ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
CONTENT TYPES

Figure 1Loading Img
ADDITION / CORRECTIONThis article has been corrected. View the notice.

Spectroscopic Investigation of Structural Rearrangements in Silver Ion-Exchanged Silicate Glasses

View Author Information
Department of Materials Engineering and Industrial Technologies, University of Trento, Via Mesiano 77, 38132 Povo (TN), Italy
Department of Computer Science, University of Verona, Strada le Grazie 15, 37134 Verona, Italy
§ Department of Physics, University of Padova and CNISM, via Marzolo 8, I-35131 Padova, Italy
Department of Molecular Sciences and Nanosystems, Ca′ Foscari University, Dorsoduro 2137, 30123 Venezia, Italy
IMEP-LAHC MINATEC, INPG 3 Parvis Louis Néel BP 257 38016 Grenoble, France.
Cite this: J. Phys. Chem. C 2012, 116, 5, 3757–3764
Publication Date (Web):December 19, 2011
https://doi.org/10.1021/jp2095399
Copyright © 2011 American Chemical Society

    Article Views

    883

    Altmetric

    -

    Citations

    LEARN ABOUT THESE METRICS
    Other access options

    Abstract

    Abstract Image

    The silver ion environment and the microstructural rearrangement of Ag+–Na+ ion-exchanged glasses were investigated by means of micro-Raman and photoluminescence spectroscopies. The samples were produced by immersing borosilicate glasses in NaNO3:AgNO3 molten salts baths with different molar ratios of silver nitrate. The modifications of the silica network microstructure were inspected by analysis of the Raman peak at about 1100 cm–1, and the evolution with the silver concentration at the glass surface of the spectral components related to the different silica tetrahedral groups was studied. The formation of silver metal nanoparticles was inferred from the occurrence of the low-frequency Raman peak due to confinement of acoustic vibrations in metal clusters, and their dimensions were evaluated from the position of its maximum. In the light of the structural analyses performed by means of Raman spectroscopy, a final assignment of the different luminescence bands of silver embedded in silicate glasses was attained.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Cited By

    This article is cited by 63 publications.

