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Phenol Photodegradation on Platinized-TiO2 Photocatalysts Related to Charge-Carrier Dynamics

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Unidad de Actividad Química, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica, Avenida General Paz 1499, 1650 San Martín, Provincia de Buenos Aires, Argentina, Hahn-Meitner-Institut, Abteilung Solare Energetik, Glienicker Strasse 100, 14109 Berlin, Germany, Laboratoire d'Ingénierie des Matériaux et des Hautes Pressions (CNRS, UPR1311), Université Paris 13, 99 Avenue J.-B. Clément, Villetaneuse 93430, France
Cite this: Langmuir 2006, 22, 8, 3606–3613
Publication Date (Web):March 18, 2006
https://doi.org/10.1021/la051962s
Copyright © 2006 American Chemical Society

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    Abstract

    Abstract Image

    Three commercial TiO2 compounds (Degussa P25, Sachtleben UV100, and Millenium PC50) and their platinized forms have been studied by the time-resolved microwave conductivity (TRMC) method to follow their charge-carrier dynamics and to relate it to the photocatalytic activity for phenol degradation in TiO2 aqueous suspensions. The degradation reaction has been studied in detail, following the time evolution of the concentration of phenol and its intermediates by liquid chromatography. The results show that platinization has a distinct influence on the commercial compounds, decreasing globally the activity of P25 and increasing the activity of PC50 and UV100. An influence of charge-carrier lifetimes on the photoactivity of pure and platinized TiO2 samples has been evidenced.

     Comisión Nacional de Energía Atómica.

     Abteilung Solare Energetik.

    §

     Université Paris 13.

    *

     Corresponding author. Mailing address:  Laboratoire d‘Ingénierie des Matériaux et des Hautes Pressions, CNRS − UPR 1311, Université Paris 13, 99 avenue J.-B. Clément, 93430 Villetaneuse, France. Phone:  +33 1 49 40 44 88. Fax:  +33 1 49 40 34 14. E-mail:  [email protected].

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