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    The Structure of Graphite Oxide: Investigation of Its Surface Chemical Groups
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    Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE, United Kingdom, Division of Physics and Applied Physics, Nanyang Technological University, 6373616 Singapore, Laboratorio de Cerámicos y Nanomateriales, Facultad de Ciencias Físicas, Universidad Nacional Mayor de San Marcos, Ap. Postal 14-0149, Lima, Perú, and Departments of Chemistry and Physics, University of New Brunswick, P.O. Box 4400, Fredericton, NB, E3B5A3, Canada
    * Corresponding author. E-mail: [email protected]. Phone: +65 6513 8459. Fax: +65 6795 7981.
    †University of Cambridge.
    ‡Nanyang Technological University.
    §Universidad Nacional Mayor de San Marcos.
    ∥University of New Brunswick.
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    The Journal of Physical Chemistry B

    Cite this: J. Phys. Chem. B 2010, 114, 17, 5723–5728
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    https://doi.org/10.1021/jp1002275
    Published April 9, 2010
    Copyright © 2010 American Chemical Society
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    The structure of graphite oxide (GO) has been systematically studied using various tools such as SEM, TEM, XRD, Fourier transform infrared spectroscopy (FT-IR), X-ray photoemission spectroscopy (XPS), 13C solid-state NMR, and O K-edge X-ray absorption near edge structure (XANES). The TEM data reveal that GO consists of amorphous and crystalline phases. The XPS data show that some carbon atoms have sp3 orbitals and others have sp2 orbitals. The ratio of sp2 to sp3 bonded carbon atoms decreases as sample preparation times increase. The 13C solid-state NMR spectra of GO indicate the existence of —OH and —O— groups for which peaks appear at 60 and 70 ppm, respectively. FT-IR results corroborate these findings. The existence of ketone groups is also implied by FT-IR, which is verified by O K-edge XANES and 13C solid-state NMR. We propose a new model for GO based on the results; —O—, —OH, and —C═O groups are on the surface.

    Copyright © 2010 American Chemical Society

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    Cite this: J. Phys. Chem. B 2010, 114, 17, 5723–5728
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    https://doi.org/10.1021/jp1002275
    Published April 9, 2010
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