    1. Ru Zhou, Courtney Calahoo, Yicong Ding, Xu Yang, Carl P. Romao, Lothar Wondraczek. Structural Origin of the Optical Properties of Ag-Doped Fluorophosphate and Sulfophosphate Glasses. The Journal of Physical Chemistry B 2021, 125 (2) , 637-656. https://doi.org/10.1021/acs.jpcb.0c09375
    2. Elena Kolobkova, Maria Sergeevna Kuznetsova, Nikolai Nikonorov. Ag/Na Ion Exchange in Fluorophosphate Glasses and Formation of Ag Nanoparticles in the Bulk and on the Surface of the Glass. ACS Applied Nano Materials 2019, 2 (11) , 6928-6938. https://doi.org/10.1021/acsanm.9b01419
    3. Courtney Calahoo, J. W. Zwanziger, and Ian S. Butler . Mechanical–Structural Investigation of Ion-Exchanged Lithium Silicate Glass using Micro-Raman Spectroscopy. The Journal of Physical Chemistry C 2016, 120 (13) , 7213-7232. https://doi.org/10.1021/acs.jpcc.6b01720
    4. Courtney Calahoo, Xiaofang Zhang, and J. W. Zwanziger . Nanoindentation Study of the Surface of Ion-Exchanged Lithium Silicate Glass. The Journal of Physical Chemistry C 2016, 120 (10) , 5585-5598. https://doi.org/10.1021/acs.jpcc.6b00733
    5. Anne Simo, Jörg Polte, Norbert Pfänder, Ulla Vainio, Franziska Emmerling, and Klaus Rademann . Formation Mechanism of Silver Nanoparticles Stabilized in Glassy Matrices. Journal of the American Chemical Society 2012, 134 (45) , 18824-18833. https://doi.org/10.1021/ja309034n
    6. Elti Cattaruzza, Giancarlo Battaglin, Francesca Visentin, Enrico Trave, Giuliana Aquilanti, and Gino Mariotto . Enhanced Photoluminescence at λ = 1.54 μm in the Cu-Doped Er:SiO2 System. The Journal of Physical Chemistry C 2012, 116 (39) , 21001-21011. https://doi.org/10.1021/jp306487a
    7. Gian Domenico Sorarù, Sebastiano Mariazzi, Mario Barozzi, Roberto Canteri, Michele Cassetta, Damiano Pellegrini, Nicola Daldosso, Roberto Sennen Brusa, Mattia Biesuz. On the structure and properties of hydrothermally toughened soda–lime silicate float glass. Journal of the American Ceramic Society 2024, 27 https://doi.org/10.1111/jace.19832
    8. Roberta Zanini, Giulia Franceschin, Elti Cattaruzza, Arianna Traviglia. A review of glass corrosion: the unique contribution of studying ancient glass to validate glass alteration models. npj Materials Degradation 2023, 7 (1) https://doi.org/10.1038/s41529-023-00355-4
    9. A. I. Sidorov, E. Ya. Leks, O. A. Podsvirov, A. Yu. Vinogradov. Crystallization and Silicon Carbide Formation in Two-Layer Amorphous Silicon–Carbon Films during Electron Irradiation. Technical Physics 2023, 68 (S1) , S115-S119. https://doi.org/10.1134/S106378422309013X
    10. Mattia Biesuz, Gino Mariotto, Michele Cassetta, Ovidiu Ersen, Dris Ihiawakrim, Petr Haušild, Paolo Giopato, Alessandro Martucci, Mauro Bortolotti, Vincenzo M. Sglavo, Gian D. Sorarù. Solid‐State Field‐Assisted Ion Exchange (Ag → Na) in Soda–Lime Float Glass: Tin Versus Air Side. Advanced Engineering Materials 2023, 25 (18) https://doi.org/10.1002/adem.202201572
    11. Michele Cassetta, Beatrice Giannetta, Francesco Enrichi, Claudio Zaccone, Gino Mariotto, Marco Giarola, Luca Nodari, Marco Zanatta, Nicola Daldosso. Effect of the alkali vs iron ratio on glass transition temperature and vibrational properties of synthetic basalt-like glasses. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2023, 293 , 122430. https://doi.org/10.1016/j.saa.2023.122430
    12. Javier Fonseca. Nanoparticles embedded into glass matrices: glass nanocomposites. Frontiers of Materials Science 2022, 16 (3) https://doi.org/10.1007/s11706-022-0607-7
