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    In Situ Molecular Spectroscopic Evidence for CO2 Intercalation into Montmorillonite in Supercritical Carbon Dioxide
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    Pacific Northwest National Laboratory, Richland, Washington 99352, United States
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    Cite this: Langmuir 2012, 28, 18, 7125–7128
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    https://doi.org/10.1021/la301136w
    Published April 25, 2012
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    The interaction of anhydrous supercritical CO2 (scCO2) with both kaolinite and ∼1W (i.e., close to but less than one layer of hydration) calcium-saturated montmorillonite was investigated under conditions relevant to geologic carbon sequestration (50 °C and 90 bar). The CO2 molecular environment was probed in situ using a combination of three novel high-pressure techniques: X-ray diffraction, magic angle spinning nuclear magnetic resonance spectroscopy, and attenuated total reflection infrared spectroscopy. We report the first direct evidence that the expansion of montmorillonite under scCO2 conditions is due to CO2 migration into the interlayer. Intercalated CO2 molecules are rotationally constrained and do not appear to react with waters to form bicarbonate or carbonic acid. In contrast, CO2 does not intercalate into kaolinite. The findings show that predicting the seal integrity of caprock will have complex dependence on clay mineralogy and hydration state.

    Copyright © This article not subject to U.S. Copyright. Published 2012 by the American Chemical Society

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    32. Qi Rao and Yongsheng Leng . Molecular Understanding of CO2 and H2O in a Montmorillonite Clay Interlayer under CO2 Geological Sequestration Conditions. The Journal of Physical Chemistry C 2016, 120 (5) , 2642-2654. https://doi.org/10.1021/acs.jpcc.5b09683
    33. Mohan Maruthi Sena, Christin P. Morrow, R. James Kirkpatrick, and Marimuthu Krishnan . Supercritical Carbon Dioxide at Smectite Mineral–Water Interfaces: Molecular Dynamics and Adaptive Biasing Force Investigation of CO2/H2O Mixtures Nanoconfined in Na-Montmorillonite. Chemistry of Materials 2015, 27 (20) , 6946-6959. https://doi.org/10.1021/acs.chemmater.5b01855
    34. Ian C. Bourg, Lauren E. Beckingham, and Donald J. DePaolo . The Nanoscale Basis of CO2 Trapping for Geologic Storage. Environmental Science & Technology 2015, 49 (17) , 10265-10284. https://doi.org/10.1021/acs.est.5b03003
    35. Meysam Makaremi, Kenneth D. Jordan, George D. Guthrie, and Evgeniy M. Myshakin . Multiphase Monte Carlo and Molecular Dynamics Simulations of Water and CO2 Intercalation in Montmorillonite and Beidellite. The Journal of Physical Chemistry C 2015, 119 (27) , 15112-15124. https://doi.org/10.1021/acs.jpcc.5b01754
    36. Evgeniy M. Myshakin, Meysam Makaremi, Vyacheslav N. Romanov, Kenneth D. Jordan, and George D. Guthrie . Molecular Dynamics Simulations of Turbostratic Dry and Hydrated Montmorillonite with Intercalated Carbon Dioxide. The Journal of Physical Chemistry A 2014, 118 (35) , 7454-7468. https://doi.org/10.1021/jp500221w
    37. Mal-Soon Lee, B. Peter McGrail, and Vassiliki-Alexandra Glezakou . Microstructural Response of Variably Hydrated Ca-rich Montmorillonite to Supercritical CO2. Environmental Science & Technology 2014, 48 (15) , 8612-8619. https://doi.org/10.1021/es5005889
