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New Routes to Hyperbranched Poly(acrylic acid) Surface Grafts on Polyethylene Films and Powders

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Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas 77842-3012
Cite this: Macromolecules 2004, 37, 23, 8686–8691
Publication Date (Web):October 22, 2004
https://doi.org/10.1021/ma048808h
Copyright © 2004 American Chemical Society
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    Abstract

    Hyperbranched grafting is a useful method for surface modification of both inorganic and organic polymer surfaces but is synthetically cumbersome as it requires synthesis of functional polymers as reagents. This paper describes an alternative approach using acrylic acid and Ce(IV) graft-on-a-graft chemistry. The substrates, polyethylene films and powders, were prepared for grafting by oxidation and incorporation of a low loading of a polyhydroxylated oligomer. In subsequent steps, the hydroxyl groups of this surface are successively grafted with Ce(IV) and acrylic acid. The resulting carboxylic acid groups were converted into yet more hydroxyl groups. Repetition of this process yields a hyperbranched graft. Copolymer grafts too can be prepared using appropriate mixtures of monomers.

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     Corresponding author:  e-mail [email protected].

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    5. Murat Barsbay, Olgun Güven. RAFT mediated grafting of poly(acrylic acid) (PAA) from polyethylene/polypropylene (PE/PP) nonwoven fabric via preirradiation. Polymer 2013, 54 (18) , 4838-4848. https://doi.org/10.1016/j.polymer.2013.06.059
    6. Sergiy Peleshanko, Vladimir V. Tsukruk. Assembling hyperbranched polymerics. Journal of Polymer Science Part B: Polymer Physics 2012, 50 (2) , 83-100. https://doi.org/10.1002/polb.22361
    7. Sergiy Peleshanko, Vladimir V. Tsukruk. Grafting and Surface Properties of Hyperbranched Polymers. 2011, 369-385. https://doi.org/10.1002/9780470929001.ch14
    8. Yanika Schneider, Brian T. McVerry, Guillermo C. Bazan. Synthesis and Characterization of Semicrystalline Polyethylene -graft- Poly(acrylic acid) Copolymers. Macromolecular Chemistry and Physics 2011, 212 (5) , 507-514. https://doi.org/10.1002/macp.201000648
    9. E.T. Kang, K.G. Neoh. Surface Modification of Polymers. 2009https://doi.org/10.1002/0471440264.pst358
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    11. Rafael Silva, Edvani C. Muniz, Adley F. Rubira. Multiple hydrophilic polymer ultra-thin layers covalently anchored to polyethylene films. Polymer 2008, 49 (19) , 4066-4075. https://doi.org/10.1016/j.polymer.2008.07.051
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    13. G. V. Korolev, M. L. Bubnova. Synthesis, properties, and practical application of hyperbranched polymers. Polymer Science Series C 2007, 49 (4) , 332-354. https://doi.org/10.1134/S1811238207040030
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    15. David E. Bergbreiter, Brandon S. Chance. “Click”-Based Covalent Layer-by-Layer Assembly on Polyethylene Using Water-Soluble Polymeric Reagents. Macromolecules 2007, 40 (15) , 5337-5343. https://doi.org/10.1021/ma0701134
    16. N.E. Leadbeater. Polymer-supported Organometallic Catalysts. 2007, 663-753. https://doi.org/10.1016/B0-08-045047-4/00179-5
    17. Liming Tang, Hu You, Ji Feng. Formation and surface modification of self-assembled films with acrylated hyperbranched poly(ester-amine) as the outmost layer. Thin Solid Films 2007, 515 (5) , 2998-3004. https://doi.org/10.1016/j.tsf.2006.09.019
    18. Yeon-Seok Kim, Kang-Shyang Liao, C. Jason Jan, David E. Bergbreiter, Jaime C. Grunlan. Conductive Thin Films on Functionalized Polyethylene Particles. Chemistry of Materials 2006, 18 (13) , 2997-3004. https://doi.org/10.1021/cm0603607
    19. Martina Källrot, Ulrica Edlund, A.-C. Albertsson. Surface functionalization of degradable polymers by covalent grafting. Biomaterials 2006, 27 (9) , 1788-1796. https://doi.org/10.1016/j.biomaterials.2005.10.010
    20. Bao-Ku Zhu, Xiu-Zhen Wei, Ling Xiao, You-Yi Xu, Kurt E Geckeler. Preparation and properties of hyperbranched poly(amine-ester) films using acetal cross-linking units. Polymer International 2006, 55 (1) , 63-70. https://doi.org/10.1002/pi.1919
    21. David E. Bergbreiter, Eric E. Simanek, Izabela Owsik. New synthetic methods for the formation of basic, polyvalent, hyperbranched grafts. Journal of Polymer Science Part A: Polymer Chemistry 2005, 43 (19) , 4654-4665. https://doi.org/10.1002/pola.20916
    22. Hans-Werner Schmidt, Nils Mohmeyer. Makromolekulare Chemie 2004. Nachrichten aus der Chemie 2005, 53 (3) , 305-311. https://doi.org/10.1002/nadc.20050530316
    23. David E. Bergbreiter, Andrew M. Kippenberger, William M. Lackowski. New Syntheses of Hyperbranched Polyamine Grafts. Macromolecules 2005, 38 (1) , 47-52. https://doi.org/10.1021/ma048197t
    24. Gennady V. Korolev, Michael M. Mogilevich. Properties and Application of Hyper-Branched Polymers. , 243-255. https://doi.org/10.1007/978-3-540-87567-3_8
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