    13. Mattia Biesuz, Mauro Bortolotti, Francesco Tessarolo, Roberto Canteri, Paolo Giopato, Giandomenico Nollo, Andrea Chiappini, Monika Vilémová, Vincenzo M. Sglavo, Gian D. Sorarù. Solid-state field-assisted ion exchange of Ag in lithium aluminum silicate glass-ceramics: A superfast processing route toward stronger materials with antimicrobial properties. Journal of the European Ceramic Society 2022, 42 (4) , 1750-1761. https://doi.org/10.1016/j.jeurceramsoc.2021.11.035
    14. Michele Cassetta, Marco Zanatta, Mattia Biesuz, Marco Giarola, Gino Mariotto. New insights about the role of Na–K ratio on the vibrational dynamics of synthetic‐basalt glasses. Journal of Raman Spectroscopy 2022, 53 (3) , 540-549. https://doi.org/10.1002/jrs.6298
    15. Natalia A. Wójcik, Sharafat Ali, Efstratios I. Kamitsos, Doris Möncke. Niobate in silicate and phosphate glasses: Effect of glass basicity on crucible dissolution. International Journal of Applied Glass Science 2022, 13 (1) , 121-134. https://doi.org/10.1111/ijag.16505
    16. Atowar Rahman, G. Mariotto, E. Cattaruzza, E. Trave, F. Gonella, A. Quaranta. Thermal annealing and laser-induced mechanisms in controlling the size and size-distribution of silver nanoparticles in Ag+-Na+ ion-exchanged silicate glasses. Journal of Non-Crystalline Solids 2021, 563 , 120815. https://doi.org/10.1016/j.jnoncrysol.2021.120815
    17. Jean-Emmanuel Broquin, Seppo Honkanen. Integrated Photonics on Glass: A Review of the Ion-Exchange Technology Achievements. Applied Sciences 2021, 11 (10) , 4472. https://doi.org/10.3390/app11104472
    18. Simone Berneschi, Giancarlo C. Righini, Stefano Pelli. Towards a Glass New World: The Role of Ion-Exchange in Modern Technology. Applied Sciences 2021, 11 (10) , 4610. https://doi.org/10.3390/app11104610
    19. A. I. Sidorov, D. A. Kirpichenko, U. V. Yurina, O. A. Podsvirov. Structural Changes in Silica Glass under the Action of Electron Beam Irradiation: The Effect of Irradiation Dose. Glass Physics and Chemistry 2021, 47 (2) , 118-125. https://doi.org/10.1134/S1087659621020140
    20. A. Rahman, G. Mariotto, E. Cattaruzza, E. Trave, F. Gonella, A. Quaranta. Thermal annealing and laser induced structural rearrangement and silver state modification in Ag+-Na+ ion-exchanged silicate glasses studied by Raman spectroscopy. Journal of Non-Crystalline Solids 2021, 552 , 120455. https://doi.org/10.1016/j.jnoncrysol.2020.120455
    21. A.A. Menazea, A.M. Abdelghany. Precipitation of silver nanoparticle within silicate glassy matrix via Nd:YAG laser for biomedical applications. Radiation Physics and Chemistry 2020, 174 , 108958. https://doi.org/10.1016/j.radphyschem.2020.108958
    22. A.I. Sidorov, Y.K. Fedorov, A.I. Sivak, N.V. Vakula. Raman spectroscopic investigations on UV irradiated phosphate glasses with high content of silver or sodium. Optical Materials 2020, 102 , 109816. https://doi.org/10.1016/j.optmat.2020.109816
    23. A.I. Sidorov, N.V. Nikonorov, A.I. Ignatiev, S.V. Nemilov. The effect of UV irradiation and thermal treatments on structural properties of silver-containing photo-thermo-refractive glasses: Studies by Raman spectroscopy. Optical Materials 2019, 98 , 109422. https://doi.org/10.1016/j.optmat.2019.109422
    24. Ang Qiao, Haizheng Tao, Yuanzheng Yue. Enhancing ionic conductivity in Ag3PS4 via mechanical amorphization. Journal of Non-Crystalline Solids 2019, 521 , 119476. https://doi.org/10.1016/j.jnoncrysol.2019.119476
    25. Wenjie Zhang, Zhimin Zhao, Zijuan Xie, Shiguang Yi. Study of the compositional, structural and stress evolutions induced by low-energy argon ions on chemically strengthened glass. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 2019, 454 , 6-13. https://doi.org/10.1016/j.nimb.2019.06.004
