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Substitutional Self-Assembly of Alkanethiol and Selenol SAMs from a Lying-Down Doubly Tethered Butanedithiol SAM on Gold

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    Substitutional Self-Assembly of Alkanethiol and Selenol SAMs from a Lying-Down Doubly Tethered Butanedithiol SAM on Gold
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    † Institut des Sciences Moléculaires d’Orsay, Université-Paris Sud, 91405 Orsay, France
    ‡ CNRS, UMR 8214, Institut des Sciences Moléculaires d’Orsay, Orsay ISMO, Bâtiment 351, Université Paris Sud, 91405 Orsay, France
    § Department of Physical & Inorganic Chemistry, Indian Institute of Science, Bangalore, India
    E-mail: [email protected]. Tel: +33169157680. Fax: +33169157671.
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    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2011, 115, 33, 16518–16523
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jp2042922
    Published July 28, 2011
    Copyright © 2011 American Chemical Society
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    Abstract

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    Substitutional self-assembly of thiol and selenol SAMs from a lying-down phase of butanedithiol (C4DT) (SAM) were investigated using thiols, disulfide, and diselenide molecules. The intent was to address the question if formation of a lying-down dithiol phase is an impediment to formation of standing-up dithiol phases as it has been assumed. It is demonstrated that this is not the case, and the C4DT SAM, where both the sulfur atoms are chemisorbed on gold, is removed and replaced in all cases. Differences in substitution kinetics are observed.

    Copyright © 2011 American Chemical Society

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    Cited By

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    This article is cited by 21 publications.

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    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2011, 115, 33, 16518–16523
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jp2042922
    Published July 28, 2011
    Copyright © 2011 American Chemical Society
    Request reuse permissions

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