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Fluorescence Turn-On Sensing of Anions Based on Disassembly Process of Urea-Functionalized Poly(phenylenebutadiynylene) Aggregates

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† Division of Biotechnology and Macromolecular Chemistry, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan
‡ Graduate School of Pure and Applied Chemistry, University of Tsukuba, Tsukuba 305-8571, Japan
*Tel +81 11 706 6602; Fax +81 11 706 6602; e-mail [email protected]
Cite this: Macromolecules 2012, 45, 10, 4122–4127
Publication Date (Web):May 8, 2012
https://doi.org/10.1021/ma300481j
Copyright © 2012 American Chemical Society
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Abstract

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A rationally designed poly(phenylenebutadiynylene) bearing urea functionalities (poly-1) was demonstrated to be a novel fluorescence turn-on probe for various anions. Poly-1 itself exhibits an extremely weak emission that was undetectable by the naked eye, whereas the fluorescence emission of poly-1 was significantly enhanced by the addition of anions. Based on the NMR, dynamic light scattering, and fluorescence decay measurements, the observed fluorescence turn-on response was determined to be realized by the fluorescence recovery based on the disassembly of the poly-1 aggregates, which was originally triggered by the anion recognition event at the urea units of poly-1.

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Cited By

This article is cited by 26 publications.

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  25. Paramjit Kaur, Hardeep Kaur, Kamaljit Singh. A ‘turn-off’ emission based chemosensor for HSO 4 − – formation of a hydrogen-bonded complex. The Analyst 2013, 138 (2) , 425-428. https://doi.org/10.1039/C2AN36100K
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