    38. John S. Loring, Eugene S. Ilton, Jeffrey Chen, Christopher J. Thompson, Paul F. Martin, Pascale Bénézeth, Kevin M. Rosso, Andrew R. Felmy, and Herbert T. Schaef . In Situ Study of CO2 and H2O Partitioning between Na–Montmorillonite and Variably Wet Supercritical Carbon Dioxide. Langmuir 2014, 30 (21) , 6120-6128. https://doi.org/10.1021/la500682t
    39. Geoffrey M. Bowers, David W. Hoyt, Sarah D. Burton, Brennan O. Ferguson, Tamas Varga, and R. James Kirkpatrick . In Situ 13C and 23Na Magic Angle Spinning NMR Investigation of Supercritical CO2 Incorporation in Smectite–Natural Organic Matter Composites. The Journal of Physical Chemistry C 2014, 118 (7) , 3564-3573. https://doi.org/10.1021/jp410535d
    40. H. T. Schaef, V.-A. Glezakou, A. T. Owen, S. Ramprasad, P. F. Martin, and B. P. McGrail . Surface Condensation of CO2 onto Kaolinite. Environmental Science & Technology Letters 2014, 1 (2) , 142-145. https://doi.org/10.1021/ez400169b
    41. Craig M. Tenney and Randall T. Cygan . Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral Interactions and Determination of Contact Angles. Environmental Science & Technology 2014, 48 (3) , 2035-2042. https://doi.org/10.1021/es404075k
    42. Marimuthu Krishnan, Moumita Saharay, and R. James Kirkpatrick . Molecular Dynamics Modeling of CO2 and Poly(ethylene glycol) in Montmorillonite: The Structure of Clay–Polymer Composites and the Incorporation of CO2. The Journal of Physical Chemistry C 2013, 117 (40) , 20592-20609. https://doi.org/10.1021/jp405321t
    43. Evgeniy M. Myshakin, Wissam A. Saidi, Vyacheslav N. Romanov, Randall T. Cygan, and Kenneth D. Jordan . Molecular Dynamics Simulations of Carbon Dioxide Intercalation in Hydrated Na-Montmorillonite. The Journal of Physical Chemistry C 2013, 117 (21) , 11028-11039. https://doi.org/10.1021/jp312589s
    44. Gernot Rother, Eugene S. Ilton, Dirk Wallacher, Thomas Hauβ, Herbert T. Schaef, Odeta Qafoku, Kevin M. Rosso, Andrew R. Felmy, Elizabeth G. Krukowski, Andrew G. Stack, Nico Grimm, and Robert J. Bodnar . CO2 Sorption to Subsingle Hydration Layer Montmorillonite Clay Studied by Excess Sorption and Neutron Diffraction Measurements. Environmental Science & Technology 2013, 47 (1) , 205-211. https://doi.org/10.1021/es301382y
    45. Vassiliki-Alexandra Glezakou B. Peter McGrail . Density Functional Simulations as a Tool To Probe Molecular Interactions in Wet Supercritical CO2. 2013, 31-49. https://doi.org/10.1021/bk-2013-1133.ch003
    46. Yandi Hu and Young-Shin Jun . Biotite Dissolution in Brine at Varied Temperatures and CO2 Pressures: Its Activation Energy and Potential CO2 Intercalation. Langmuir 2012, 28 (41) , 14633-14641. https://doi.org/10.1021/la3028995
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    48. Anton Kasprzhitskii, Georgy Lazorenko. Effect of surface cations on the CO2 capture performance of montmorillonite. Solid State Communications 2025, 397 , 115785. https://doi.org/10.1016/j.ssc.2024.115785
    49. Salim Ok, Julia M. Sheets, Susan A. Welch, David R. Cole. Methane–Natural Clay Interfacial Interactions as Revealed by High-Pressure Magic Angle Spinning (MAS) Nuclear Magnetic Resonance (NMR) Spectroscopy. Fuels 2025, 6 (1) , 16. https://doi.org/10.3390/fuels6010016
    50. Yichen Wang, Ziwei Ding, Zhou Cao, Fangchun Han, Yang Wang, Hongfei Cheng. Molecular simulation of CO2 adsorption on kaolinite: Insights into geological storage of CO2. Applied Clay Science 2024, 258 , 107495. https://doi.org/10.1016/j.clay.2024.107495
