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Sequence-Programmable Multicomponent Multilayers of Nanometer-Sized Tetralactam Macrocycles on Gold Surfaces

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Institut für Chemie und Biochemie, Freie Universität Berlin, Takustraße 3, 14195 Berlin, Germany
BAM, Bundesanstalt für Materialforschung und -prüfung, Unter den Eichen 44-46, 12203 Berlin, Germany
*E-mail: [email protected] (C.A.S.).
*E-mail: [email protected] (W.E.S.U.).
Cite this: J. Phys. Chem. C 2013, 117, 37, 18980–18985
Publication Date (Web):August 19, 2013
https://doi.org/10.1021/jp405492v
Copyright © 2013 American Chemical Society

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    Abstract

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    Multicomponent multilayers have been deposited on gold surfaces by metal-ion-mediated layer-by-layer self-assembly of differently functionalized tetralactam macrocycles. The layer stack can be programmed with respect to the sequences of metal ions and macrocycles by the deposition sequence.

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    Full experimental procedures and characterization of new compounds, copies of 1H, 13C, and 19F NMR spectra, multilayer preparation, instrumentation and data processing used for the described experiments, additional transmission UV/vis, XPS, NEXAFS, and ToF-SIMS data for the characterization of the multilayers. This material is available free of charge via the Internet at http://pubs.acs.org.

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