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Tunable Synthesis of Prussian Blue in Exponentially Growing Polyelectrolyte Multilayer Films†

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‡ Centre National de la Recherche Scientifique, Unité Propre de Recherche 22, Institut Charles Sadron, 23 rue du Loess, BP 84047, 67034 Strasbourg Cedex 2, France
Institut National de la Santé et de la Recherche Médicale, Unité 977, 11 rue Humann, 67085 Strasbourg Cedex, France
§ Université de Strasbourg, Faculté de Chirurgie Dentaire, 1 Place de l’Hôpital, 67000 Strasbourg, France
∥ Centre National de la Recherche Scientifique - Université de Strasbourg, Unité Mixte de Recherche 7504, Institut de Physique et Chimie des Matériaux de Strasbourg, 23 rue du Loess, BP 43, 67034 Strasbourg Cedex 2, France
*Corresponding author. Phone: +33 (0)3 90 24 32 58; fax: +33 (0)3 90 24 33 79; e-mail: [email protected] (V.B.). Phone: +33 (0)3 88 41 40 12; e-mail: [email protected] (P.S.).
Cite this: Langmuir 2009, 25, 24, 14030–14036
Publication Date (Web):August 13, 2009
https://doi.org/10.1021/la901479z
Copyright © 2009 American Chemical Society
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Abstract

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Polyelectrolyte multilayer (PEM) films have become very popular for surface functionalization and the design of functional architectures such as hollow polyelectrolyte capsules. It is known that properties such as permeability to small ionic solutes are strongly dependent on the buildup regime of the PEM films. This permeability can be modified by tuning the ionization degree of the polycations or polyanions, provided the film is made from weak polyelectrolytes. In most previous investigations, this was achieved by playing on the solution pH either during the film buildup or by a postbuildup pH modification. Herein we investigate the functionalization of poly(allylamine hydrochloride)/poly(glutamic acid) (PAH/PGA) multilayers by ferrocyanide and Prussian Blue (PB). We demonstrate that dynamic exchange processes between the film and polyelectrolyte solutions containing one of the component polyelectrolyte allow one to modify its Donnan potential and, as a consequence, the amount of ferrocyanide anions able to be retained in the PAH/PGA film. This ability of the film to be a tunable reservoir of ferrocyanide anions is then used to produce a composite film containing PB particles obtained by a single precipitation reaction with a solution containing Fe3+ cations in contact with the film. The presence of PB in the PEM films then provides magnetic as well as electrochemical properties to the whole architecture.

Part of the “Langmuir 25th Year: Self-assembled polyelectrolyte multilayers: structure and function” special issue.

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Evolution of the oxidation and reduction charge of FCIV-filled MPS−(PAH/PGA)10 films depending on the number of measurement cycles and the duration of the rest time between successive scanning cycles, the influence of the post-treatment of a PEI−(PGA/PAH)10 film with PGA or PAH solutions on its ATR-FTIR spectrum, and CV and ATR-FTIR spectrum of PEM films containing PB. Evaluation of the number of available amino groups in an MPS−(PAH/PGA)10 film. This material is available free of charge via the Internet at http://pubs.acs.org.

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This article is cited by 31 publications.

