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Synthesis of Birnessite Structure Layers at the Solution–Air Interface and the Formation of Microtubules from Them

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    Synthesis of Birnessite Structure Layers at the Solution–Air Interface and the Formation of Microtubules from Them
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    Institute of Chemistry, St. Petersburg State University, Universitetskiy pr. 26 St. Peterhof, St. Petersburg, Russia 198504
    *E-mail: [email protected], [email protected]
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    Langmuir

    Cite this: Langmuir 2014, 30, 28, 8366–8372
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    https://doi.org/10.1021/la501204k
    Published June 26, 2014
    Copyright © 2014 American Chemical Society
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    Abstract

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    HxMnO2·nH2O layers have been successfully produced through a facile low-temperature process at the solution–air interface without using any templates. The crystalline structures of layers can be tuned by the compositions and the pH of the growth solutions. The analysis of birnessite-like layers indicates that they are formed by nanosheets approximately 4–6 nm thick that are oriented for the most part normally to the interface. Our results demonstrated that 1–3-μm-thick layers can roll up into microtubules 20 to 100 μm in diameter and up to 10 mm long. The hypothesis explaining the formation of the microtubular structures is assumed.

    Copyright © 2014 American Chemical Society

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    Supporting Information

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    A video of the process of formation of the tubular structures from the birnessite structure layer. The playback speed of the video is set at a 3-fold slower value. The process was recorded at 50× magnification. Diagram of states of manganese ions in Mn(CH3COO)2 solution with no admixture of CH3COONa. XRD nanosheets of the samples obtained from solutions of MnCl2, MnSO4, and Mn(NO3)2. XPS spectrum of an HxMnO2·nH2O sample synthesized from Mn(CH3COO)2 + CH3COONa solutions. SEM images of HxMnO2·nH2O samples. EPMA results. This material is available free of charge via the Internet at http://pubs.acs.org.

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    This article is cited by 33 publications.

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    Langmuir

    Cite this: Langmuir 2014, 30, 28, 8366–8372
    Click to copy citationCitation copied!
    https://doi.org/10.1021/la501204k
    Published June 26, 2014
    Copyright © 2014 American Chemical Society
    Request reuse permissions

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