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Characteristic Changes of Bond Energies for Gas-Phase Cluster Ions of Halide Ions with Methane and Chloromethanes

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    Characteristic Changes of Bond Energies for Gas-Phase Cluster Ions of Halide Ions with Methane and Chloromethanes
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    Faculty of Engineering, Yamanashi University, Takeda-4, Kofu 400-8511, Japan
    Department of Chemistry, Nara University of Education, Takabatake-cho, Nara 630-8528, Japan
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    The Journal of Physical Chemistry A

    Cite this: J. Phys. Chem. A 2001, 105, 20, 4887–4893
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    https://doi.org/10.1021/jp010143n
    Published April 26, 2001
    Copyright © 2001 American Chemical Society
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    Abstract

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    Gas-phase equilibria for clustering reactions of both halide ions (X-) with methane and chloride ions with chloromethanes (CH4-mClm) were measured with a pulsed electron-beam high-pressure mass spectrometer. The bond energies were found to show irregular decreases for F-(CH4)n, with n = 6 and 8, for Cl-(CH3Cl)n, with n = 2, 4, and 6, and for Cl-(CH2Cl2)n, with n = 2 and 4. These even numbers indicate that the core ions are preferably solvated by the ligands with these n values. The theoretical calculation revealed that the cluster ion Cl-(CCl4) has the structure of [Cl...ClCCl3]- rather than Cl-...Cl3CCl. The unexpectedly large bond energy for Cl-(CCl4 ) (13.4 kcal/mol) is due to the charge dispersal in the complex [Cl...ClCCl3]-.

    Copyright © 2001 American Chemical Society

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    The Journal of Physical Chemistry A

    Cite this: J. Phys. Chem. A 2001, 105, 20, 4887–4893
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jp010143n
    Published April 26, 2001
    Copyright © 2001 American Chemical Society
    Request reuse permissions

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