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Indirect Magnetic Coupling of Manganese Porphyrin to a Ferromagnetic Cobalt Substrate

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    Indirect Magnetic Coupling of Manganese Porphyrin to a Ferromagnetic Cobalt Substrate†
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    Laboratory for Micro- and Nanotechnology, Paul Scherrer Institut, Villigen, Switzerland, Department of Physics and Astronomy, Uppsala University, Uppsala, Sweden, Department of Physics and Research Center OPTIMAS, University of Kaiserslautern, Kaiserslautern, Germany, General Energy Department, Paul Scherrer Institut, Villigen, Switzerland, and Swiss Light Source, Paul Scherrer Institut, Villigen, Switzerland
    †Part of the “Alfons Baiker Festschrift”.
    * To whom correspondence should be addressed. E-mail: [email protected], [email protected], and [email protected]
    ‡Laboratory for Micro- and Nanotechnology, Paul Scherrer Institut.
    §Uppsala University.
    ∥University of Kaiserslautern.
    ⊥General Energy Department, Paul Scherrer Institut.
    #Swiss Light Source, Paul Scherrer Institut.
    ∇Present address: Leibniz Institute for Solid State and Materials Research, Dresden, Germany.
    ○Present address: Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, United States.
    ◆Present address: Theoretische Chemie, Ruhr-Universität Bochum, Bochum, Germany.
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    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2011, 115, 4, 1295–1301
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    https://doi.org/10.1021/jp106822s
    Published December 20, 2010
    Copyright © 2010 American Chemical Society
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    Abstract

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    The coupling mechanism of magnetic molecules to ferromagnetic surfaces is of scientific interest to design and tune molecular spintronic interfaces utilizing their molecular and surface architecture. Indirect magnetic coupling has been proposed earlier on the basis of density functional theory +U (DFT+U) calculations, for the magnetic coupling of manganese(II) porphyrin (MnP) molecules to thin Co films. Here we provide an experimental X-ray magnetic circular dichroism (XMCD) spectroscopy and scanning tunneling microscopy (STM) study of manganese(III) tetraphenylporphyrin chloride (MnTPPCl) on rough (exhibiting a high density of monatomic steps) and smooth (exhibiting a low density of monatomic steps) thin Co films grown on a Cu(001) single crystal toward the assessment of the magnetic coupling mechanism. After deposition onto the surface, MnTPPCl molecules were found to couple ferromagnetically to both rough and smooth Co substrates. For high molecular coverage, we observed higher XMCD signals at the Mn L-edges on the smooth Co substrate than on the rough Co substrate, as expected for the proposed indirect magnetic coupling mechanism on the basis of its predominance on the flat surface areas. In particular, DFT+U calculations predict a weak ferromagnetic molecule−substrate coupling only if the chloride ion of the MnTPPCl molecule orients away (Co−Mn−Cl) from the Co surface.

    Copyright © 2010 American Chemical Society

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    This article is cited by 45 publications.

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    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2011, 115, 4, 1295–1301
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jp106822s
    Published December 20, 2010
    Copyright © 2010 American Chemical Society
    Request reuse permissions

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