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    Deep-Red Emitting Mn4+ Doped Mg2TiO4 Nanoparticles
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    † University of Belgrade, Vinča Institute of Nuclear Sciences, P.O. Box 522, Belgrade 11001, Serbia
    ‡ College of Sciences, Chongqing University of Posts and Telecommunications, Chongqing 400065, People’s Republic of China
    § Institute of Physics, University of Tartu, Tartu 50411, Estonia
    ∥ Institute of Physics, Jan Dlugosz University, PL-42200 Czestochowa, Poland
    ⊥ Laboratory for Materials Chemistry, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana, Slovenia
    *Tel. +381 11 3408607; e-mail: [email protected]
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    The Journal of Physical Chemistry C

    Cite this: J. Phys. Chem. C 2015, 119, 1, 724–730
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    https://doi.org/10.1021/jp5095646
    Published December 10, 2014
    Copyright © 2014 American Chemical Society
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    Synthesis, structure, morphology, and detailed spectroscopic and crystal-field analysis of Mn4+ doped Mg2TiO4 nanoparticles (NPs) are presented. These Mg2TiO4:Mn4+ NPs are obtained through a Pechini-type polymerized complex route and calcination at 600 °C, and are approximately 10 nm in diameter and loosely agglomerated into 1-μm particles, as evidenced from transmission electron microscopy. These NPs exhibit strong, sharp red emission at 658 nm (with a 1.2 ms emission decay) as a result of the spin-forbidden 2Eg → 4A2g electron transition of the tetravalent manganese ions. No signatures of the presence of manganese ions in divalent or trivalent valence states are observed in the NPs with either photoluminescence or diffuse reflection spectroscopy. The energy levels of the Mn4+ ions in a trigonal crystal field of Mg2TiO4 are calculated using the exchange-charge model and are well matched with the experimental photoluminescence excitation and emission spectra. The absolute values of the calculated crystal-field parameters (CFPs) are similar to those reported for trigonal point symmetry at Mn4+ dopant sites (Y2Ti2O7, Y2Sn2O7, and Na2SiF6). It is also observed that the contributions of covalent and exchange effects to the CFPs are nearly eight times greater than the point-charge contribution.

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    Cite this: J. Phys. Chem. C 2015, 119, 1, 724–730
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    https://doi.org/10.1021/jp5095646
    Published December 10, 2014
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