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Contact-Line Friction of Liquid Drops on Self-Assembled Monolayers:  Chain-Length Effects

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Download Hi-Res ImageDownload to MS-PowerPointCite This:Langmuir 2007, 23, 9, 4695-4699
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    Contact-Line Friction of Liquid Drops on Self-Assembled Monolayers:  Chain-Length Effects
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    Centre de Recherches en Modélisation Moléculaire, Université de Mons-Hainaut/Materia Nova, Parc Initialis, Av. Copernic, 1, B-7000 Mons, Belgium, Service de Science des Polymères, Université Libre de Bruxelles, CP233 Bvd du Triomphe, B-1050 Bruxelles, Belgium, Institut de Chimie des Surfaces et Interfaces de Mulhouse, BP 2488, 15 rue Jean Starckyn, F-8057 Mulhouse Cedex, France
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    Langmuir

    Cite this: Langmuir 2007, 23, 9, 4695–4699
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    https://doi.org/10.1021/la062884r
    Published March 28, 2007
    Copyright © 2007 American Chemical Society
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    Abstract

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    The static and dynamic wetting properties of self-assembled alkanethiol monolayers of increasing chain length were studied. The molecular-kinetic theory of wetting was used to interpret the dynamic contact angle data and evaluate the contact-line friction on the microscopic scale. Although the surfaces had a similar static wettability, the coefficient of contact-line friction ζ0 increased linearly with alkyl chain length. This result supports the hypothesis of energy dissipation due to a local deformation of the nanometer-thick layer at the contact line.

    Copyright © 2007 American Chemical Society

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    *

     Corresponding author. E-mail:  [email protected].

    †

     Université de Mons-Hainaut.

    ‡

     Université Libre de Bruxelles.

    §

     Institut de Chimie des Surfaces et Interfaces de Mulhouse.

    Cited By

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    This article is cited by 29 publications.

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    Langmuir

    Cite this: Langmuir 2007, 23, 9, 4695–4699
    Click to copy citationCitation copied!
    https://doi.org/10.1021/la062884r
    Published March 28, 2007
    Copyright © 2007 American Chemical Society
    Request reuse permissions

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