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  2. Eduardo Guzmán, Jesica A. Cavallo, Raquel Chuliá-Jordán, César Gómez, Miriam C. Strumia, Francisco Ortega, and Ramón G. Rubio . pH-Induced Changes in the Fabrication of Multilayers of Poly(acrylic acid) and Chitosan: Fabrication, Properties, and Tests as a Drug Storage and Delivery System. Langmuir 2011, 27 (11) , 6836-6845. https://doi.org/10.1021/la200522r
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  5. Raphael Zahn, Fouzia Boulmedais, János Vörös, Pierre Schaaf and Tomaso Zambelli . Ion and Solvent Exchange Processes in PGA/PAH Polyelectrolyte Multilayers Containing Ferrocyanide. The Journal of Physical Chemistry B 2010, 114 (11) , 3759-3768. https://doi.org/10.1021/jp9106074
  6. Yuancai Ge, Pei Dong, Steven R. Craig, Pulickel M. Ajayan, Mingxin Ye, Jianfeng Shen. Transforming Nickel Hydroxide into 3D Prussian Blue Analogue Array to Obtain Ni 2 P/Fe 2 P for Efficient Hydrogen Evolution Reaction. Advanced Energy Materials 2018, 8 (21) , 1800484. https://doi.org/10.1002/aenm.201800484
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  8. S.N. Rao. Adsorption. 2018, 251-331. https://doi.org/10.1016/B978-0-12-801970-2.00005-7
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  10. C. Ringwald, V. Ball. Step-by-step deposition of type B gelatin and tannic acid displays a peculiar ionic strength dependence at pH 5. RSC Advances 2016, 6 (6) , 4730-4738. https://doi.org/10.1039/C5RA24337H
  11. Ball Vincent. Permeabilty of silver cations through (PAH–PSS)m polyelectrolyte multilayer films to deposit silver in underlying (PAH–tannic acid)n film without external reducing agent at pH 5.0. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2015, 484 , 70-74. https://doi.org/10.1016/j.colsurfa.2015.07.049
  12. Vincent Ball. Phase Diagram of Sodium Hexametaphosphate and Poly(allylamine hydrochloride) Mixtures and In Situ Monitoring of Step-by-Step Deposition in This Polyelectrolyte System. Macromolecular Chemistry and Physics 2015, 216 (1) , 85-94. https://doi.org/10.1002/macp.201400392
  13. Felix A. Plamper. Changing Polymer Solvation by Electrochemical Means: Basics and Applications. 2014, 125-212. https://doi.org/10.1007/12_2014_284
  14. Vincent Ball. Donnan potential of polyelectrolyte multilayer films made from poly-l-glutamic/polyallylamine hydrochloride and the stability of hexacyanoferrate retained in the films. Physical Chemistry Chemical Physics 2013, 15 (38) , 16249. https://doi.org/10.1039/c3cp52476k
  15. E. Guzmán, M. Ruano, R.G. Rubio, F. Ortega. Polyelectrolyte assemblies for drug storage and delivery: multilayers, nanocapsules and multicapsules. 2013, 94-145. https://doi.org/10.1533/9780857098696.2.94
  16. Vincent Ball. Organic and Inorganic Dyes in Polyelectrolyte Multilayer Films. Materials 2012, 5 (12) , 2681-2704. https://doi.org/10.3390/ma5122681
  17. Andre G. Skirtach, Dmitry V. Volodkin, Helmuth Möhwald. Remote and Self‐Induced Release from Polyelectrolyte Multilayer Capsules and Films. 2012, 925-950. https://doi.org/10.1002/9783527646746.ch39
  18. Ernesto. J. Calvo. Electrochemically Active LbL Multilayer Films: From Biosensors to Nanocatalysts. 2012, 1003-1038. https://doi.org/10.1002/9783527646746.ch42
  19. Marc Michel, Vincent Ball. Diffusion of Nanoparticles and Biomolecules into Polyelectrolyte Multilayer Films: Towards New Functional Materials. 2012, 691-710. https://doi.org/10.1002/9783527646746.ch28
  20. Raphael Zahn, Géraldine Coullerez, János Vörös, Tomaso Zambelli. Effect of polyelectrolyte interdiffusion on electron transport in redox-active polyelectrolyte multilayers. Journal of Materials Chemistry 2012, 22 (22) , 11073. https://doi.org/10.1039/c2jm30469d
  21. Qinglin Sheng, Ruixiao Liu, Jianbin Zheng. Prussian blue nanospheres synthesized in deep eutectic solvents. Nanoscale 2012, 4 (21) , 6880. https://doi.org/10.1039/c2nr31830j
  22. Julien Petersen, Marc Michel, Valérie Toniazzo, David Ruch, Guy Schmerber, Dris Ihiawakrim, Dominique Muller, Aziz Dinia, Vincent Ball. Atmospheric plasma polymer films as templates for inorganic synthesis to yield functional hybrid coatings. RSC Advances 2012, 2 (26) , 9860. https://doi.org/10.1039/c2ra21028b
  23. Mihaela Delcea, Helmuth Möhwald, André G. Skirtach. Stimuli-responsive LbL capsules and nanoshells for drug delivery. Advanced Drug Delivery Reviews 2011, 63 (9) , 730-747. https://doi.org/10.1016/j.addr.2011.03.010
  24. Eduardo Guzmán, Hernán Ritacco, Francisco Ortega, Ramón G. Rubio. Evidence of the influence of adsorption kinetics on the internal reorganization of polyelectrolyte multilayers. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2011, 384 (1-3) , 274-281. https://doi.org/10.1016/j.colsurfa.2011.04.005
  25. Philippe Lavalle, Jean-Claude Voegel, Dominique Vautier, Bernard Senger, Pierre Schaaf, Vincent Ball. Dynamic Aspects of Films Prepared by a Sequential Deposition of Species: Perspectives for Smart and Responsive Materials. Advanced Materials 2011, 23 (10) , 1191-1221. https://doi.org/10.1002/adma.201003309
  26. Wei Qi, Li Duan, Junbai Li. Fabrication of glucose-sensitive protein microcapsules and their applications. Soft Matter 2011, 7 (5) , 1571-1576. https://doi.org/10.1039/C0SM00627K
  27. Cosette Betscha, Vincent Ball. Large distribution in the Donnan potential of hexacyanoferrate anions permeating in and partially dissolving (PAH-HA)n polyelectrolyte multilayer films. Soft Matter 2011, 7 (5) , 1819. https://doi.org/10.1039/c0sm00889c
  28. Eduardo Guzmán, Raquel Chuliá-Jordán, Francisco Ortega, Ramón G. Rubio. Influence of the percentage of acetylation on the assembly of LbL multilayers of poly(acrylic acid) and chitosan. Physical Chemistry Chemical Physics 2011, 13 (40) , 18200. https://doi.org/10.1039/c1cp21609k
  29. Raphael Zahn, János Vörös, Tomaso Zambelli. Swelling of electrochemically active polyelectrolyte multilayers. Current Opinion in Colloid & Interface Science 2010, 15 (6) , 427-434. https://doi.org/10.1016/j.cocis.2010.07.006
  30. Riadh Zouari, Marc Michel, Jean Di Martino, Vincent Ball. Production of free standing composite membranes or of patterned films after sol–gel reactions in an exponential layer-by-layer architecture. Materials Science and Engineering: C 2010, 30 (8) , 1291-1297. https://doi.org/10.1016/j.msec.2010.07.017
  31. Mario Tagliazucchi, Federico J. Williams, Ernesto J. Calvo. Metal-ion responsive redox polyelectrolyte multilayers. Chemical Communications 2010, 46 (47) , 9004. https://doi.org/10.1039/c0cc02738c

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