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Uptake Measurements of Dibasic Esters by Water Droplets and Determination of Their Henry's Law Constants

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Centre de Géochimie de la Surface/CNRS and Université Louis Pasteur, 1 rue Blessig, F-67084 Strasbourg Cedex, France
Cite this: J. Phys. Chem. A 2003, 107, 51, 11433–11439
Publication Date (Web):December 2, 2003
https://doi.org/10.1021/jp0368132
Copyright © 2003 American Chemical Society

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    Abstract

    The uptake of dimethyl malonate and dimethyl succinate on aqueous surfaces was measured between 266 and 279 K, using the droplet train technique coupled with mass spectrometric detection. The uptake coefficients γ were found to be independent of the aqueous phase composition and of the gas−liquid contact times. In addition, the uptake coefficients and the derived mass accommodation coefficients α show a negative temperature dependence in the temperature ranges studied. The mass accommodations decrease from 7.8 × 10-2 to 5.0 × 10-2 and from 4.5 × 10-2 to 2.3 × 10-2 for dimethyl malonate and succinate, respectively. These results are used to discuss the incorporation of oxygenated volatile organic compounds (VOCs) into the liquid using the nucleation theory. Henry's law constants of both compounds were directly measured between 283 and 298 K using a dynamic equilibrium system. Their values exponentially decrease when temperature increases, from (2.60 ± 0.30) × 104 to (0.40 ± 0.05) × 104 and from (1.20 ± 0.10) × 104 to (0.30 ± 0.03) × 104 for dimethyl malonate and succinate, respectively (in units of M atm-1). The partitioning of both dibasic esters between gas and aqueous phases and the corresponding atmospheric lifetimes have then been derived.

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     To whom correspondence should be addressed. E-mail: slecalve@ illite.u-strasbg.fr.

    Cited By

    This article is cited by 9 publications.

    1. Michael L. Klossek, Didier Touraud, and Werner Kunz . Highly and Fully Water Dilutable Sustainable Microemulsions with Dibasic Esters as Oil Phase. ACS Sustainable Chemistry & Engineering 2013, 1 (6) , 603-610. https://doi.org/10.1021/sc300132x
    2. Xiuquan Sun, Tsun-mei Chang, Yang Cao, Satomi Niwayama, William L. Hase and Liem X. Dang . Solvation of Dimethyl Succinate in a Sodium Hydroxide Aqueous Solution. A Computational Study. The Journal of Physical Chemistry B 2009, 113 (18) , 6473-6477. https://doi.org/10.1021/jp901950g
    3. Rolf Sander. Compilation of Henry's law constants (version 5.0.0) for water as solvent. Atmospheric Chemistry and Physics 2023, 23 (19) , 10901-12440. https://doi.org/10.5194/acp-23-10901-2023
    4. R. Sander. Compilation of Henry's law constants (version 4.0) for water as solvent. Atmospheric Chemistry and Physics 2015, 15 (8) , 4399-4981. https://doi.org/10.5194/acp-15-4399-2015
    5. Lyassine Allou, Lahcen El Maimouni, Stéphane Le Calvé. Henry’s law constant measurements for formaldehyde and benzaldehyde as a function of temperature and water composition. Atmospheric Environment 2011, 45 (17) , 2991-2998. https://doi.org/10.1016/j.atmosenv.2010.05.044
    6. C. E. Kolb, R. A. Cox, J. P. D. Abbatt, M. Ammann, E. J. Davis, D. J. Donaldson, B. C. Garrett, C. George, P. T. Griffiths, D. R. Hanson, M. Kulmala, G. McFiggans, U. Pöschl, I. Riipinen, M. J. Rossi, Y. Rudich, P. E. Wagner, P. M. Winkler, D. R. Worsnop, C. D. O' Dowd. An overview of current issues in the uptake of atmospheric trace gases by aerosols and clouds. Atmospheric Chemistry and Physics 2010, 10 (21) , 10561-10605. https://doi.org/10.5194/acp-10-10561-2010
    7. . References. 2007, 1577-1701. https://doi.org/10.1201/9781420009132.bmatt1
    8. Pascal Diévart, Lyassine Allou, Florent Louis, Stéphane Le Calvé. Tropospheric multiphase chemistry of 2,5- and 2,6-dimethylphenols: determination of the mass accommodation coefficients and the Henry’s law constants. Physical Chemistry Chemical Physics 2006, 8 (14) , 1714. https://doi.org/10.1039/b516193b
    9. Valérie Feigenbrugel, Stéphane Le Calvé, Philippe Mirabel, Florent Louis. Henry's law constant measurements for phenol, o-, m-, and p-cresol as a function of temperature. Atmospheric Environment 2004, 38 (33) , 5577-5588. https://doi.org/10.1016/j.atmosenv.2004.06.025

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