Measurement of Free-Radical Propagation Rate Coefficients for Ethyl, Butyl, and Isobutyl Methacrylates by Pulsed-Laser PolymerizationClick to copy article linkArticle link copied!
Note: In lieu of an abstract, this is the article's first page.
Cited By
This article is cited by 46 publications.
- Matthew D. Miller and Andrew J. Holder . A Quantum Mechanical Study of Methacrylate Free-Radical Polymerizations. The Journal of Physical Chemistry A 2010, 114
(41)
, 10988-10996. https://doi.org/10.1021/jp104198p
- Jaeup U. Kim, , Ben O'Shaughnessy. Laser Pulse Control of High-Conversion Free Radical Polymerization. Macromolecules 2004, 37
(4)
, 1630-1640. https://doi.org/10.1021/ma034607m
- Carine Burguière,, Marie-Anne Dourges,, Bernadette Charleux, and, Jean-Pierre Vairon. Synthesis and Characterization of ω-Unsaturated Poly(styrene-b-n-butyl methacrylate) Block Copolymers Using TEMPO-Mediated Controlled Radical Polymerization. Macromolecules 1999, 32
(12)
, 3883-3890. https://doi.org/10.1021/ma982037y
- David M. Huang,, Michael J. Monteiro, and, Robert G. Gilbert. A Theoretical Study of Propagation Rate Coefficients for Methacrylonitrile and Acrylonitrile. Macromolecules 1998, 31
(16)
, 5175-5187. https://doi.org/10.1021/ma980229n
- Michael D. Zammit,, Michelle L. Coote,, Thomas P. Davis, and, Gary D. Willett. Effect of the Ester Side-Chain on the Propagation Kinetics of Alkyl MethacrylatesAn Entropic or Enthalpic Effect?. Macromolecules 1998, 31
(4)
, 955-963. https://doi.org/10.1021/ma9707291
- Krzysztof Matyjaszewski . Mechanistic Aspects of Atom Transfer Radical Polymerization. 1998, 258-283. https://doi.org/10.1021/bk-1998-0685.ch016
- Graeme Moad,, Devon A. Shipp,, Trevor A. Smith, and, David H. Solomon. Direct Measurement of Primary Radical Concentrations in Pulsed Laser Photolysis. Macromolecules 1997, 30
(24)
, 7627-7630. https://doi.org/10.1021/ma9708095
- R. A. Hutchinson,, S. Beuermann,, D. A. Paquet, Jr., and, J. H. McMinn. Determination of Free-Radical Propagation Rate Coefficients for Alkyl Methacrylates by Pulsed-Laser Polymerization. Macromolecules 1997, 30
(12)
, 3490-3493. https://doi.org/10.1021/ma970176u
- E. F. McCord,, W. H. Shaw, Jr., and, R. A. Hutchinson. Short-Chain Branching Structures in Ethylene Copolymers Prepared by High-Pressure Free-Radical Polymerization: An NMR Analysis. Macromolecules 1997, 30
(2)
, 246-256. https://doi.org/10.1021/ma9606871
- Robert A. Lyons,, Jelica Hutovic,, Mark C. Piton,, David I. Christie,, Paul A. Clay,, Bart G. Manders,, Scott H. Kable, and, Robert G. Gilbert. Pulsed-Laser Polymerization Measurements of the Propagation Rate Coefficient for Butyl Acrylate. Macromolecules 1996, 29
(6)
, 1918-1927. https://doi.org/10.1021/ma950747n
- Michael D. Zammit,, Thomas P. Davis, and, David M. Haddleton. Determination of the Propagation Rate Coefficient (kp) and Termination Mode in the Free-Radical Polymerization of Methyl Methacrylate, Employing Matrix-Assisted Laser Desorption Ionization Time-of-Flight Mass Spectrometry for Molecular Weight Distribution Analysis. Macromolecules 1996, 29
(1)
, 492-494. https://doi.org/10.1021/ma9512925
- S. Beuermann,, D. A. Paquet, Jr.,, J. H. McMinn, and, R. A. Hutchinson. Determination of Free-Radical Propagation Rate Coefficients of Butyl, 2-Ethylhexyl, and Dodecyl Acrylates by Pulsed-Laser Polymerization. Macromolecules 1996, 29
(12)
, 4206-4215. https://doi.org/10.1021/ma960081c
- David Dorschner, Woosung Jung, Marzieh Riahinezhad, Thomas A. Duever, Alexander Penlidis. Case studies with mathematical modeling of free-radical multi-component bulk/solution polymerizations: Part 2. Journal of Macromolecular Science, Part A 2017, 54
(6)
, 339-371. https://doi.org/10.1080/10601325.2017.1312678
- T. Furuncuoğlu Özaltın, B. Dereli, Ö. Karahan, S. Salman, V. Aviyente. Solvent effects on free-radical copolymerization of styrene and 2-hydroxyethyl methacrylate: a DFT study. New J. Chem. 2014, 38
(1)
, 170-178. https://doi.org/10.1039/C3NJ00820G