    26. Wenjie Zhang, Zhimin Zhao, Zijuan Xie, Xiao Zhuang, Erbin He. Subsurface modification induced on ion-exchanged glass substrates by deposition and bombardment. Applied Surface Science 2019, 475 , 542-548. https://doi.org/10.1016/j.apsusc.2019.01.034
    27. Marcelo Sandrini, Robson Ferrari Muniz, Vitor Santaella Zanuto, Franciana Pedrochi, Yannick Guyot, Antonio Carlos Bento, Mauro Luciano Baesso, Alysson Steimacher, Antonio Medina Neto. Enhanced and tunable white light emission from Ag nanoclusters and Eu 3+ -co-doped CaBAl glasses. RSC Advances 2018, 8 (61) , 35263-35270. https://doi.org/10.1039/C8RA07114D
    28. Jingyuan Zhao, Zhengwen Yang, Chengye Yu, Jianbei Qiu, Zhiguo Song. Preparation of ultra-small molecule-like Ag nano-clusters in silicate glass based on ion-exchange process: Energy transfer investigation from molecule-like Ag nano-clusters to Eu3+ ions. Chemical Engineering Journal 2018, 341 , 175-186. https://doi.org/10.1016/j.cej.2018.02.028
    29. M. Haouari, F. Ben Slimen, A. Maaoui, N. Gaumer. Structural and spectroscopic properties of Eu3+ doped tellurite glass containing silver nanoparticles. Journal of Alloys and Compounds 2018, 743 , 586-596. https://doi.org/10.1016/j.jallcom.2018.01.192
    30. C. Ragoen, L. Cormier, A.-I. Bidegaray, S. Vives, F. Henneman, N. Trcera, S. Godet. A XANES investigation of the network-modifier cations environment before and after the Na + /K + ion-exchange in silicate glasses. Journal of Non-Crystalline Solids 2018, 479 , 97-104. https://doi.org/10.1016/j.jnoncrysol.2017.10.021
    31. C. Ragoen, M.A.T. Marple, S. Sen, T. Lambricht, S. Godet. Structural modifications induced by Na+/K+ ion exchange in silicate glasses: A multinuclear NMR spectroscopic study. Journal of Non-Crystalline Solids 2017, 474 , 9-15. https://doi.org/10.1016/j.jnoncrysol.2017.08.006
    32. Ali Talimian, Gino Mariotto, Vincenzo M. Sglavo. Electric field‐assisted ion exchange strengthening of borosilicate and soda lime silicate glass. International Journal of Applied Glass Science 2017, 8 (3) , 291-300. https://doi.org/10.1111/ijag.12266
    33. Y.M. Sgibnev, N.V. Nikonorov, A.I. Ignatiev. High efficient luminescence of silver clusters in ion-exchanged antimony-doped photo-thermo-refractive glasses: Influence of antimony content and heat treatment parameters. Journal of Luminescence 2017, 188 , 172-179. https://doi.org/10.1016/j.jlumin.2017.04.028
    34. Junhong Zhao, Jian Lin, Wenjun Zhang, Shuo Zhang, Guannan Zhao, Wen Cai. An optical investigation of silver nanoclusters composite soda-lime glass formed by electric field assisted diffusion. Journal of Wuhan University of Technology-Mater. Sci. Ed. 2017, 32 (2) , 338-344. https://doi.org/10.1007/s11595-017-1600-3
    35. G. Valotto, E. Cattaruzza, M. Mardegan, A. Quaranta. PARAFAC analysis of IBIL spectra from silver ion exchanged glasses. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2017, 171 , 346-350. https://doi.org/10.1016/j.saa.2016.08.024
    36. E. M. Sgibnev, N. V. Nikonorov, A. I. Ignat’ev. Spectral-luminescent properties of silver molecular clusters and nanoparticles formed by ion exchange in antimony-doped photo-thermo-refractive glasses. Optics and Spectroscopy 2017, 122 (1) , 133-138. https://doi.org/10.1134/S0030400X1701026X
    37. Josslyn Beltran Madrigal, Ricardo Tellez-Limon, Florent Gardillou, Denis Barbier, Wei Geng, Christophe Couteau, Rafael Salas-Montiel, Sylvain Blaize. Hybrid integrated optical waveguides in glass for enhanced visible photoluminescence of nanoemitters. Applied Optics 2016, 55 (36) , 10263. https://doi.org/10.1364/AO.55.010263
