ACS Publications. Most Trusted. Most Cited. Most Read
Electronic Control of the Tip-Induced Hopping of an Hexaphenyl-Benzene Molecule Physisorbed on a Bare Si(100) Surface at 9 K
My Activity

Figure 1Loading Img
    Article

    Electronic Control of the Tip-Induced Hopping of an Hexaphenyl-Benzene Molecule Physisorbed on a Bare Si(100) Surface at 9 K
    Click to copy article linkArticle link copied!

    View Author Information
    Institut des Sciences Moléculaires d’Orsay, ISMO, UMR 8214, CNRS, Université Paris Sud, 91405 Orsay Cedex, France
    Institut de Sciences des Matériaux de Mulhouse, IS2M, UMR 7361,CNRS, Université de Haute-Alsace, 3b rue A. Werner, 68093 Mulhouse, France
    Other Access Options

    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2013, 117, 26, 13663–13675
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jp4025014
    Published June 3, 2013
    Copyright © 2013 American Chemical Society

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    In this work, we show that the hopping directivity of individual hexaphenyl-benzene (HPB) molecules physisorbed along the SA step edge of a bare Si(100)-2×1 surface can be reversibly controlled with a periodic hopping length. This is achieved by using the tunnel electrons of a low temperature (9 K) scanning tunneling microscope (STM). A statistical analysis of the electronic excitations applied at various positions on the HPB molecule reveals that the hopping process is related to a strong decrease of the tunnel junction conductance. This process is associated with a charge transfer from the silicon surface to the HPB molecule leading to a hopping mechanism that occurs in two sequential steps. The first step of the hopping process involves the formation of an HPB anion that triggers the molecular motion into a metastable state. The second step is related to the neutralization of the HPB anion which provokes the manipulation of the molecule to its final steady position. Our experimental data are supported by the calculations of the relaxed molecule using the density functional theory on the Si(100) surface that takes the van der Waals forces interactions into account. Additional calculations of the HPB anion orbitals depict the spatial localization of the extra charge inside the HPB molecule and the relative energies of the HPB molecular orbitals. Finally, our study shows that the hopping direction can be optimized by positioning the STM tip at specific locations along the hopping pathway.

    Copyright © 2013 American Chemical Society

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Cited By

    Click to copy section linkSection link copied!
    Citation Statements
    Explore this article's citation statements on scite.ai

    This article is cited by 14 publications.

    1. Eric Duverger, Damien Riedel. Mapping the Reversible Charge State Control of an Iron Tetraphenyl Porphyrin Molecule Adsorbed on a CaF2/Si(100) Semi-Insulating Surface at Low Temperature (9 K). The Journal of Physical Chemistry C 2024, 128 (29) , 12023-12035. https://doi.org/10.1021/acs.jpcc.4c02455
    2. Zhiyu Yi, Le Lin, Xuda Luo, Yanxiao Ning, Qiang Fu. Oxide-Metal Interaction Probed by Scanning Tunneling Microscope Manipulation of Cr2O7 Clusters on Au(111). The Journal of Physical Chemistry Letters 2023, 14 (8) , 2163-2170. https://doi.org/10.1021/acs.jpclett.3c00184
    3. Eric Duverger, Anne-Gaëlle Boyer, Hélène Sauriat-Dorizon, Philippe Sonnet, Régis Stephan, Marie-Christine Hanf, Damien Riedel. Two-Dimensional Functionalized Ultrathin Semi-Insulating CaF2 Layer on the Si(100) Surface at a Low Temperature for Molecular Electronic Decoupling. ACS Applied Materials & Interfaces 2020, 12 (26) , 29661-29670. https://doi.org/10.1021/acsami.0c06631
    4. Mayssa Yengui, Eric Duverger, Philippe Sonnet, Damien Riedel. Translational Manipulation of Magnetic Cobalt Adatoms on the Si(100)-2 × 1 Surface at 9 K. The Journal of Physical Chemistry C 2019, 123 (43) , 26415-26423. https://doi.org/10.1021/acs.jpcc.9b07951
    5. Szymon Godlewski, Hiroyo Kawai, Marek Kolmer, Rafał Zuzak, Antonio M. Echavarren, Christian Joachim, Marek Szymonski, and Mark Saeys . Single-Molecule Rotational Switch on a Dangling Bond Dimer Bearing. ACS Nano 2016, 10 (9) , 8499-8507. https://doi.org/10.1021/acsnano.6b03590
    6. Mayssa Yengui and Damien Riedel . Evidence of Low Schottky Barrier Effects and the Role of Gap States in the Electronic Transport through Individual CoSi2 Silicide Nanoislands at Low Temperature (9 K). The Journal of Physical Chemistry C 2015, 119 (39) , 22700-22708. https://doi.org/10.1021/acs.jpcc.5b06816
    7. Hoon-Seok Seo, Ryoma Hayakawa, Toyohiro Chikyow, and Yutaka Wakayama . Multilevel Operation of Resonant Tunneling with Binary Molecules in a Metal–Insulator–Semiconductor Configuration. The Journal of Physical Chemistry C 2014, 118 (12) , 6467-6472. https://doi.org/10.1021/jp411386s
    8. Pablo Ramos, Marc Mankarious, Michele Pavanello, Damien Riedel. Probing charge transfer dynamics in a single iron tetraphenylporphyrin dyad adsorbed on an insulating surface. Nanoscale 2018, 10 (37) , 17603-17616. https://doi.org/10.1039/C8NR05424J
    9. Mayssa Yengui, Eric Duverger, Philippe Sonnet, Damien Riedel. A two-dimensional ON/OFF switching device based on anisotropic interactions of atomic quantum dots on Si(100):H. Nature Communications 2017, 8 (1) https://doi.org/10.1038/s41467-017-02377-4
    10. Hatem Labidi, Henry P. Pinto, Jerzy Leszczynski, Damien Riedel. Exploiting a single intramolecular conformational switching Ni-TPP molecule to probe charge transfer dynamics at the nanoscale on bare Si(100)-2 × 1. Physical Chemistry Chemical Physics 2017, 19 (42) , 28982-28992. https://doi.org/10.1039/C7CP05906J
    11. Franco Chiaravalloti, Gérald Dujardin, Damien Riedel. Atomic scale control of hexaphenyl molecules manipulation along functionalized ultra-thin insulating layer on the Si(1 0 0) surface at low temperature (9 K). Journal of Physics: Condensed Matter 2015, 27 (5) , 054006. https://doi.org/10.1088/0953-8984/27/5/054006
    12. Mayssa Yengui, Henry P Pinto, Jerzy Leszczynski, Damien Riedel. Atomic scale study of corrugating and anticorrugating states on the bare Si(1 0 0) surface. Journal of Physics: Condensed Matter 2015, 27 (4) , 045001. https://doi.org/10.1088/0953-8984/27/4/045001
    13. Ph. Sonnet, D. Riedel. The Scanning Tunneling Microscopy of Adsorbed Molecules on Semiconductors: Some Theoretical Answers to the Experimental Observations. 2014, 1-44. https://doi.org/10.1007/978-1-4899-7445-7_1
    14. Mayssa Yengui, Damien Riedel. Cobalt adsorption on the bare Si(100) 2 × 1 surface at low temperature (12 K). Surface Science 2014, 619 , 10-18. https://doi.org/10.1016/j.susc.2013.10.005

    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2013, 117, 26, 13663–13675
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jp4025014
    Published June 3, 2013
    Copyright © 2013 American Chemical Society

    Article Views

    520

    Altmetric

    -

    Citations

    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.