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Redox Active Ordered Arrays via Metal Initiated Self-Assembly of Terpyridine Based Ligands

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    Redox Active Ordered Arrays via Metal Initiated Self-Assembly of Terpyridine Based Ligands†
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    Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301
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    The Journal of Physical Chemistry B

    Cite this: J. Phys. Chem. B 2001, 105, 37, 8746–8754
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    https://doi.org/10.1021/jp0105645
    Published June 22, 2001
    Copyright © 2001 American Chemical Society
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    Abstract

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    The interfacial reaction of terpyridyl-pendant poly-amido amine (PAMAM) dendrimers (dend-n-tpy; n = 4, 8, 32) and of bis-terpyridine containing bridging ligands (tpy-bridge-tpy), dissolved in CH2Cl2, with aqueous Fe2+ or Co2+ gives rise to film formation on HOPG and Pt(111) single crystal surfaces. Molecularly resolved STM images reveal that these films form highly ordered 2-D trigonal arrays, which appear to be composed of one-dimensional polymeric strands with a repeat unit of (tpy-dendrimer-tpy-M)x, in the case of dendrimers, or (tpy-bridge-tpy-M)x, in the case of the bridging ligands. An extensive study with ligands of tailored architecture has been carried out, providing insight on the relationship between the ligand's molecular structure and that of the resulting films. The formation of ordered domains appears to be controlled, at least in part, by the rigidity of the molecule containing the terpyridine groups. Films derived from bridging ligands containing long chains did not give rise to observable periodic structures, whereas, rotationally hindered bridging ligands gave rise to well-ordered films. The use of optically active ligands gave rise to helical structures whose sense was dependent on the chirality of the molecule employed. The physical extension of the ordered domains appears to be delimited by terrace width on the HOPG surface. The dimensions obtained from an analysis of STM images are consistent with the estimated size (from molecular modeling) of the molecules from which the films were derived. In all cases, the films are electrochemically active and exhibit a metal based reversible wave at a formal potential that corresponds to that for the respective [M(tpy)2]+2 complex.

    Copyright © 2001 American Chemical Society

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    †

     Part of the special issue “Royce W. Murray Festschrift”.

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    In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

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    This article is cited by 42 publications.

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    Cite this: J. Phys. Chem. B 2001, 105, 37, 8746–8754
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jp0105645
    Published June 22, 2001
    Copyright © 2001 American Chemical Society
    Request reuse permissions

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