ACS Publications. Most Trusted. Most Cited. Most Read
CONTENT TYPES

Figure 1Loading Img

System Message

The ACS Publications site will be temporarily unavailable for planned maintenance on Friday, Oct. 15 starting at 6:00 pm ET for up to 4 hours. We apologize for this inconvenience.

Metallopolymers Containing Excess Metal–Ligand Complex for Improved Mechanical Properties

View Author Information
U.S. Army Research Laboratory, Weapons & Materials Research Directorate, Aberdeen Proving Ground, Aberdeen, Maryland 21005-5069, United States
*E-mail [email protected] (A.C.J.).
Cite this: Macromolecules 2014, 47, 13, 4144–4150
Publication Date (Web):June 23, 2014
https://doi.org/10.1021/ma500516p
Copyright © 2014 American Chemical Society
Article Views
1240
Altmetric
-
Citations
LEARN ABOUT THESE METRICS
Read OnlinePDF (9 MB)
Supporting Info (1)»

Abstract

Abstract Image

This work incorporates ML complexes as unbound entities that interact with ML complexes bound to the backbone of the polymer. The π–π interactions and Coulombic forces between bound and unbound ML complexes hold the ML-rich phase together and result in improved mechanical properties over polymers containing only the bound ML complexes. The ML-rich phase formed ordered, cylindrical domains. The storage modulus, surface elastic modulus, and high temperature stability of these metallopolymers increased with increasing concentration of ML complex in the polymer while an optimal concentration and morphology are necessary to improve the strength and creep resistance of the polymer. Ultimately, the successful addition and patterning of unbound ML complexes as a hard phase in a polymer matrix provides an important template for the design of a new type of supramolecular nanocomposite.

Supporting Information

ARTICLE SECTIONS
Jump To

Additional electron microscopy, AFM, and SAXS fits. This material is available free of charge via the Internet at http://pubs.acs.org.

Terms & Conditions

Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

Cited By


This article is cited by 17 publications.