    51. Maram Almolliyeh, Snehasis Tripathy, Sivachidambaram Sadasivam, Shakil Masum, Sara Edwards Rassner, Andy Mitchell, Hywel Rhys Thomas. Subcritical CO2 adsorption on geomaterials of coal-bearing strata in the context of geological carbon sequestration. International Journal of Coal Geology 2023, 277 , 104340. https://doi.org/10.1016/j.coal.2023.104340
    52. M. Zhang, C. J. Spiers, S. J. T. Hangx. Effect of CO2-H2O-Smectite Interactions on Permeability of Clay-Rich Rocks Under CO2 Storage Conditions. Rock Mechanics and Rock Engineering 2023, 56 (5) , 3451-3474. https://doi.org/10.1007/s00603-023-03259-6
    53. Manju Pharkavi Murugesu, Nerine Joewondo, Manika Prasad. Carbon storage capacity of shale formations: Mineral control on CO 2 adsorption. International Journal of Greenhouse Gas Control 2023, 124 , 103833. https://doi.org/10.1016/j.ijggc.2023.103833
    54. Denys I. Grekov, Jean-Charles Robinet, Bernd Grambow. Adsorption of methane and carbon dioxide by water-saturated clay minerals and clay rocks. Applied Clay Science 2023, 232 , 106806. https://doi.org/10.1016/j.clay.2022.106806
    55. Santanu Ghosh, Tushar Adsul, Atul Kumar Varma. Organic matter and mineralogical acumens in CO2 sequestration. 2023, 561-594. https://doi.org/10.1016/B978-0-323-99429-3.00016-3
    56. Ryan T. Grimes, Joseph W. Bennett. Surface transformation thermodynamics of alkaline earth carbonates using first-principles calculations. Surface Science 2022, 726 , 122165. https://doi.org/10.1016/j.susc.2022.122165
    57. Nina Zeyen, Baolin Wang, Sasha Wilson, Carlos Paulo, Amanda R. Stubbs, Ian M. Power, Matthew Steele-Maclnnis, Antonio Lanzirotti, Matthew Newville, David J. Paterson, Jessica L. Hamilton, Thomas R. Jones, Connor C. Turvey, Gregory M. Dipple, Gordon Southam. Cation Exchange in Smectites as a New Approach to Mineral Carbonation. Frontiers in Climate 2022, 4 https://doi.org/10.3389/fclim.2022.913632
    58. Miao Zhang, Christopher James Spiers, Jinfeng Liu, Hongwei Zhou. Stress-Strain-Sorption Behaviour of Smectites Upon Exposure to Dry and Wet CO2. Frontiers in Earth Science 2022, 10 https://doi.org/10.3389/feart.2022.911247
    59. Carlos Paulo, Ian M. Power, Amanda R. Stubbs, Baolin Wang, Nina Zeyen, Sasha Wilson. Evaluating feedstocks for carbon dioxide removal by enhanced rock weathering and CO2 mineralization. Applied Geochemistry 2021, 129 , 104955. https://doi.org/10.1016/j.apgeochem.2021.104955
    60. Redouane Haounati, Hassan Ouachtak, Rachid El Haouti, Siham Akhouairi, Fadwa Largo, Feryal Akbal, Abdeljalil Benlhachemi, Amane Jada, Abdelaziz Ait Addi. Elaboration and properties of a new SDS/CTAB@Montmorillonite organoclay composite as a superb adsorbent for the removal of malachite green from aqueous solutions. Separation and Purification Technology 2021, 255 , 117335. https://doi.org/10.1016/j.seppur.2020.117335
    61. Denys I. Grekov, Tomo Suzuki-Muresan, Andrey G. Kalinichev, Pascaline Pré, Bernd Grambow. Thermodynamic data of adsorption reveal the entry of CH 4 and CO 2 in a smectite clay interlayer. Physical Chemistry Chemical Physics 2020, 22 (29) , 16727-16733. https://doi.org/10.1039/D0CP02135K
    62. Brennan L. Kessenich, Nihit Pokhrel, Elias Nakouzi, Christina J. Newcomb, Markus Flury, Lutz Maibaum, James J. De Yoreo. Connecting wettability, topography, and chemistry in a simple lipid-montmorillonite system. Journal of Colloid and Interface Science 2019, 555 , 498-508. https://doi.org/10.1016/j.jcis.2019.07.075
