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Transition Scenarios during the Evolution of the Belousov−Zhabotinsky Reaction in an Unstirred Batch Reactor

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Università di Sassari, Dipartimento di Chimica, Via Vienna 2, 07100 Sassari, Italia
Cite this: J. Phys. Chem. A 1999, 103, 33, 6564–6570
Publication Date (Web):August 3, 1999
https://doi.org/10.1021/jp9902708
Copyright © 1999 American Chemical Society
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Abstract

We report experimental evidence of transition scenarios during the chemical evolution in an unstirred closed Belousov−Zhabotinsky (BZ) system. We demonstrate that during its chemical evolution the system spontaneously gives the following sequence of dynamic behavior before reaching equilibrium:  period-1 → quasiperiodicity → chaos → quasiperiodicity → period-1. Two transition scenarios are observed:  at the onset of chaos and at its end. One appears as the mirror image of the other. Our observations support the view that closed chemical systems also are able to show chaotic behavior and the corresponding transition scenarios.

*

 Corresponding author e-mail:  [email protected]

†

 Università di Siena, Dipartimento di Scienze e Tecnologie Chimiche e dei Biosistemi, Pian dei Mantellini 44, 53100 Siena, Italia.

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