Single-Walled Carbon Nanotube Combing during Layer-by-Layer Assembly: From Random Adsorption to Aligned CompositesClick to copy article linkArticle link copied!
Abstract

Oriented SWNTs in polymer composites have shown dramatic improvements in the physical properties of a composite because of the anisotropic shape and properties of SWNTs. Controlled alignment of SWNTs during composite fabrication implies better material function performance. This letter reports a new fabrication technique whereby aligned SWNTs and robust SWNT−polymer composites can be made using a fusion method of SWNT combing and layer-by-layer (LBL) assembly. As we previously reported, LBL assembly demonstrated exceptional processing ability in constructing the uniform distribution of a SWNT−polymer composite. Combined with this uniformity, this SWNT combing technique endows controlled alignment of single-stranded SWNTs in a SWNT−polymer composite system. SWNT combing employs air−water interfacial forces to change the molecular topography from the random adsorption state to the stretched alignment of SWNTs. More specifically, air−water interfacial forces are associated with an excess viscous drag force and an intrinsic dewetting rate along SWNTs. Moreover, the alignment efficiency of SWNTs is high enough to construct a multilayered LBL film with horizontal−linear weaving structures. This simple method also can be applied for aligning other nanowire materials because it utilizes simple geometric features of SWNTs.
†
Department of Chemical Engineering.
*
Corresponding author. E-mail: [email protected]. Tel: 1-734-763-8768. Fax: 1-734-764-7453.
‡
Departments of Materials Science and Biomedical Engineering.
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