Neat Liquid Consisting of Hydrogen-Bonded Tetramers: Dicyclohexylmethanol
View Author Information
Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan
* To whom correspondence should be addressed. E-mail: [email protected]
†Present address: National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan.
Abstract
Nonmonotonous temperature dependence was detected in the heat capacity and dielectric constant of the title compound in the liquid state. A coherent analysis of FT-IR spectra, heat capacity, and dielectric constants shows that the neat liquid at low temperatures consists of closed (square) tetramers via H-bonds.
Cited By
This article is cited by 16 publications.
- Václav Pokorný, Ctirad Červinka, Vojtěch Štejfa, Jakub Havlín, Květoslav Růžička, Michal Fulem. Heat Capacities of l-Alanine, l-Valine, l-Isoleucine, and l-Leucine: Experimental and Computational Study. Journal of Chemical & Engineering Data 2020, 65 (4) , 1833-1849. https://doi.org/10.1021/acs.jced.9b01086
- Yasuhisa Yamamura, Yu-ta Suzuki, Masato Sumita, and Kazuya Saito . Calorimetric Study of Glass Transition in Molecular Liquids Consisting of Globular Associates: Dicyclorohexylmethanol and Tricyclohexylmethanol. The Journal of Physical Chemistry B 2012, 116 (13) , 3938-3943. https://doi.org/10.1021/jp210809j
- Kazuya Saito. Molecular Liquids. 2020,,, 53-64. https://doi.org/10.1007/978-981-15-9023-8_3
- Kazuya Saito. Chemical Physics of Molecular Condensed Matter. 2020,,https://doi.org/10.1007/978-981-15-9023-8
- Tomáš Mahnel, Václav Pokorný, Michal Fulem, David Sedmidubský, Květoslav Růžička. Measurement of low-temperature heat capacity by relaxation technique: Calorimeter performance testing and heat capacity of benzo[b]fluoranthene, benzo[k]fluoranthene, and indeno[1,2,3-cd]pyrene. The Journal of Chemical Thermodynamics 2020, 142 , 105964. https://doi.org/10.1016/j.jct.2019.105964
- Małgorzata Jasiurkowska-Delaporte, Tomasz Rozwadowski, Ewa Juszyńska-Gałązka. Kinetics of Non-Isothermal and Isothermal Crystallization in a Liquid Crystal with Highly Ordered Smectic Phase as Reflected by Differential Scanning Calorimetry, Polarized Optical Microscopy and Broadband Dielectric Spectroscopy. Crystals 2019, 9 (4) , 205. https://doi.org/10.3390/cryst9040205
- Paulo B. P. Serra, Ivan Krakovský, Michal Fulem, Květoslav Růžička. Calorimetric and FTIR study of selected aliphatic octanols. Journal of Thermal Analysis and Calorimetry 2018, 134 (3) , 2157-2170. https://doi.org/10.1007/s10973-018-7382-9
- Kazuya Saito, Mafumi Hishida, Kent Koike, Shigenori Nagatomo, Yasuhisa Yamamura. X-ray study of molecular association in alcohols having bulky substituents. Chemical Physics Letters 2017, 673 , 74-77. https://doi.org/10.1016/j.cplett.2017.02.011
- Kazuya Saito, Takaaki Ikeda, Yasuhisa Yamamura, Hideki Saitoh, Mafumi Hishida, Yutaro Kobayashi, Takeshi Fujita, Junji Ichikawa. Cell-quintupling: Structural phase transition in a molecular crystal, bis( trans -4–butylcyclohexyl)methanol. The Journal of Chemical Physics 2017, 146 (7) , 074503. https://doi.org/10.1063/1.4976318
- Paulo B.P. Serra, Květoslav Růžička, Michal Fulem, Ondřej Vlk, Ivan Krakovský. Calorimetric and FTIR study of selected aliphatic heptanols. Fluid Phase Equilibria 2016, 423 , 43-54. https://doi.org/10.1016/j.fluid.2016.04.003
- Vojtěch Štejfa, Michal Fulem, Květoslav Růžička, Pavel Matějka. Vapor pressures and thermophysical properties of selected hexenols and recommended vapor pressure for hexan-1-ol. Fluid Phase Equilibria 2015, 402 , 18-29. https://doi.org/10.1016/j.fluid.2015.05.026
- Christian Wohlfarth. Static dielectric constant of dicyclohexylmethanol. 2015,,, 210-210. https://doi.org/10.1007/978-3-662-48168-4_209
- Christian Wohlfarth, . Static Dielectric Constants of Pure Liquids and Binary Liquid Mixtures. 2015,,https://doi.org/10.1007/978-3-662-48168-4
- Martin Straka, Květoslav Růžička, Michal Fulem. Heat capacities of 2-propenol and selected cyclohexylalcohols. Thermochimica Acta 2014, 587 , 67-71. https://doi.org/10.1016/j.tca.2014.03.043
- E. Juszyńska-Gałązka, P.M. Zieliński, M. Massalska-Arodź, J. Krawczyk. Solid State Polymorphism and Dynamics οf 2,2-Dimethylbutan-1-ol as Studied by Adiabatic Calorimetry and Dielectric Spectroscopy. Acta Physica Polonica A 2013, 124 (6) , 917-925. https://doi.org/10.12693/APhysPolA.124.917
- Shigenori Nagatomo, Megumi Nobuhira, Yasuhisa Yamamura, Masato Sumita, Kazuya Saito. Identification of Hydrogen-Bonded Oligomers in Associating Liquid by 1 H NMR: 1-Phenyl-1-cyclohexanol. Bulletin of the Chemical Society of Japan 2013, 86 (5) , 569-576. https://doi.org/10.1246/bcsj.20120322