- Annemieke M. Aerdts, Alex M. van Herk, Bert Klumperman, Jenci Kurja, Anton L. German. Emulsion Polymerization. 2013https://doi.org/10.1002/9783527603978.mst0231
- Till Gruendling, Dominik Voll, Michael Guilhaus, Christopher Barner‐Kowollik. A Perfect Couple: PLP/SEC/ESI‐MS for the Accurate Determination of Propagation Rate Coefficients in Free Radical Polymerization. Macromolecular Chemistry and Physics 2010, 211
(1)
, 80-90. https://doi.org/10.1002/macp.200900394
- David F. Sangster, Jesper Feldthusen, Jelica Strauch, Christopher M. Fellows. Measurement of Transfer Coefficients to Monomer for
n
‐Butyl Methacrylate by Molecular Weight Distributions from Emulsion Polymerization. Macromolecular Chemistry and Physics 2008, 209
(15)
, 1612-1627. https://doi.org/10.1002/macp.200800059
- Emma M. Coen, Sarah Peach, Bradley R. Morrison, Robert G. Gilbert. First-principles calculation of particle formation in emulsion polymerization: pseudo-bulk systems. Polymer 2004, 45
(11)
, 3595-3608. https://doi.org/10.1016/j.polymer.2004.03.084
- Takahiro Harada, Per B. Zetterlund, Bunichiro Yamada. Preparation of macromonomers by copolymerization of methyl acrylate dimer involving β fragmentation. Journal of Polymer Science Part A: Polymer Chemistry 2004, 42
(3)
, 597-607. https://doi.org/10.1002/pola.10803
- Ben O'Shaughnessy, Dimitrios Vavylonis. Pulsed Laser Polymerization at Low Conversions: Broadening and Chain Transfer Effects. Macromolecular Theory and Simulations 2003, 12
(6)
, 401-412. https://doi.org/10.1002/mats.200350001
- F. García, J. M. García, F. Rubio, J. L. de la Peña, J. Guzmán, E. Riande. Synthesis and radical polymerization of hydrophilic methacrylates with oxyethylene units in the pendant chain. Journal of Polymer Science Part A: Polymer Chemistry 2003, 41
(11)
, 1567-1579. https://doi.org/10.1002/pola.10703
- Jiansheng Tang, Tianhua Ding, Eric S. Daniels, Victoria L. Dimonie, Andrew Klein, Mohamed S. El‐Aasser. Synthesis of well‐defined, functionalized polymer latex particles through semicontinuous emulsion polymerization processes. Journal of Applied Polymer Science 2003, 88
(1)
, 30-41. https://doi.org/10.1002/app.11685
- Sabine Beuermann, Michael Buback. Rate coefficients of free-radical polymerization deduced from pulsed laser experiments. Progress in Polymer Science 2002, 27
(2)
, 191-254. https://doi.org/10.1016/S0079-6700(01)00049-1
- Kenta Tanaka, Bunichiro Yamada, Christopher M. Fellows, Robert G. Gilbert, Thomas P. Davis, Lachlan H. Yee, Gregory B. Smith, Mark T. L. Rees, Gregory T. Russell. Pulsed‐laser polymerization‐gel permeation chromatographic determination of the propagation‐rate coefficient for the methyl acrylate dimer: A sterically hindered monomer. Journal of Polymer Science Part A: Polymer Chemistry 2001, 39
(22)
, 3902-3915. https://doi.org/10.1002/pola.10034
- Tsuneyuki Sato, Takayuki Oki, Makiko Seno, Tomohiro Hirano. Radical and cationic polymerizations of 3‐ethyl‐3‐methacryloyloxymethyloxetane. Journal of Polymer Science Part A: Polymer Chemistry 2001, 39
(9)
, 1269-1279. https://doi.org/10.1002/pola.1104
- Michael J. Monteiro, Marcelle Hodgson, Hans De Brouwer. The influence of RAFT on the rates and molecular weight distributions of styrene in seeded emulsion polymerizations. Journal of Polymer Science Part A: Polymer Chemistry 2000, 38
(21)
, 3864-3874. https://doi.org/10.1002/1099-0518(20001101)38:21<3864::AID-POLA30>3.0.CO;2-3
- Halina Kaczmarek, Alina Kamińska, Alex van Herk. Photooxidative degradation of poly(alkyl methacrylate)s. European Polymer Journal 2000, 36
(4)
, 767-777. https://doi.org/10.1016/S0014-3057(99)00125-1
- R. Dhib, J. Gao, A. Penlidis. Simulation of Free Radical Bulk/Solution Homopolymerization Using Mono- and Bi-functional Initiators. Polymer Reaction Engineering 2000, 8
(4)
, 299-464. https://doi.org/10.1080/10543414.2000.10744557
- Masataka Ohoka, Sadahito Misumi, Masahide Yamamoto. Determination of Propagation Rate Coefficient of Free-Radical Polymerization of N-Vinylcarbazole by Pulsed-Laser Polymerization. Polymer Journal 1999, 31
(10)
, 878-882. https://doi.org/10.1295/polymj.31.878