    63. Nesrine Chouikhi, Juan Antonio Cecilia, Enrique Vilarrasa-García, Sabrine Besghaier, Mohamed Chlendi, Francisco Ignacio Franco Duro, Enrique Rodriguez Castellon, Mohamed Bagane. CO2 Adsorption of Materials Synthesized from Clay Minerals: A Review. Minerals 2019, 9 (9) , 514. https://doi.org/10.3390/min9090514
    64. Ange‐Therese Akono, Jennifer L. Druhan, Gabriela Dávila, Theodore Tsotsis, Kristian Jessen, Samantha Fuchs, Dustin Crandall, Zhuofan Shi, Laura Dalton, Mary K. Tkach, Angela L. Goodman, Scott Frailey, Charles J. Werth. A review of geochemical–mechanical impacts in geological carbon storage reservoirs. Greenhouse Gases: Science and Technology 2019, 9 (3) , 474-504. https://doi.org/10.1002/ghg.1870
    65. Sahar Bakhshian, Seyyed A. Hosseini. Prediction of CO2 adsorption-induced deformation in shale nanopores. Fuel 2019, 241 , 767-776. https://doi.org/10.1016/j.fuel.2018.12.095
    66. Narasimhan Loganathan, Geoffrey M. Bowers, Brice F. Ngouana Wakou, Andrey G. Kalinichev, R. James Kirkpatrick, A. Ozgur Yazaydin. Understanding methane/carbon dioxide partitioning in clay nano- and meso-pores with constant reservoir composition molecular dynamics modeling. Physical Chemistry Chemical Physics 2019, 21 (13) , 6917-6924. https://doi.org/10.1039/C9CP00851A
    67. Xiaofeng Chen, Peter Eichhubl, Jon E. Olson, Thomas A. Dewers. Effect of Water on Fracture Mechanical Properties of Shales. Journal of Geophysical Research: Solid Earth 2019, 124 (3) , 2428-2444. https://doi.org/10.1029/2018JB016479
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    69. Merve Yeşilbaş, Michael Holmboe, Jean-François Boily. Residence times of nanoconfined CO 2 in layered aluminosilicates. Environmental Science: Nano 2019, 6 (1) , 146-151. https://doi.org/10.1039/C8EN01156G
    70. John S. Loring, Quin R.S. Miller, Chris J. Thompson, H. Todd Schaef. Experimental Studies of Reactivity and Transformations of Rocks and Minerals in Water-Bearing Supercritical CO2. 2019, 63-88. https://doi.org/10.1016/B978-0-12-812752-0.00004-6
    71. Anastasia G. Ilgen, Pania Newell, Tomasz Hueckel, D. Nicolas Espinoza, Manman Hu. Coupled Chemical-Mechanical Processes Associated With the Injection of CO2 into Subsurface. 2019, 337-359. https://doi.org/10.1016/B978-0-12-812752-0.00015-0
    72. J. Hwang, L. Joss, R. Pini. Measuring and modelling supercritical adsorption of CO2 and CH4 on montmorillonite source clay. Microporous and Mesoporous Materials 2019, 273 , 107-121. https://doi.org/10.1016/j.micromeso.2018.06.050
    73. Evelyn M. Mervine, Sasha Wilson, Ian M. Power, Gregory M. Dipple, Connor C. Turvey, Jessica L. Hamilton, Sterling Vanderzee, Mati Raudsepp, Colette Southam, Juerg M. Matter, Peter B. Kelemen, Johann Stiefenhofer, Zandile Miya, Gordon Southam. Potential for offsetting diamond mine carbon emissions through mineral carbonation of processed kimberlite: an assessment of De Beers mine sites in South Africa and Canada. Mineralogy and Petrology 2018, 112 (S2) , 755-765. https://doi.org/10.1007/s00710-018-0589-4
    74. Zijing Li, Jilong Guo, Zhao Dong, Jiawei Chen. Insight into interactions of olivine-scCO2-water system at 140 °C and 15 MPa during CO2 mineral sequestration. Geoscience Frontiers 2018, 9 (6) , 1945-1955. https://doi.org/10.1016/j.gsf.2017.12.008
