acetamide (2)} mixtures in the range 278.15–323.15 K and 0.10–100 MPa. The Journal of Chemical Thermodynamics 2019, 138 , 240-254. https://doi.org/10.1016/j.jct.2019.06.028
    3. M.A. Krestyaninov, E.G. Odintsova, A.M. Kolker, M.G. Kiselev. The structure of water – Acetamide hydrogen bonded complexes. Quantum chemical analysis. Journal of Molecular Liquids 2018, 264 , 343-351. https://doi.org/10.1016/j.molliq.2018.05.070
    4. Andrés Felipe Torres, Carmen M. Romero. Influence of aliphatic amides on the temperature of maximum density of water. The Journal of Chemical Thermodynamics 2017, 105 , 173-178. https://doi.org/10.1016/j.jct.2016.10.024
    5. Francesco D'Amico, Barbara Rossi, Gaia Camisasca, Filippo Bencivenga, Alessandro Gessini, Emiliano Principi, Riccardo Cucini, Claudio Masciovecchio. Slow-to-fast transition of hydrogen bond dynamics in acetamide hydration shell formation. Physical Chemistry Chemical Physics 2015, 17 (16) , 10987-10992. https://doi.org/10.1039/C5CP00486A
    6. Luis H. Blanco, P. Andrea Escamilla, Carmen M. Romero. Transition points in the system 1,3,5,7-tetraazatricyclo[3.3.1.1 3,7 ] decane (HMT): water between 275.15 and 313.15 K. Physics and Chemistry of Liquids 2014, 52 (1) , 1-6. https://doi.org/10.1080/00319104.2013.782545
    7. Cassie A. Goodman, Christopher G. Hamaker, Shawn R. Hitchcock. Synthesis and evaluation of some variants of the Nefkens’ reagent. Tetrahedron Letters 2013, 54 (45) , 6012-6014. https://doi.org/10.1016/j.tetlet.2013.08.066
    8. Carmen M. Romero, Carlos D. Oviedo. Effect of Temperature on The Solubility of α-Amino Acids and α,ω-Amino Acids in Water. Journal of Solution Chemistry 2013, 42 (6) , 1355-1362. https://doi.org/10.1007/s10953-013-0031-9

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