    38. F. Enrichi, C. Armellini, G. Battaglin, F. Belluomo, S. Belmokhtar, A. Bouajaj, E. Cattaruzza, M. Ferrari, F. Gonella, A. Lukowiak, M. Mardegan, S. Polizzi, E. Pontoglio, G.C. Righini, C. Sada, E. Trave, L. Zur. Silver doping of silica-hafnia waveguides containing Tb 3+ /Yb 3+ rare earths for downconversion in PV solar cells. Optical Materials 2016, 60 , 264-269. https://doi.org/10.1016/j.optmat.2016.07.048
    39. Y.M. Sgibnev, N.V. Nikonorov, A.I. Ignatiev. Luminescence of silver clusters in ion-exchanged cerium-doped photo-thermo-refractive glasses. Journal of Luminescence 2016, 176 , 292-297. https://doi.org/10.1016/j.jlumin.2016.04.001
    40. T. Som, S.P. Singh, B. Karmakar. Plasmonic Antimony and Bismuth Oxide Glass Nanocomposites. 2016, 215-238. https://doi.org/10.1016/B978-0-323-39309-6.00009-2
    41. Pejman Hadi, Chao Ning, James D. Kubicki, Karl Mueller, Jonathan W. Fagan, Zhengtang Luo, Lutao Weng, Gordon McKay. Sustainable development of a surface-functionalized mesoporous aluminosilicate with ultra-high ion exchange efficiency. Inorganic Chemistry Frontiers 2016, 3 (4) , 502-513. https://doi.org/10.1039/C5QI00182J
    42. Qing Jiao, Xi Wang, Jianbei Qiu, Dacheng Zhou. Effect of silver ions and clusters on the luminescence properties of Eu-doped borate glasses. Materials Research Bulletin 2015, 72 , 264-268. https://doi.org/10.1016/j.materresbull.2015.08.012
    43. William Woelffel, Corinne Claireaux, Michael J. Toplis, Ekaterina Burov, Étienne Barthel, Abhay Shukla, Johan Biscaras, Marie-Hélène Chopinet, Emmanuelle Gouillart. Analysis of soda-lime glasses using non-negative matrix factor deconvolution of Raman spectra. Journal of Non-Crystalline Solids 2015, 428 , 121-131. https://doi.org/10.1016/j.jnoncrysol.2015.08.016
    44. Xijia He, Xuhui Xu, Dacheng Zhou, Cuiqiong Yan, Jianbei Qiu. Effects of copper ions on the near-infrared luminescence in Bi doped silicate glass via copper for sodium ion exchange. Journal of Non-Crystalline Solids 2015, 421 , 30-34. https://doi.org/10.1016/j.jnoncrysol.2015.04.024
    45. Francesco Gonella. Silver doping of glasses. Ceramics International 2015, 41 (5) , 6693-6701. https://doi.org/10.1016/j.ceramint.2015.02.058
    46. Weidong Cheng, Zhaojun Wu, Xiaohua Gu, Xueqing Xing, Guang Mo, Zhonghua Wu. Grazing incidence small angle X-ray scattering study of silver nanoparticles in ion-exchanged glasses. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 2015, 351 , 51-55. https://doi.org/10.1016/j.nimb.2015.04.014
    47. W.D. Cheng, Z.J. Wu, X.H. Gu, F. Lin, X.Q. Xing, G. Mo, Z.H. Wu. GISAXS study on the size and distribution evolutions of Ag nanoparticles in ion-exchange glass during annealing. Materials Chemistry and Physics 2015, 152 , 48-53. https://doi.org/10.1016/j.matchemphys.2014.12.009
    48. Tiziana Cesca, Boris Kalinic, Niccolò Michieli, Chiara Maurizio, Angela Trapananti, Carlo Scian, Giancarlo Battaglin, Paolo Mazzoldi, Giovanni Mattei. Au–Ag nanoalloy molecule-like clusters for enhanced quantum efficiency emission of Er 3+ ions in silica. Physical Chemistry Chemical Physics 2015, 17 (42) , 28262-28269. https://doi.org/10.1039/C5CP01084E
    49. S. Ali, Y. Iqbal, M. Ajmal, F. Gonella, E. Cattaruzza, A. Quaranta. Field-driven diffusion of transition metal and rare-earth ions in silicate glasses. Journal of Non-Crystalline Solids 2014, 405 , 39-44. https://doi.org/10.1016/j.jnoncrysol.2014.08.042
    50. S. Ali, Y. Iqbal, A. Samreen, N. Ali. Field-assisted diffusion behavior of transition metal ions in silicate glasses. Journal of Non-Crystalline Solids 2014, 404 , 13-18. https://doi.org/10.1016/j.jnoncrysol.2014.07.027