    75. A.G. Ilgen, M. Aman, D.N. Espinoza, M.A. Rodriguez, J.M. Griego, T.A. Dewers, J.D. Feldman, T.A. Stewart, R.C. Choens, J. Wilson. Shale-brine-CO2 interactions and the long-term stability of carbonate-rich shale caprock. International Journal of Greenhouse Gas Control 2018, 78 , 244-253. https://doi.org/10.1016/j.ijggc.2018.07.002
    76. Marie-Paule Bassez. Water near its Supercritical Point and at Alkaline pH for the Production of Ferric Oxides and Silicates in Anoxic Conditions. A New Hypothesis for the Synthesis of Minerals Observed in Banded Iron Formations and for the Related Geobiotropic Chemistry inside Fluid Inclusions. Origins of Life and Evolution of Biospheres 2018, 48 (3) , 289-320. https://doi.org/10.1007/s11084-018-9560-y
    77. Sean Sanguinito, Angela Goodman, Mary Tkach, Barbara Kutchko, Jeffrey Culp, Sittichai Natesakhawat, Jim Fazio, Isis Fukai, Dustin Crandall. Quantifying dry supercritical CO2-induced changes of the Utica Shale. Fuel 2018, 226 , 54-64. https://doi.org/10.1016/j.fuel.2018.03.156
    78. M. Pilavtepe, L. Delavernhe, A. Steudel, R. Schumann, N. Willenbacher, K. Emmerich. Formation of Arrested States in Natural Di- and Trioctahedral Smectite Dispersions Compared to Those in Synthetic Hectorite — A Macro- and Microrheological Study. Clays and Clay Minerals 2018, 66 (4) , 339-352. https://doi.org/10.1346/CCMN.2018.064102
    79. Greeshma Gadikota1, Andrew Allen. Microstructural and Structural Characterization of Materials for CO 2 Storage Using Multi‐Scale X‐Ray Scattering Methods. 2018, 296-318. https://doi.org/10.1002/9781119231059.ch7
    80. M. Zhang, S.M. de Jong, C.J. Spiers, A. Busch, H.M. Wentinck. Swelling stress development in confined smectite clays through exposure to CO2. International Journal of Greenhouse Gas Control 2018, 74 , 49-61. https://doi.org/10.1016/j.ijggc.2018.04.014
    81. Julie K. Pearce, Grant K. W. Dawson. Experimental Determination of Impure CO2 Alteration of Calcite Cemented Cap-Rock, and Long Term Predictions of Cap-Rock Reactivity. Geosciences 2018, 8 (7) , 241. https://doi.org/10.3390/geosciences8070241
    82. Haixiang Hu, Yanfei Xing, Xiaochun Li. Molecular modeling on transportation of CO 2 in montmorillonite: Diffusion and permeation. Applied Clay Science 2018, 156 , 20-27. https://doi.org/10.1016/j.clay.2018.01.019
    83. Francesco Tavanti, Francesco Muniz-Miranda, Alfonso Pedone. The Effect of Alkaline Cations on the Intercalation of Carbon Dioxide in Sepiolite Minerals: A Molecular Dynamics Investigation. Frontiers in Materials 2018, 5 https://doi.org/10.3389/fmats.2018.00012
    84. Jiamin Wan, Tetsu K. Tokunaga, Paul D. Ashby, Yongman Kim, Marco Voltolini, Benjamin Gilbert, Donald J. DePaolo. Supercritical CO 2 uptake by nonswelling phyllosilicates. Proceedings of the National Academy of Sciences 2018, 115 (5) , 873-878. https://doi.org/10.1073/pnas.1710853114
    85. Vyacheslav Romanov. Advanced Experimental Techniques in Geochemistry. 2018, 77-94. https://doi.org/10.1007/978-3-319-12661-6_5
    86. Lei Hong, Vyacheslav Romanov. Experimental Studies: Molecular Interactions at Clay Interfaces. 2018, 95-123. https://doi.org/10.1007/978-3-319-12661-6_6
    87. Vyacheslav Romanov, Evgeniy M. Myshakin. Experimental Studies: Clay Swelling. 2018, 125-145. https://doi.org/10.1007/978-3-319-12661-6_7
    88. Nicholas R. Jaegers, Mary Y. Hu, David W. Hoyt, Yong Wang, Jian Zhi Hu. Development and Application of In Situ High-Temperature, High-Pressure Magic Angle Spinning NMR. 2018, 1073-1091. https://doi.org/10.1007/978-3-319-28388-3_93
