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    Bilayer in a Liquid Self-Supported Film
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    Centre de Physique Moléculaire Optique et Hertzienne, CNRS UMR 5798, Université Bordeaux I, 33405 Talence Cedex, France, Laboratoire de Physique, CNRS UMR 5672, Ecole Normale Supérieure de Lyon, 69364 Lyon Cedex 07, France, and Laboratoire de Physico-Chimie Moléculaire, CNRS UMR 5803, Université Bordeaux I, 33405 Talence Cedex, France
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    Langmuir

    Cite this: Langmuir 2003, 19, 21, 8615–8617
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    https://doi.org/10.1021/la0346853
    Published September 18, 2003
    Copyright © 2003 American Chemical Society
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    Abstract

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    The drainage of vertical soap films formed from nonionic surfactant solutions of pentaethylene glycol monododecyl ether (C12E5) was studied using Fourier transform infrared spectroscopy. At relatively low surfactant concentrations in the bulk solution (but above the critical micelle concentration), a transient surfactant bilayer was observed within these soap films. The expulsion of water and of a surfactant bilayer from the film was followed as a function of time. The bilayer found within the film displayed a much higher degree of molecular order than the two outer monolayers of the soap film. This study can serve as a model for similar studies on biomembranes.

    Copyright © 2003 American Chemical Society

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    *

     To whom correspondence should be addressed. Present address: Netherlands Forensic Institute, Ministry of Justice, P.O. Box 3110, 2280 GC Rijswijk, The Netherlands.

    †

     Centre de Physique Moléculaire Optique et Hertzienne, CNRS UMR 5798, Université Bordeaux I.

    ‡

     Laboratoire de Physique, CNRS UMR 5672, Ecole Normale Supérieure de Lyon.

    §

     Laboratoire de Physico-Chimie Moléculaire, CNRS UMR 5803, Université Bordeaux I.

    Cited By

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    This article is cited by 5 publications.

    1. Jian Jin, Weifeng Bu and Izumi Ichinose . Thermal and Mechanical Properties of Dried Foam Films and Their Incorporation of Water-Soluble Compounds. Langmuir 2010, 26 (13) , 10506-10512. https://doi.org/10.1021/la100523b
    2. Weifeng Bu, Jian Jin, Izumi Ichinose. Dried foam films with a triple bilayer structure induced by ionic liquids. Chemical Communications 2007, 100?102 (13) , 1325. https://doi.org/10.1039/b616831k
    3. G. Ropars, D. Chauvat, A. Le Floch, M. N. O’Sullivan-Hale, R. W. Boyd. Dynamics of gravity-induced gradients in soap film thicknesses. Applied Physics Letters 2006, 88 (23) https://doi.org/10.1063/1.2209201
    4. Jian Jin, Jianguo Huang, Izumi Ichinose. Dried Foam Films: Self‐Standing, Water‐Free, Reversed Bilayers of Amphiphilic Compounds. Angewandte Chemie 2005, 117 (29) , 4608-4611. https://doi.org/10.1002/ange.200500036
    5. Jian Jin, Jianguo Huang, Izumi Ichinose. Dried Foam Films: Self‐Standing, Water‐Free, Reversed Bilayers of Amphiphilic Compounds. Angewandte Chemie International Edition 2005, 44 (29) , 4532-4535. https://doi.org/10.1002/anie.200500036
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    Langmuir

    Cite this: Langmuir 2003, 19, 21, 8615–8617
    Click to copy citationCitation copied!
    https://doi.org/10.1021/la0346853
    Published September 18, 2003
    Copyright © 2003 American Chemical Society
    Request reuse permissions

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