  1. Chase B. Thompson, LaShanda T. J. Korley. 100th Anniversary of Macromolecular Science Viewpoint: Engineering Supramolecular Materials for Responsive Applications—Design and Functionality. ACS Macro Letters 2020, 9 (9) , 1198-1216. https://doi.org/10.1021/acsmacrolett.0c00418
  2. Yuval Vidavsky, Michael R. Buche, Zachary M. Sparrow, Xinyue Zhang, Steven J. Yang, Robert A. DiStasio Jr., Meredith N. Silberstein. Tuning the Mechanical Properties of Metallopolymers via Ligand Interactions: A Combined Experimental and Theoretical Study. Macromolecules 2020, 53 (6) , 2021-2030. https://doi.org/10.1021/acs.macromol.9b02756
  3. Alice M. Savage, Scott D. Walck, Robert H. Lambeth, Frederick L. Beyer. Tuning the Morphology of an Acrylate-Based Metallo-Supramolecular Network: From Vesicles to Cylinders. Macromolecules 2018, 51 (5) , 1636-1643. https://doi.org/10.1021/acs.macromol.7b02536
  4. Anton O. Razgoniaev, Evgeniia V. Butaeva, Alexei V. Iretskii, and Alexis D. Ostrowski . Changing Mechanical Strength in Cr(III)- Metallosupramolecular Polymers with Ligand Groups and Light Irradiation. Inorganic Chemistry 2016, 55 (11) , 5430-5437. https://doi.org/10.1021/acs.inorgchem.6b00422
  5. Tomasz Jungst, Willi Smolan, Kristin Schacht, Thomas Scheibel, and Jürgen Groll . Strategies and Molecular Design Criteria for 3D Printable Hydrogels. Chemical Reviews 2016, 116 (3) , 1496-1539. https://doi.org/10.1021/acs.chemrev.5b00303
  6. Pengfei Zhang, Andraž Rešetič, Marc Behl, Andreas Lendlein. Multifunctionality in Polymer Networks by Dynamic of Coordination Bonds. Macromolecular Chemistry and Physics 2021, 222 (3) , 2000394. https://doi.org/10.1002/macp.202000394
  7. Robert H. Lambeth, Brian F. Morgan, Alice M. Savage, Frederick L. Beyer. Metallo‐supramolecular Crosslinked Polyurethanes. Journal of Polymer Science Part B: Polymer Physics 2019, 57 (24) , 1744-1757. https://doi.org/10.1002/polb.24909
  8. Changlin Cao, Congyu Cai, Yangtao Wang, Qingrong Qian, Qinghua Chen. Impact of the aluminum sulfate 18‐hydrate particle size on the coordination crosslinking behaviors of acrylonitrile–butadiene rubber–aluminum sulfate 18‐hydrate composites. Journal of Applied Polymer Science 2019, 136 (36) , 47717. https://doi.org/10.1002/app.47717
  9. Lanhai Lai, Dong Luo, Ting Liu, Wenjie Zheng, Tianfeng Chen, Dan Li. Self‐Assembly of Copper Polypyridyl Supramolecular Metallopolymers to Achieve Enhanced Anticancer Efficacy. ChemistryOpen 2019, 8 (4) , 434-437. https://doi.org/10.1002/open.201900036
  10. Yanlan Wang, Didier Astruc, Alaa S. Abd-El-Aziz. Metallopolymers for advanced sustainable applications. Chemical Society Reviews 2019, 48 (2) , 558-636. https://doi.org/10.1039/C7CS00656J
  11. Prithwiraj Mandal, Sovan Lal Banerjee, Koushik Bhattacharya, Nikhil K. Singha. A superparamagnetic metallopolymer using tailor-made poly[2-(acetoacetoxy)ethyl methacrylate] bearing pendant β-keto ester functionality. European Polymer Journal 2018, 103 , 31-39. https://doi.org/10.1016/j.eurpolymj.2018.03.024
  12. Sourenjit Naskar, Barun Jana, Pradyut Ghosh. Anion-dependent thermo-responsive supramolecular superstructures of Cu( ii ) macrocycles. Dalton Transactions 2018, 47 (16) , 5734-5742. https://doi.org/10.1039/C8DT00683K
  13. Marek Brzeziński, Anna Kacprzak, Marcelo Calderón, Sebastian Seiffert. Metallo-Polymer Chain Extension Controls the Morphology and Release Kinetics of Microparticles Composed of Terpyridine-Capped Polylactides and their Stereocomplexes. Macromolecular Rapid Communications 2017, 38 (7) , 1600790. https://doi.org/10.1002/marc.201600790
  14. Haixia Li, Wei Wei, Huiming Xiong. An asymmetric A–B–A′ metallo-supramolecular triblock copolymer linked by Ni 2+ –bis-terpyridine complexes at one junction. Soft Matter 2016, 12 (5) , 1411-1418. https://doi.org/10.1039/C5SM02639C
  15. Ying Zhao, Ling He, Song Qin, Guo-Hong Tao. Tunable luminescence of lanthanide (Ln = Sm, Eu, Tb) hydrophilic ionic polymers based on poly(N-methyl-4-vinylpyridinium-co-styrene) cations. Polymer Chemistry 2016, 7 (46) , 7068-7077. https://doi.org/10.1039/C6PY01472K
  16. Yuya Domoto, Eric Busseron, Mounir Maaloum, Emilie Moulin, Nicolas Giuseppone. Control over Nanostructures and Associated Mesomorphic Properties of Doped Self-Assembled Triarylamine Liquid Crystals. Chemistry - A European Journal 2015, 21 (5) , 1938-1948. https://doi.org/10.1002/chem.201405567
  17. Haixia Li, Wei Wei, Huiming Xiong. Metallo-supramolecular complexes mediated thermoplastic elastomeric block copolymer. Polymer 2014, 55 (22) , 5739-5745. https://doi.org/10.1016/j.polymer.2014.09.032

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

STEP 1:
Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

MENDELEY PAIRING EXPIRED
Your Mendeley pairing has expired. Please reconnect

This website uses cookies to improve your user experience. By continuing to use the site, you are accepting our use of cookies. Read the ACS privacy policy.

CONTINUE