    89. Haixiang Hu, Yanfei Xing, Xiaochun Li. Self-diffusivity, M–S and Fick diffusivity of CO2 in Na-clay: The influences of concentration and temperature. Scientific Reports 2017, 7 (1) https://doi.org/10.1038/s41598-017-05758-3
    90. Tuan Anh Ho, Jeffery A. Greathouse, Yifeng Wang, Louise J. Criscenti. Atomistic Structure of Mineral Nano-aggregates from Simulated Compaction and Dewatering. Scientific Reports 2017, 7 (1) https://doi.org/10.1038/s41598-017-15639-4
    91. Eszter Sendula, Mariann Páles, Barbara Péter Szabó, Beatrix Udvardi, István Kovács, Péter Kónya, Ágnes Freiler, Anikó Besnyi, Csilla Király, Edit Székely, Csaba Szabó, György Falus. Experimental Study of CO2-saturated Water – Illite/Kaolinite/Montmorillonite System at 70-80 °C, 100-105 Bar. Energy Procedia 2017, 114 , 4934-4947. https://doi.org/10.1016/j.egypro.2017.03.1635
    92. Sahar Bakhshian, Muhammad Sahimi. Adsorption-induced swelling of porous media. International Journal of Greenhouse Gas Control 2017, 57 , 1-13. https://doi.org/10.1016/j.ijggc.2016.12.011
    93. Nicholas R. Jaegers, Mary Y. Hu, David W. Hoyt, Yong Wang, Jian Zhi Hu. Development and Application of In Situ High-Temperature, High-Pressure Magic Angle Spinning NMR. 2017, 1-19. https://doi.org/10.1007/978-3-319-28275-6_93-1
    94. Tomohiko Okada, Makoto Ogawa. Adsorbents Derived from Layered Solids. 2017, 263-301. https://doi.org/10.1007/978-4-431-56496-6_9
    95. G.P.D. De Silva, P.G. Ranjith, M.S.A. Perera, Z.X. Dai, S.Q. Yang. An experimental evaluation of unique CO2 flow behaviour in loosely held fine particles rich sandstone under deep reservoir conditions and influencing factors. Energy 2017, 119 , 121-137. https://doi.org/10.1016/j.energy.2016.11.144
    96. Hendrik M. Wentinck, Andreas Busch. Modelling of CO 2 diffusion and related poro-elastic effects in a smectite-rich cap rock above a reservoir used for CO 2 storage. Geological Society, London, Special Publications 2017, 454 (1) , 155-173. https://doi.org/10.1144/SP454.4
    97. William Taifan, Jean-François Boily, Jonas Baltrusaitis. Surface chemistry of carbon dioxide revisited. Surface Science Reports 2016, 71 (4) , 595-671. https://doi.org/10.1016/j.surfrep.2016.09.001
    98. Quin R.S. Miller, Xiuyu Wang, John P. Kaszuba, Katherine M. Mouzakis, Alexis K. Navarre-Sitchler, Vladimir Alvarado, John E. McCray, Gernot Rother, José Leobardo Bañuelos, Jason E. Heath. Experimental Study of Porosity Changes in Shale Caprocks Exposed to Carbon Dioxide-Saturated Brine II: Insights from Aqueous Geochemistry. Environmental Engineering Science 2016, 33 (10) , 736-744. https://doi.org/10.1089/ees.2015.0592
    99. Julie K. Pearce, Grant K.W. Dawson, Alison C.K. Law, Dean Biddle, Suzanne D. Golding. Reactivity of micas and cap-rock in wet supercritical CO2 with SO2 and O2 at CO2 storage conditions. Applied Geochemistry 2016, 72 , 59-76. https://doi.org/10.1016/j.apgeochem.2016.06.010
    100. Greg A. Mutch, James A. Anderson, Rebecca Walker, Giuseppina Cerrato, Sara Morandi, Lorenza Operti, David Vega-Maza. In-situ infrared spectroscopy as a non-invasive technique to study carbon sequestration at high pressure and high temperature. International Journal of Greenhouse Gas Control 2016, 51 , 126-135. https://doi.org/10.1016/j.ijggc.2016.05.012
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    Cite this: Langmuir 2012, 28, 18, 7125–7128
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