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A New Fluorescein Derivative Bearing a Boronic Acid Group as a Fluorescent Chemosensor for Fluoride Ion

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Department of Chemistry and Division of Nano Science, Ewha Womans University, 11−1 Daehyon-Dong, Sodaemun-Ku, Seoul 120-750, Korea [email protected]
Cite this: J. Org. Chem. 2006, 71, 22, 8626–8628
Publication Date (Web):October 6, 2006
Copyright © 2006 American Chemical Society

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    A new fluorescein derivative 1 bearing a boronic acid group was investigated as a fluorescent chemosensor for F-. An off−on type fluorescence enhancement was observed by the blocking of the photoinduced electron transfer mechanism, which was induced by the interaction between fluoride and boronic acid moiety.

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    General experimental section and 1H and 13C NMR spectra of compound 1. The material is available free of charge via the Internet at

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