ACS Publications. Most Trusted. Most Cited. Most Read
Synthesis of Supported Transition Metal Oxide Catalysts by the Designed Deposition of Acetylacetonate Complexes
My Activity
    Research Article

    Synthesis of Supported Transition Metal Oxide Catalysts by the Designed Deposition of Acetylacetonate Complexes
    Click to copy article linkArticle link copied!

    View Author Information
    Laboratory of Adsorption and Catalysis, Department of Chemistry, University of Antwerpen (U.I.A.), Universiteitsplein 1, B-2610 Wilrijk, Belgium
    Other Access Options

    Langmuir

    Cite this: Langmuir 1999, 15, 18, 5841–5845
    Click to copy citationCitation copied!
    https://doi.org/10.1021/la981362b
    Published March 25, 1999
    Copyright © 1999 American Chemical Society

    Abstract

    Click to copy section linkSection link copied!

    The molecular designed dispersion method is used to prepare supported transition metal oxide catalysts (Mo, Cu, V). The corresponding transition metal acetylacetonate complexes were reacted with silica or alumina, and subsequently thermally converted into the supported metal oxide. The deposition of these acetylacetonate complexes depends on the geometry and stability of the complex, the support properties and the synthesis procedure. By thorough control of the reaction parameters, this novel synthesis method enables the creation of uniform and highly dispersed supported transition metal oxides. Therefore, the molecular designed dispersion method plays an important role in the development of a new generation of catalysts. This paper is forwarded to the special issue of the Langmuir journal, devoted to the ISSHAC-3 symposium.

    Copyright © 1999 American Chemical Society

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

     Presented at the Third International Symposium on Effect of Surface Heterogeneity in Adsorption and Catalysis on Solids, held in Poland, August 9−16, 1998.

    *

     Corresponding author. E-mail: [email protected]. Phone: 32-3-820.23.75. Fax: 32-3-820.23.74.

    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 74 publications.

    1. Ziyi Wang, Wuchen Xiang, Chang Shi, Shuping Xiao, Rui Wu, Xueli Yu, Liang Ma, Zhongli Qin, Hongwei Lei, Xiangbai Chen, Guojia Fang, Pingli Qin. Bifunctional Interface Passivation via Copper Acetylacetonate for Efficient and Stable Perovskite Solar Cells. ACS Applied Materials & Interfaces 2023, 15 (42) , 49739-49748. https://doi.org/10.1021/acsami.3c09720
    2. Thomas E. Shaw, Zahra Ali, Taylor M. Currie, S. Novia Berriel, Brian Butkus, J. Tyler Wagner, Konstantin Preradovic, Glenn P. A. Yap, Jennifer C. Green, Parag Banerjee, Alfred P. Sattelberger, Lisa McElwee-White, Titel Jurca. Molybdenum(III) Amidinate: Synthesis, Characterization, and Vapor Phase Growth of Mo-Based Materials. ACS Applied Materials & Interfaces 2023, 15 (29) , 35590-35599. https://doi.org/10.1021/acsami.3c04074
    3. Artem Vityuk, Hristiyan A. Aleksandrov, Georgi N. Vayssilov, Shuguo Ma, Oleg S. Alexeev, and Michael D. Amiridis . Effect of Si/Al Ratio on the Nature and Reactivity of HY Zeolite-Supported Rhodium Dicarbonyl Complexes. The Journal of Physical Chemistry C 2014, 118 (46) , 26772-26788. https://doi.org/10.1021/jp507526g
    4. Jennifer Strunk, William C. Vining, and Alexis T. Bell . Synthesis of Different CeO2 Structures on Mesoporous Silica and Characterization of Their Reduction Properties. The Journal of Physical Chemistry C 2011, 115 (10) , 4114-4126. https://doi.org/10.1021/jp1105746
    5. Jungki Ryu, Sung-Wook Kim, Kisuk Kang and Chan Beum Park. Synthesis of Diphenylalanine/Cobalt Oxide Hybrid Nanowires and Their Application to Energy Storage. ACS Nano 2010, 4 (1) , 159-164. https://doi.org/10.1021/nn901156w
    6. A. E. Lewandowska, M. A. Bañares, D. F. Khabibulin and O. B. Lapina . Precursor Effect on the Molecular Structure, Reactivity, and Stability of Alumina-Supported Vanadia. The Journal of Physical Chemistry C 2009, 113 (48) , 20648-20656. https://doi.org/10.1021/jp9057884
    7. Chuan Wang, Sangyun Lim, Guoan Du, Codruta Zoican Loebicki, Nan Li, Salim Derrouiche and Gary L. Haller. Synthesis, Characterization, and Catalytic Performance of Highly Dispersed Co-SBA-15. The Journal of Physical Chemistry C 2009, 113 (33) , 14863-14871. https://doi.org/10.1021/jp901823v
    8. Miyako Hisamoto, Ryan C. Nelson, Ming-Yung Lee, Juergen Eckert and Susannah L. Scott . Mode of Adsorption of (CH3)2Au(acac) onto Partially Dehydroxylated Silica. The Journal of Physical Chemistry C 2009, 113 (20) , 8794-8805. https://doi.org/10.1021/jp810057v
    9. Chia-Hung Lee,, Tien-Sung Lin, and, Chung-Yuan Mou. Preparation and Characterization of Vanadium Oxide Species Supported on Mesoporous Silica for the Hydroxylation of Benzene. The Journal of Physical Chemistry C 2007, 111 (10) , 3873-3882. https://doi.org/10.1021/jp066323k
    10. Hanjing Tian,, Elizabeth I. Ross, and, Israel E. Wachs. Quantitative Determination of the Speciation of Surface Vanadium Oxides and Their Catalytic Activity. The Journal of Physical Chemistry B 2006, 110 (19) , 9593-9600. https://doi.org/10.1021/jp055767y
    11. Piotr Kuśtrowski,, Lucjan Chmielarz,, Janusz Surman,, Ewa Bidzińska,, Roman Dziembaj,, Pegie Cool, and, Etienne F. Vansant. Catalytic Activity of MCM-48-, SBA-15-, MCF-, and MSU-Type Mesoporous Silicas Modified with Fe3+ Species in the Oxidative Dehydrogenation of Ethylbenzene in the Presence of N2O. The Journal of Physical Chemistry A 2005, 109 (43) , 9808-9815. https://doi.org/10.1021/jp0535442
    12. Piotr Kuśtrowski,, Lucjan Chmielarz,, Roman Dziembaj,, Pegie Cool, and, Etienne F. Vansant. Modification of MCM-48-, SBA-15-, MCF-, and MSU-type Mesoporous Silicas with Transition Metal Oxides Using the Molecular Designed Dispersion Method. The Journal of Physical Chemistry B 2005, 109 (23) , 11552-11558. https://doi.org/10.1021/jp050696o
    13. Y. Segura,, P. Cool,, P. Kustrowski,, L. Chmielarz,, R. Dziembaj, and, E. F. Vansant. Characterization of Vanadium and Titanium Oxide Supported SBA-15. The Journal of Physical Chemistry B 2005, 109 (24) , 12071-12079. https://doi.org/10.1021/jp0507750
    14. S. Van Doorslaer,, Y. Segura, and, P. Cool. Structural Investigation of Vanadyl-Acetylacetonate-Containing Precursors of TiOx−VOx Mixed Oxides on SBA-15. The Journal of Physical Chemistry B 2004, 108 (50) , 19404-19412. https://doi.org/10.1021/jp046611l
    15. Y. Segura,, P. Cool,, P. Van Der Voort,, F. Mees,, V. Meynen, and, E. F. Vansant. TiOx-VOx Mixed Oxides on SBA-15 Support Prepared by the Designed Dispersion of Acetylacetonate Complexes:  Spectroscopic Study of the Reaction Mechanisms. The Journal of Physical Chemistry B 2004, 108 (12) , 3794-3800. https://doi.org/10.1021/jp036259w
    16. Jetta Keranen,, Claude Guimon,, Eero Iiskola,, Aline Auroux, and, Lauri Niinisto. Surface-Controlled Gas-Phase Deposition and Characterization of Highly Dispersed Vanadia on Silica. The Journal of Physical Chemistry B 2003, 107 (39) , 10773-10784. https://doi.org/10.1021/jp030385i
    17. Javier Guzman and, Bruce C. Gates. Reactions of Au(CH3)2(acac) on γ-Al2O3:  Characterization of the Surface Organic, Organometallic, Metal Oxide, and Metallic Species. Langmuir 2003, 19 (9) , 3897-3903. https://doi.org/10.1021/la0268101
    18. Marco de Ridder,, Patrick C. van de Ven,, Rob G. van Welzenis, and, Hidde H. Brongersma, , Steve Helfensteyn and, Claude Creemers, , Pascal Van Der Voort,, Michael Baltes,, Mariska Mathieu, and, Etienne F. Vansant. Growth of Iron Oxide on Yttria-Stabilized Zirconia by Atomic Layer Deposition. The Journal of Physical Chemistry B 2002, 106 (51) , 13146-13153. https://doi.org/10.1021/jp0211640
    19. Philippe Serp and, Philippe Kalck, , Roselyne Feurer. Chemical Vapor Deposition Methods for the Controlled Preparation of Supported Catalytic Materials. Chemical Reviews 2002, 102 (9) , 3085-3128. https://doi.org/10.1021/cr9903508
    20. P. Van Der Voort,, R. van Welzenis,, M. de Ridder,, H. H. Brongersma,, M. Baltes,, M. Mathieu,, P. C. van de Ven, and, E. F. Vansant. Controlled Deposition of Iron Oxide on the Surface of Zirconia by the Molecular Designed Dispersion of Fe(acac)3: A Spectroscopic Study. Langmuir 2002, 18 (11) , 4420-4425. https://doi.org/10.1021/la025679u
    21. Michael Baltes,, Arla Kytökivi,, Bert M. Weckhuysen,, Robert A. Schoonheydt,, Pascal Van Der Voort, and, Etienne F. Vansant. Supported Tantalum Oxide and Supported Vanadia-tantala Mixed Oxides: Structural Characterization and Surface Properties. The Journal of Physical Chemistry B 2001, 105 (26) , 6211-6220. https://doi.org/10.1021/jp010628b
    22. Ziyi Wang, Bobo Yuan, Yiheng Gao, Rui Wu, Shuping Xiao, Wuchen Xiang, Xueli Yu, Pingli Qin. Spiro-OMeTAD Anchoring perovskite for gradual homojunction in stable perovskite solar cells. Solid-State Electronics 2024, 221-222 , 109003. https://doi.org/10.1016/j.sse.2024.109003
    23. Jakob Hochholzer, Pablo Waldschmidt, Frank W. Heinemann, Hansjörg Grützmacher, Karsten Meyer. A Genuine Trivalent Bis‐Acylphosphide (BAP) Complex of Uranium. European Journal of Inorganic Chemistry 2024, 27 (6) https://doi.org/10.1002/ejic.202300592
    24. Noor Ul Huda, Anwar Ul‐Hamid, Muhammad Abdullah Khan, Shabnam Shahida, Muhammad Zaheer. Mesoporous Silica (MCM‐41) Containing Dispersed Palladium Nanoparticles as Catalyst for Dehydrogenation, Methanolysis, and Reduction Reactions. ChemPlusChem 2023, 88 (10) https://doi.org/10.1002/cplu.202300338
    25. Haojie Li, Zhengyuan Wu, Siyu Wu, Pengfei Tian, Zhilai Fang. (AlxGa1-x)2O3-based materials: Growth, properties, and device applications. Journal of Alloys and Compounds 2023, 960 , 170671. https://doi.org/10.1016/j.jallcom.2023.170671
    26. Majid D. Farahani, Cheslin Moodley, Abdul S. Mahomed, Holger B. Friedrich. Morphology, oxygen vacancies, and other factors affecting the performance of supported bimetallic ceria catalysts. iScience 2022, 25 (12) , 105560. https://doi.org/10.1016/j.isci.2022.105560
    27. Aram Yoon, Gyutae Kim, Minjeong Lee, Zonghoon Lee, Gyoeng Hee Ryu. Thermally driven phase transition of cobalt hydroxide sheets via cobalt oxides to cobalt nanoparticles. Nanoscale Horizons 2022, 7 (10) , 1210-1216. https://doi.org/10.1039/D2NH00218C
    28. Majid D. Farahani, Yimin Zeng, Ying Zheng. The application of nonthermal plasma in methanol synthesis via CO 2 hydrogenation. Energy Science & Engineering 2022, 10 (5) , 1572-1583. https://doi.org/10.1002/ese3.1107
    29. Kentaro Kaneko, Kazuyuki Uno, Riena Jinno, Shizuo Fujita. Prospects for phase engineering of semi-stable Ga2O3 semiconductor thin films using mist chemical vapor deposition. Journal of Applied Physics 2022, 131 (9) https://doi.org/10.1063/5.0069554
    30. Atefeh Tavakoli, Noushin Nasiri, Yadollah Mortazavi, Abbas Ali Khodadadi. Cyclic molecular designed dispersion (CMDD) of Fe2O3 on CeO2 promoted by Au for preferential CO oxidation in hydrogen. International Journal of Hydrogen Energy 2020, 45 (58) , 33598-33611. https://doi.org/10.1016/j.ijhydene.2020.09.123
    31. Hossein Kazerooni, Jafar Towfighi Darian, Yadollah Mortazavi, Abbas Ali Khadadadi, Reza Asadi. Titania-Supported Vanadium Oxide Synthesis by Atomic Layer Deposition and Its Application for Low-Temperature Oxidative Dehydrogenation of Propane. Catalysis Letters 2020, 150 (10) , 2807-2822. https://doi.org/10.1007/s10562-020-03189-w
    32. Kazuyuki Uno, Marika Ohta, Ichiro Tanaka. Growth mechanism of α -Ga2O3 on a sapphire substrate by mist chemical vapor deposition using acetylacetonated gallium source solutions. Applied Physics Letters 2020, 117 (5) https://doi.org/10.1063/5.0014056
    33. Alexandre Amormino S. Gonçalves, Mietek Jaroniec. Evaporation-induced self-assembly synthesis of nanostructured alumina-based mixed metal oxides with tailored porosity. Journal of Colloid and Interface Science 2019, 537 , 725-735. https://doi.org/10.1016/j.jcis.2018.11.044
    34. Piriya Pinthong, Piyasan Praserthdam, Bunjerd Jongsomjit. Effect of Calcination Temperature on Mg-Al Layered Double Hydroxides (LDH) as Promising Catalysts in Oxidative Dehydrogenation of Ethanol to Acetaldehyde. Journal of Oleo Science 2019, 68 (1) , 95-102. https://doi.org/10.5650/jos.ess18177
    35. Piriya Pinthong, Piyasan Praserthdam, Bunjerd Jongsomjit. Oxidative Dehydrogenation of Ethanol over Vanadium- and Molybdenum-modified Mg-Al Mixed Oxide Derived from Hydrotalcite. Journal of Oleo Science 2019, 68 (7) , 679-687. https://doi.org/10.5650/jos.ess19035
    36. Andrzej Kowalczyk, Aneta Święs, Barbara Gil, Małgorzata Rutkowska, Zofia Piwowarska, Aleksandra Borcuch, Marek Michalik, Lucjan Chmielarz. Effective catalysts for the low-temperature NH3-SCR process based on MCM-41 modified with copper by template ion-exchange (TIE) method. Applied Catalysis B: Environmental 2018, 237 , 927-937. https://doi.org/10.1016/j.apcatb.2018.06.052
    37. Lucjan Chmielarz, Małgorzata Rutkowska, Andrzej Kowalczyk. Advances in Functionalization of Inorganic Porous Materials for Environmental Catalysis. 2018, 323-383. https://doi.org/10.1016/bs.adioch.2018.05.005
    38. Isabel Correia, Ielyzaveta Chorna, Isabel Cavaco, Somnath Roy, Maxim L. Kuznetsov, Nádia Ribeiro, Gonçalo Justino, Fernanda Marques, Teresa Santos‐Silva, Marino F.A. Santos, Hugo M. Santos, José L. Capelo, James Doutch, João Costa Pessoa. Interaction of [V IV O(acac) 2 ] with Human Serum Transferrin and Albumin. Chemistry – An Asian Journal 2017, 12 (16) , 2062-2084. https://doi.org/10.1002/asia.201700469
    39. Andrzej Kowalczyk, Aleksandra Borcuch, Marek Michalik, Małgorzata Rutkowska, Barbara Gil, Zbigniew Sojka, Paulina Indyka, Lucjan Chmielarz. MCM-41 modified with transition metals by template ion-exchange method as catalysts for selective catalytic oxidation of ammonia to dinitrogen. Microporous and Mesoporous Materials 2017, 240 , 9-21. https://doi.org/10.1016/j.micromeso.2016.11.002
    40. Tasha L. Drake, Peter C. Stair. Vapor deposition of molybdenum oxide using bis(ethylbenzene) molybdenum and water. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films 2016, 34 (5) https://doi.org/10.1116/1.4959532
    41. Andrzej Kowalczyk, Zofia Piwowarska, Daniel Macina, Piotr Kuśtrowski, Anna Rokicińska, Marek Michalik, Lucjan Chmielarz. MCM-41 modified with iron by template ion-exchange method as effective catalyst for DeNOx and NH 3 -SCO processes. Chemical Engineering Journal 2016, 295 , 167-180. https://doi.org/10.1016/j.cej.2016.03.049
    42. François Bérubé, Abdelkarim Khadraoui, Justyna Florek, Serge Kaliaguine, Freddy Kleitz. A generalized method toward high dispersion of transition metals in large pore mesoporous metal oxide/silica hybrids. Journal of Colloid and Interface Science 2015, 449 , 102-114. https://doi.org/10.1016/j.jcis.2014.12.001
    43. Parijat Borah, Xing Ma, Kim Truc Nguyen, Yanli Zhao. A Vanadyl Complex Grafted to Periodic Mesoporous Organosilica: A Green Catalyst for Selective Hydroxylation of Benzene to Phenol. Angewandte Chemie 2012, 124 (31) , 7876-7881. https://doi.org/10.1002/ange.201203275
    44. Parijat Borah, Xing Ma, Kim Truc Nguyen, Yanli Zhao. A Vanadyl Complex Grafted to Periodic Mesoporous Organosilica: A Green Catalyst for Selective Hydroxylation of Benzene to Phenol. Angewandte Chemie International Edition 2012, 51 (31) , 7756-7761. https://doi.org/10.1002/anie.201203275
    45. Jing Lu, Ceren Aydin, Nigel D. Browning, Bruce C. Gates. Imaging Isolated Gold Atom Catalytic Sites in Zeolite NaY. Angewandte Chemie 2012, 124 (24) , 5944-5948. https://doi.org/10.1002/ange.201107391
    46. Jing Lu, Ceren Aydin, Nigel D. Browning, Bruce C. Gates. Imaging Isolated Gold Atom Catalytic Sites in Zeolite NaY. Angewandte Chemie International Edition 2012, 51 (24) , 5842-5846. https://doi.org/10.1002/anie.201107391
    47. Mannar R. Maurya, Amit Kumar, J. Costa Pessoa. Vanadium complexes immobilized on solid supports and their use as catalysts for oxidation and functionalization of alkanes and alkenes. Coordination Chemistry Reviews 2011, 255 (19-20) , 2315-2344. https://doi.org/10.1016/j.ccr.2011.01.050
    48. Grigoriy Sereda, Taejin Kim, Aubrey Jones, Hari Khatri, Christopher L. Marshall, H. Subramanian, Ranjit T. Koodali. Phthalocyanine- and Calixarene-Templating Effect on the Catalytic Performance of Solid Supported Vanadates. Catalysis Letters 2011, 141 (8) , 1086-1096. https://doi.org/10.1007/s10562-011-0662-7
    49. Maritana Farias, Márcia Martinelli, Guilherme Koszeniewski Rolim. Immobilized molybdenum acetylacetonate complex on montmorillonite K-10 as catalyst for epoxidation of vegetable oils. Applied Catalysis A: General 2011, 403 (1-2) , 119-127. https://doi.org/10.1016/j.apcata.2011.06.021
    50. Guojun Shi, Thomas Franzke, Wei Xia, Miguel D. Sanchez, Martin Muhler. Highly Dispersed MoO 3 /Al 2 O 3 Shell‐Core Composites Synthesized by CVD of Mo(CO) 6 under Atmospheric Pressure. Chemical Vapor Deposition 2011, 17 (4-6) , 162-169. https://doi.org/10.1002/cvde.201106909
    51. Clara Pereira, José F. Silva, André M. Pereira, João P. Araújo, Ginesa Blanco, Jose M. Pintado, Cristina Freire. [VO(acac)2] hybrid catalyst: from complex immobilization onto silica nanoparticles to catalytic application in the epoxidation of geraniol. Catalysis Science & Technology 2011, 1 (5) , 784. https://doi.org/10.1039/c1cy00090j
    52. Janusz Ryczkowski. Infrared photoacoustic spectroscopy in catalysis and surface science. Applied Surface Science 2010, 256 (17) , 5545-5550. https://doi.org/10.1016/j.apsusc.2009.12.135
    53. L. Chmielarz, P. Kuśtrowski, R. Dziembaj, P. Cool, E.F. Vansant. SBA-15 mesoporous silica modified with metal oxides by MDD method in the role of DeNOx catalysts. Microporous and Mesoporous Materials 2010, 127 (1-2) , 133-141. https://doi.org/10.1016/j.micromeso.2009.07.003
    54. Clara Pereira, Krzysztof Biernacki, Susana L.H. Rebelo, Alexandre L. Magalhães, Ana Paula Carvalho, João Pires, Cristina Freire. Designing heterogeneous oxovanadium and copper acetylacetonate catalysts: Effect of covalent immobilisation in epoxidation and aziridination reactions. Journal of Molecular Catalysis A: Chemical 2009, 312 (1-2) , 53-64. https://doi.org/10.1016/j.molcata.2009.07.004
    55. Bruno Jarrais, Clara Pereira, Ana Rosa Silva, Ana P. Carvalho, João Pires, Cristina Freire. Grafting of vanadyl acetylacetonate onto organo-hexagonal mesoporous silica and catalytic activity in the allylic epoxidation of geraniol. Polyhedron 2009, 28 (5) , 994-1000. https://doi.org/10.1016/j.poly.2008.12.049
    56. Hongchuan Xin, Jian Liu, Fengtao Fan, Zhaochi Feng, Guoqing Jia, Qihua Yang, Can Li. Mesoporous ferrosilicates with high content of isolated iron species synthesized in mild buffer solution and their catalytic application. Microporous and Mesoporous Materials 2008, 113 (1-3) , 231-239. https://doi.org/10.1016/j.micromeso.2007.11.022
    57. Clara Pereira, Ana Rosa Silva, Ana Paula Carvalho, João Pires, Cristina Freire. Vanadyl acetylacetonate anchored onto amine-functionalised clays and catalytic activity in the epoxidation of geraniol. Journal of Molecular Catalysis A: Chemical 2008, 283 (1-2) , 5-14. https://doi.org/10.1016/j.molcata.2007.11.034
    58. J. Ryczkowski. Recent applications of FT-IR/PAS studies in catalysis. The European Physical Journal Special Topics 2008, 154 (1) , 357-361. https://doi.org/10.1140/epjst/e2008-00575-4
    59. Clara Pereira, Sónia Patrício, Ana Rosa Silva, Alexandre L. Magalhães, Ana Paula Carvalho, João Pires, Cristina Freire. Copper acetylacetonate anchored onto amine-functionalised clays. Journal of Colloid and Interface Science 2007, 316 (2) , 570-579. https://doi.org/10.1016/j.jcis.2007.07.053
    60. Alina-Mihaela Hanu, Shiquan Liu, Vera Meynen, Pegie Cool, Eveline Popovici, Etienne F. Vansant. Influence of the MCM-41 morphology on the vanadia deposition by a molecular designed dispersion method. Microporous and Mesoporous Materials 2006, 95 (1-3) , 31-38. https://doi.org/10.1016/j.micromeso.2006.04.015
    61. L. Chmielarz, P. Kuśtrowski, R. Dziembaj, P. Cool, E.F. Vansant. Catalytic performance of various mesoporous silicas modified with copper or iron oxides introduced by different ways in the selective reduction of NO by ammonia. Applied Catalysis B: Environmental 2006, 62 (3-4) , 369-380. https://doi.org/10.1016/j.apcatb.2005.09.004
    62. Laxmidhar Rout, Tharmalingam Punniyamurthy. Silica‐Supported Vanadium‐Catalyzed N ‐Oxidation of Tertiary Amines with Aqueous Hydrogen Peroxide. Advanced Synthesis & Catalysis 2005, 347 (15) , 1958-1960. https://doi.org/10.1002/adsc.200505166
