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Photoassisted Degradation (in the UV) of Phenyltin(IV) Chlorides in the Presence of Titanium Dioxide

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    Research Article

    Photoassisted Degradation (in the UV) of Phenyltin(IV) Chlorides in the Presence of Titanium Dioxide
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    Instituto de Ciencia de Materiales de Sevilla, Centro de Investigaciones Científicas “Isla de la Cartuja”, c/Américo Vespucio, s/n, Isla de la cartuja, 41092 Sevilla, Spain, Dpto. De Química Orgánica, Facultad de Química, Universidad de Sevilla, 41012-Sevilla, Spain, and Dpto. De Química y Ciencia de los Materiales, Escuela Politécnica Superior, Universidad de Huelva, Campus de la Rábida, Huelva, Spain
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    Langmuir

    Cite this: Langmuir 1998, 14, 2, 388–395
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    https://doi.org/10.1021/la970318d
    Published January 20, 1998
    Copyright © 1998 American Chemical Society
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    Abstract

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    The photoassisted degradation of phenyltin(IV) chlorides in air-equilibrated aqueous TiO2 suspension has been studied. The stability of the triphenyltin(IV) derivative in aqueous solutions at different pH values and the extent of adsorption of tri- and diphenyltin(IV) chloride species were examined. Particular interest is focused on the TiO2-assisted photodegradation of phenyltin species. Detailed surface analyses of the catalyst particles by IR and of the liquid medium by GC-MS are reported. A mechanism consisting of interfacial trapping of a photogenerated electron−hole pair can explain the TiO2-photoassisted degradation of phenyltin species. The results are compared with those previously reported on the photolytic degradation of theses species in water and with those of n-butyltin species (photolytic and TiO2-photoassisted). Our results allow that this is not a photocatalysis system but a photoassisted one in the presence of TiO2.

    Copyright © 1998 American Chemical Society

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    *

     Corresponding author.

    †

     Instituto de Ciencia de Materiales de Sevilla.

    ‡

     Universidad de Sevilla.

    §

     Escuela Politécnica Superior.

    ✗

     Abstract published in Advance ACS Abstracts, December 1, 1997.

    Cited By

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    This article is cited by 21 publications.

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    19. Gilles Mailhot, Nathalie Brand, Michel Astruc, Michele Bolte. Photoinduced degradation by iron(III): removal of triphenyltin chloride from water. Applied Organometallic Chemistry 2002, 16 (1) , 27-33. https://doi.org/10.1002/aoc.256
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    21. . Solar Water Detoxification. Current Status and Perspectives. Zeitschrift für Physikalische Chemie 1998, 1 (1) , 217-228. https://doi.org/10.1524/zpch.1998.1.1.217
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    Langmuir

    Cite this: Langmuir 1998, 14, 2, 388–395
    Click to copy citationCitation copied!
    https://doi.org/10.1021/la970318d
    Published January 20, 1998
    Copyright © 1998 American Chemical Society
    Request reuse permissions

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