- E Takács, S.S Emmi, L Wojnárovits. Study of polymerization kinetics of acrylic and methacrylic acid esters at low conversions. Radiation Physics and Chemistry 1999, 55
(5-6)
, 621-624. https://doi.org/10.1016/S0969-806X(99)00258-3
- C. Cirman, M. Bouquey, J. Terrisse, R. Muller. Rheological Study of the Interfacial Crosslinking Reaction in Reactive Polymer Blends. Applied Rheology 1999, 9
(3)
, 108-115. https://doi.org/10.1515/arh-2009-0008
- M. Kamachi, B. Yamada. Propagation and Termination Constants in Free Radical Polymerization. 1999https://doi.org/10.1002/0471532053.bra004
- T. F. Mckenna, A. M. Santos. Activation Energies of Propagation and Termination in Free Radical Polymerization. 1999https://doi.org/10.1002/0471532053.bra013
- Annemieke M. Aerdts, Alex M. van Herk, Bert Klumperman, Jenci Kurja, Anton L. German. Emulsion Polymerization. 1998, 268-316. https://doi.org/10.1002/9783527619313.ch9
- M. Fernández-Garcia, J.J. Martinez, E.L. Madruga. Solvent effects on the free-radical polymerization of methyl methacrylate. Polymer 1998, 39
(4)
, 991-995. https://doi.org/10.1016/S0032-3861(97)00406-0
- Oskar Friedrich Olaj, Andreas Kornherr, Gerhard Zifferer. Chain‐length dependent termination in pulsed‐laser polymerization, 2. On the prospects of determining the bimolecular termination constant
k
t
from the second moment of the chain‐length distribution. Macromolecular Rapid Communications 1997, 18
(12)
, 997-1007. https://doi.org/10.1002/marc.1997.030181202
- Alex M. van Herk. Pulsed Initiation Polymerization as a Means of Obtaining Propagation Rate Coefficients in Free-Radical Polymerizations. Journal of Macromolecular Science, Part C: Polymer Reviews 1997, 37
(4)
, 633-648. https://doi.org/10.1080/15321799708009651
- E. Takács, L. Wojnárovits. Kinetic study on the radiation-induced polymerization of HDDA and HDDMA. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 1997, 131
(1-4)
, 295-299. https://doi.org/10.1016/S0168-583X(97)00335-2
- Sabine Beuermann, Michael Buback, Thomas P. Davis, Robert G. Gilbert, Robin A. Hutchinson, Oskar Friedrich Olaj, Gregory T. Russell, Johannes Schweer, Alex M. van Herk. Critically evaluated rate coefficients for free‐radical polymerization, 2.. Propagation rate coefficients for methyl methacrylate. Macromolecular Chemistry and Physics 1997, 198
(5)
, 1545-1560. https://doi.org/10.1002/macp.1997.021980518
- A. M. Herk. Particle Growth in Emulsion Polymerization. 1997, 17-30. https://doi.org/10.1007/978-94-011-5512-0_2
- Dax Kukulj, Robert G. Gilbert. Polymerization at High Conversion. 1997, 97-107. https://doi.org/10.1007/978-94-011-5512-0_7
- Michael Buback. Free‐radical polymerization kinetics in extended ranges of temperature, pressure and monomer conversion. Macromolecular Symposia 1996, 111
(1)
, 229-242. https://doi.org/10.1002/masy.19961110121
- Michael Buback, Markus Busch, Ralf A. Lämmel. Modeling of molecular weight distribution in pulsed laser free‐radical homopolymerizations. Macromolecular Theory and Simulations 1996, 5
(5)
, 845-861. https://doi.org/10.1002/mats.1996.040050505
- Gerhard Zifferer, Oskar Friedrich Olaj. The incorporation of side reactions into pseudostationary polymerization, 1. The closed solution of a kinetic scheme comprising chain‐transfer to monomer or solvent. Macromolecular Theory and Simulations 1996, 5
(5)
, 901-921. https://doi.org/10.1002/mats.1996.040050508
- Enrique López Madruga, Marta Fernández‐García. Kinetic study of free‐radical copolymerization of methyl acrylate and methyl methacrylate in benzene. Macromolecular Chemistry and Physics 1996, 197
(4)
, 1185-1191. https://doi.org/10.1002/macp.1996.021970402
- Friedhelm Bandermann, Claus Günther, Johannes Schweer. Towards the propagation rate coefficient for the free‐radical polymerization of 1,3‐butadiene. Macromolecular Chemistry and Physics 1996, 197
(3)
, 1055-1069. https://doi.org/10.1002/macp.1996.021970324
Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.
Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.
The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.