    63. Yolanda Segura, Lucjan Chmielarz, Piotr Kustrowski, Pegie Cool, Roman Dziembaj, Etienne F. Vansant. Characterisation and reactivity of vanadia–titania supported SBA-15 in the SCR of NO with ammonia. Applied Catalysis B: Environmental 2005, 61 (1-2) , 69-78. https://doi.org/10.1016/j.apcatb.2005.04.011
    64. V. Meynen, Y. Segura, M. Mertens, P. Cool, E.F. Vansant. Diffusion effects in SBA-15 and its plugged analogous by a deposition of metal–acetylacetonate complexes. Microporous and Mesoporous Materials 2005, 85 (1-2) , 119-128. https://doi.org/10.1016/j.micromeso.2005.05.035
    65. L. Chmielarz, P. Kuśtrowski, M. Kruszec, R. Dziembaj, P. Cool, E. F. Vansant. Nitrous Oxide Reduction with Ammonia and Methane Over Mesoporous Silica Materials Modified with Transition Metal Oxides. Journal of Porous Materials 2005, 12 (3) , 183-191. https://doi.org/10.1007/s10934-005-1646-z
    66. Yolanda Segura, Johan S. Paul, Kevin Huyghe, Walter Vermandel, Pegie Cool, Etienne F. Vansant, Bert F. Sels, Pierre A. Jacobs. Molecular designed vanadia–titania supported SBA-15 for the oxidative dehydrogenation of isobutane and propane. 2005, 733-740. https://doi.org/10.1016/S0167-2991(05)80280-0
    67. K Anas, K.K Mohammed Yusuff. Synthesis, characterization and hydrodesulphurisation activity of CoMo/γ-Al2O3 catalyst prepared through molecular designed dispersion method. Applied Catalysis A: General 2004, 264 (2) , 213-217. https://doi.org/10.1016/j.apcata.2003.12.050
    68. Bert M. Weckhuysen, Daphne E. Keller. Chemistry, spectroscopy and the role of supported vanadium oxides in heterogeneous catalysis. Catalysis Today 2003, 78 (1-4) , 25-46. https://doi.org/10.1016/S0920-5861(02)00323-1
    69. Jetta Keränen, Claude Guimon, Aline Auroux, Eero I. Iiskola, Lauri Niinistö. Gas-phase synthesis, structure and surface acid–base properties of highly dispersed vanadia/titania/silica catalysts. Phys. Chem. Chem. Phys. 2003, 5 (23) , 5333-5342. https://doi.org/10.1039/B307902C
    70. E. Romero-Pascual, A. Larrea, A. Monzón, R.D. González. Thermal Stability of Pt/Al2O3 Catalysts Prepared by Sol–Gel. Journal of Solid State Chemistry 2002, 168 (1) , 343-353. https://doi.org/10.1006/jssc.2002.9680
    71. Valeri Naydenov, Lubomira Tosheva, Johan Sterte. Spherical silica macrostructures containing vanadium and tungsten oxides assembled by the resin templating method. Microporous and Mesoporous Materials 2002, 55 (3) , 253-263. https://doi.org/10.1016/S1387-1811(02)00427-4
    72. J Keränen, A Auroux, S Ek, L Niinistö. Preparation, characterization and activity testing of vanadia catalysts deposited onto silica and alumina supports by atomic layer deposition. Applied Catalysis A: General 2002, 228 (1-2) , 213-225. https://doi.org/10.1016/S0926-860X(01)00975-9
    73. J Keränen, A Auroux, S Ek-Härkönen, L Niinistö. Calorimetric measurements of the acidity of supported vanadium oxides prepared by ALE and impregnation. Thermochimica Acta 2001, 379 (1-2) , 233-239. https://doi.org/10.1016/S0040-6031(01)00621-9
    74. M Baltes, K Cassiers, P Van Der Voort, B.M Weckhuysen, R.A Schoonheydt, E.F Vansant. MCM-48-Supported Vanadium Oxide Catalysts, Prepared by the Molecular Designed Dispersion of VO(acac)2: A Detailed Study of the Highly Reactive MCM-48 Surface and the Structure and Activity of the Deposited VOx. Journal of Catalysis 2001, 197 (1) , 160-171. https://doi.org/10.1006/jcat.2000.3066

    Langmuir

    Cite this: Langmuir 1999, 15, 18, 5841–5845
    Click to copy citationCitation copied!
    https://doi.org/10.1021/la981362b
    Published March 25, 1999
    Copyright © 1999 American Chemical Society

    Article Views

    1828

    Altmetric

    -

    Citations

    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.