    51. E. Cattaruzza, M. Mardegan, T. Pregnolato, G. Ungaretti, G. Aquilanti, A. Quaranta, G. Battaglin, E. Trave. Ion exchange doping of solar cell coverglass for sunlight down-shifting. Solar Energy Materials and Solar Cells 2014, 130 , 272-280. https://doi.org/10.1016/j.solmat.2014.07.028
    52. E. Stavrou, D. Palles, E.I. Kamitsos, A. Lipovskii, D. Tagantsev, Y. Svirko, S. Honkanen. Vibrational study of thermally ion-exchanged sodium aluminoborosilicate glasses. Journal of Non-Crystalline Solids 2014, 401 , 232-236. https://doi.org/10.1016/j.jnoncrysol.2013.12.017
    53. A. Quaranta, E. Cattaruzza, F. Gonella, A. Rahman, G. Mariotto. Cross-sectional Raman micro-spectroscopy study of silver nanoparticles in soda–lime glasses. Journal of Non-Crystalline Solids 2014, 401 , 219-223. https://doi.org/10.1016/j.jnoncrysol.2013.12.041
    54. Longji Li, Yong Yang, Dacheng Zhou, Zhengwen Yang, Xuhui Xu, Jianbei Qiu, . Influence of the Eu 2+ on the Silver Aggregates Formation in Ag + – Na + Ion‐Exchanged Eu 3+ ‐Doped Sodium–Aluminosilicate Glasses. Journal of the American Ceramic Society 2014, 97 (4) , 1110-1114. https://doi.org/10.1111/jace.12745
    55. Qing Jiao, Jianbei Qiu, Dacheng Zhou, Xuhui Xu. Contribution of Eu ions on the precipitation of silver nanoparticles in Ag-Eu co-doped borate glasses. Materials Research Bulletin 2014, 51 , 315-319. https://doi.org/10.1016/j.materresbull.2013.12.044
    56. Longji Li, Yong Yang, Dacheng Zhou, Xuhui Xu, Jianbei Qiu. The influence of Ag species on spectroscopic features of Tb3+-activated sodium–aluminosilicate glasses via Ag+–Na+ ion exchange. Journal of Non-Crystalline Solids 2014, 385 , 95-99. https://doi.org/10.1016/j.jnoncrysol.2013.11.017
    57. E. Trave, E. Cattaruzza, P. Riello. Er and Cu codoped SiO2 films obtained by sputtering deposition: Enhancement of the rare earth emission at 1.54μm mediated by metal sensitizers. Optical Materials 2013, 35 (11) , 2018-2022. https://doi.org/10.1016/j.optmat.2012.09.036
    58. Longji Li, Yong Yang, Dacheng Zhou, Zhengwen Yang, Xuhui Xu, Jianbei Qiu. Investigation of the interaction between different types of Ag species and europium ions in Ag^+-Na^+ ion-exchange glass. Optical Materials Express 2013, 3 (6) , 806. https://doi.org/10.1364/OME.3.000806
    59. Longji Li, Yong Yang, Dacheng Zhou, Zhengwen Yang, Xuhui Xu, Jianbei Qiu. Investigation of the role of silver species on spectroscopic features of Sm3+-activated sodium–aluminosilicate glasses via Ag+-Na+ ion exchange. Journal of Applied Physics 2013, 113 (19) https://doi.org/10.1063/1.4807313
    60. A.S. Kuznetsov, V.K. Tikhomirov, V.V. Moshchalkov. UV-driven efficient white light generation by Ag nanoclusters dispersed in glass host. Materials Letters 2013, 92 , 4-6. https://doi.org/10.1016/j.matlet.2012.10.053
    61. A. Rahman, G. Mariotto, E. Cattaruzza, F. Gonella, A. Quaranta. Glass structure modifications induced by diffusion of chromium ions into silicate glasses: An investigation by in-depth profiling Raman micro-spectroscopy. Solid State Ionics 2013, 230 , 59-65. https://doi.org/10.1016/j.ssi.2012.10.016
    62. A. S. Kuznetsov, V. K. Tikhomirov, M. V. Shestakov, V. V. Moshchalkov. Ag nanocluster functionalized glasses for efficient photonic conversion in light sources, solar cells and flexible screen monitors. Nanoscale 2013, 5 (21) , 10065. https://doi.org/10.1039/c3nr02798h
    63. Gabrio Valotto, Alberto Quaranta, Elti Cattaruzza, Francesco Gonella, Giancarlo Rampazzo. Multivariate analysis of Ion Beam Induced Luminescence spectra of irradiated silver ion-exchanged silicate glasses. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2012, 95 , 533-539. https://doi.org/10.1016/j.saa.2012.04.045

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect