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Mechanisms of UV Photodissociation of Small Protonated Peptides

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Download Hi-Res ImageDownload to MS-PowerPointCite This:J. Phys. Chem. A 2010, 114, 9, 3147-3156
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    Mechanisms of UV Photodissociation of Small Protonated Peptides†
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    Université Paris-Sud, Laboratoire des Collisions Atomiques et Moléculaires, UMR 8625, Bât. 351, Orsay, F-91405 France and Université. Paris-Sud, Laboratoire de Photophysique Moléculaire, UPR 3361, Bât. 210, Orsay, F-91405 France
    Université Paris-Sud, Laboratoire des Collisions Atomiques et Moléculaires, UMR 8625, Bât. 351, Orsay, F-91405 France, and CNRS, UMR 8625, Orsay, F-91405 France
    Université Paris-Sud, Laboratoire de Photophysique Moléculaire, UPR 3361, Bât. 210, Orsay, F-91405 France, and CNRS, UPR 3361, Orsay, F-91405 France
    †Part of the “Benoît Soep Festschrift”.
    * Corresponding author. E-mail: [email protected]
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    The Journal of Physical Chemistry A

    Cite this: J. Phys. Chem. A 2010, 114, 9, 3147–3156
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jp908937s
    Published November 20, 2009
    Copyright © 2009 American Chemical Society
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    Abstract

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    Photofragmentation of protonated dipeptides by 263 nm photons is investigated with an experimental technique based on the detection in coincidence of the ionic and neutral fragments. With this method, it is possible to determine whether the fragmentation takes place in one or several steps. The timing of these steps can also be evaluated. The interpretation of the various fragmentation pathways is tentatively developed along the same line as that previously proposed for tryptophan. The fragmentation can be explained by two types of mechanisms: internal conversions and direct fragmentations triggered by the migration of the photoactive electron on positive charged sites or on oxygen sites.

    Copyright © 2009 American Chemical Society

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    This article is cited by 33 publications.

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    The Journal of Physical Chemistry A

    Cite this: J. Phys. Chem. A 2010, 114, 9, 3147–3156
    Click to copy citationCitation copied!
    https://doi.org/10.1021/jp908937s
    Published November 20, 2009
    Copyright © 2009 American Chemical Society
    Request reuse permissions

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