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Molar Volumes and Refractive Indexes of Hexane-1,2,3,4,5,6-hexol in Aqueous Solutions of 1-Propanol and 2-Propanol

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College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, P. R. China
* Corresponding author. E-mail: [email protected]. Fax: +86-635-8239196.
Cite this: J. Chem. Eng. Data 2010, 55, 8, 2909–2913
Publication Date (Web):February 23, 2010
https://doi.org/10.1021/je900966r
Copyright © 2010 American Chemical Society

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    Abstract

    Apparent molar volumes (VΦ) of hexane-1,2,3,4,5,6-hexol in aqueous solutions of 1- and 2-propanols were obtained from densities of ternary solutions, accurately measured with a quartz vibrating-tube densimeter at several temperatures in the range from (293.15 to 313.15) K. Refractive indexes (nD) measurements were also made for hexane-1,2,3,4,5,6-hexol + propanol + water at T = 298.15 K. The data of VΦ have been used to deduce the limiting partial molar volumes of hexane-1,2,3,4,5,6-hexol (V0Φ) and limiting partial molar volumes of transfer (ΔtrsV0Φ) from water to different alcohol solutions at different concentrations. From the values of nD, molar refractive indexes (RD) were calculated. Then the changes of these parameters were discussed in the light of interaction between solute and solvent and the different locations of the hydroxyl group in propanol isomers.

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