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Theoretical Estimates of Redox Potentials for Group 6 Elements, Including Element 106, Seaborgium, in Acid Solutions

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Gesellschaft für Schwerionenforschung, Darmstadt, D-64291 Germany
Florida Agricultural and Mechanical University, Tallahassee, Florida 32307-6600
Theoretical Physics Department, University of Kassel, D-34109 Kassel, Germany
Cite this: J. Phys. Chem. A 1999, 103, 42, 8463–8470
Publication Date (Web):October 4, 1999
https://doi.org/10.1021/jp990322t
Copyright © 1999 American Chemical Society

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    Abstract

    Standard reduction potentials for group 6 elements, including element 106 (Sg), in acid solutions have been estimated on the basis of ionization potentials calculated using the multiconfiguration Dirac−Fock method. The stability of the 6+ oxidation state is shown to increase within group 6, while that of the 5+, 4+, and 3+ states is shown to decrease. No extra stability of the 4+ oxidation state of Sg can be inferred. Thus, no deviation from the Mendeleev-type periodicity is found for group 6 elements.

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