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Formation of PVP-Protected Metal Nanoparticles in DMF
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    Formation of PVP-Protected Metal Nanoparticles in DMF
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    Departamento de Química Física, Universidade de Vigo, 36200 Vigo, Spain
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    Langmuir

    Cite this: Langmuir 2002, 18, 7, 2888–2894
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    https://doi.org/10.1021/la015578g
    Published February 21, 2002
    Copyright © 2002 American Chemical Society

    Abstract

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    Poly(vinylpyrrolidone) (PVP) is a polymer capable of complexing and stabilizing Ag and Au nanoparticles formed through the reduction of Ag+ or AuCl4- ions with N,N-dimethylformamide. The reduction can be efficiently performed both at reflux and under microwave irradiation, but each of these methods leads to different nanoparticle morphology and colloid stability. The use of microwave irradiation provides an extra degree of control of the reduction process. The use of PVP with different polymer chain lengths leads to particles with similar sizes though with a different degree of stability. The colloids are also stable in ethanol for months, but only marginally stable in water.

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     To whom correspondence should be addressed. E-mail:  [email protected].

    Supporting Information Available

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    Spectral evolution during Ag reduction at reflux with mixing of AgClO4 and PVP prior to heating and with simultaneous addition at reflux; spectral evolution during Au reduction under microwave irradiation with PVPK15 and at reflux with PVPK30. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cite this: Langmuir 2002, 18, 7, 2888–2894
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    https://doi.org/10.1021/la015578g
    Published February 21, 2002
    Copyright © 2002 American Chemical Society

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