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Layer-by-Layer Assembly of Thin Films Containing Exfoliated Pristine Graphene Nanosheets and Polyethyleneimine

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Department of Applied Mathematics, Research School of Physics and Engineering, Australian National University, Canberra, Australian Capital Territory 0200, Australia
Faculty of Life and Social Sciences, Swinburne University of Technology, Hawthorn, Victoria 3122, Australia
*Telephone: +61-392148635. E-mail: [email protected]
Cite this: Langmuir 2014, 30, 9, 2410–2418
Publication Date (Web):February 16, 2014
https://doi.org/10.1021/la404745b
Copyright © 2014 American Chemical Society
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Abstract

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A method for the modification of surface properties through the deposition of stabilized graphene nanosheets is described. Here, the thickness of the film is controlled through the use of the layer-by-layer technique, where the sequential adsorption of the cationic polyethyleneimine (PEI) is followed by the adsorption of anionic graphene sheets modified with layers of polyethylene oxide–polypropylene oxide–polyethylene oxide (PEO–PPO–PEO) surfactants. The graphene particles were prepared using the surfactant-assisted liquid-phase exfoliation technique, with the low residual negative charge arising from edge defects. The buildup of the multilayer assembly through electrostatic interactions was strongly influenced by the solution conditions, including pH, ionic strength, and ionic species. Thereby, not only could the thickness of the film be tailored through the choice of the number of bilayers deposited but the viscoelastic properties of the film could also be modified by changing solution conditions at which the different species were deposited. The quartz crystal microbalance was used to measure the mass of graphene and polyelectrolyte immobilized at the interface as well as to probe the energy dissipated in the adsorbed layer.

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Characterization data of graphene particles, including UV–vis spectra, Raman spectra, and lateral size dimensions. This material is available free of charge via the Internet at http://pubs.acs.org.

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This article is cited by 22 publications.

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  14. Fangming Xiang, Dorsa Parviz, Tara M. Givens, Ping Tzeng, Eric M. Davis, Christopher M. Stafford, Micah J. Green, Jaime C. Grunlan. Stiff and Transparent Multilayer Thin Films Prepared Through Hydrogen-Bonding Layer-by-Layer Assembly of Graphene and Polymer. Advanced Functional Materials 2016, 26 (13) , 2143-2149. https://doi.org/10.1002/adfm.201504758
  15. Haifeng Pan, Bihao Yu, Wei Wang, Ying Pan, Lei Song, Yuan Hu. Comparative study of layer by layer assembled multilayer films based on graphene oxide and reduced graphene oxide on flexible polyurethane foam: flame retardant and smoke suppression properties. RSC Advances 2016, 6 (115) , 114304-114312. https://doi.org/10.1039/C6RA15522G
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  19. Alison Y.W. Sham, Shannon M. Notley. Graphene–polyelectrolyte multilayer film formation driven by hydrogen bonding. Journal of Colloid and Interface Science 2015, 456 , 32-41. https://doi.org/10.1016/j.jcis.2015.05.035
  20. Yanhong Wu, Rui Cao, Liangliang Ji, Weichun Huang, Xiaoming Yang, Yingfeng Tu. Synergistic toughening of bioinspired artificial nacre by polystyrene grafted graphene oxide. RSC Advances 2015, 5 (36) , 28085-28091. https://doi.org/10.1039/C5RA03074A
  21. João Borges, Luísa C. Rodrigues, Rui L. Reis, João F. Mano. Layer-by-Layer Assembly of Light-Responsive Polymeric Multilayer Systems. Advanced Functional Materials 2014, 24 (36) , 5624-5648. https://doi.org/10.1002/adfm.201401050
  22. Shannon M. Notley, Drew R. Evans. Aqueous processing of graphene–polymer hybrid thin film nano-composites and gels. Advances in Colloid and Interface Science 2014, 209 , 196-203. https://doi.org/10.1016/j.cis.2014.04.006

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