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Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Phys. Chem. C 2010, 114, 39, 16389-16394
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    Three-Dimensional Colloidal Crystal Arrays Exhibiting Stop Band in Near-Infrared Region
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    Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Strasse-6, 01069, Dresden, Germany, Institut für Makromolekulare Chemie, Technische Universität Dresden, D-01062 Dresden, Germany, and Department of Materials Science & Engineering, University of Ioannina, 45110 Ioannina, Greece
    * To whom correspondence should be addressed. E-mail: [email protected] ((M.A.) or [email protected] (M.S.).
    †Leibniz-Institut für Polymerforschung Dresden e.V, Hohe Strasse-6, 01069, Dresden, Germany.
    ‡Present address: Institut für Makromolekulare Chemie, Technische Universität Dresden, 01062, Dresden, Germany.
    §Present address: Department of Materials Science & Engineering, University of Ioannina, Greece.
    ∥Institut für Makromolekulare Chemie, Technische Universität Dresden, 01069, Dresden, Germany.
    ⊥Present address: Functional and Interactive Polymers, DWI RWTH Aachen University, Pauwelsstr. 8, 52056 Aachen, Germany.
    #Department of Materials Science & Engineering, University of Ioannina, Greece.
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    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2010, 114, 39, 16389–16394
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jp106961w
    Published September 8, 2010
    Copyright © 2010 American Chemical Society
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    Abstract

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    We report on the fabrication of three-dimensional colloidal crystal arrays (CCAs) on an underlying substrate via gravity sedimentation of TiO2-coated polystyrene (PS) colloidal particles. The beauty of the described system lies in the fact that obtained CCAs, for the first time, display a photonic band gap in the near-infrared (NIR) region with as much bandwidth (Δλ/λ) as 54−61%. Interestingly, stop band position and bandwidth have been found to be modulated with structural parameters of building blocks such as particle size and thickness of TiO2 shell, etc. Moreover, no significant change in stop band position was observed with the variation in incidence angle of the light. Theoretical calculations from the simulation studies have been found in agreement with the experimental findings.

    Copyright © 2010 American Chemical Society

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    This article is cited by 18 publications.

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    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2010, 114, 39, 16389–16394
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jp106961w
    Published September 8, 2010
    Copyright © 2010 American Chemical Society
    Request reuse permissions

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