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p−T−x Measurements for Some Working Fluids for an Absorption Heat Transformer: 1,1,1,2-Tetrafluoroethane (R134a) + Dimethylether Diethylene Glycol (DMEDEG) and Dimethylether Triethylene Glycol (DMETrEG)

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Laboratoire de l’Ingénierie des Procédés de l’Environnement (LIPE), Département de Chimie Industrielle, Université Mentouri Constantine, Route Ain El Bey, Constantine 25017, Algérie, and Mines ParisTech, CEP/TEP-Centre Energétique et Procédés, 35 Rue Saint Honoré, 77305 Fontainebleau, France
* Corresponding author. E-mail: [email protected]
†Université Mentouri Constantine.
‡Mines ParisTech, CEP/TEP-Centre Energétique et Procédés.
Cite this: J. Chem. Eng. Data 2010, 55, 8, 2769–2775
Publication Date (Web):February 12, 2010
https://doi.org/10.1021/je9009915
Copyright © 2010 American Chemical Society
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    Abstract

    The solubilities of 1,1,1,2-tetrafluoroethane (R134a), CF3CH2F, + dimethylether diethylene glycol (DMEDEG), CH3O(CH2CH2O)2CH3, and R134a + dimethylether triethylene glycol (DMETrEG) binary systems were measured, using the “static−analytic” method at temperatures between (303 and 353) K. This work was an opportunity to test the use of R134a as a refrigerant in combination with an organic absorbent, like DMEDEG and DMETrEG, in an absorption heat transformer (AHT), also known as a type II absorption heat pump or a reversed absorption heat pump. The experimental data were correlated using the Peng−Robinson equation of state (PR-EoS) in combination with Mathias−Copeman α function, Huron−Vidal mixing rules, and the nonrandom two-liquid (NRTL) activity coefficient model. The experimental results were compared to the predicted values obtained using the predictive Soave−Redlich−Kwong group contribution equation of state (PSRK-EoS).

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