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Synthesis and Comparison of the Optical Properties of Platinum(II) Poly-ynes with Fused and Non-Fused Oligothiophenes

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    Synthesis and Comparison of the Optical Properties of Platinum(II) Poly-ynes with Fused and Non-Fused Oligothiophenes
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    Cavendish Laboratory, University of Cambridge, Cambridge CB3 OHE, U.K., Department of Physics, University of Bayreuth, Bayreuth 95440, Germany, Department of Chemistry, College of Science, Sultan Qaboos University, Sultanate of Oman, The STFC Daresbury Laboratory, Daresbury, Warrington WA4 4AD, U.K., and Department of Chemistry, University of Bath, Bath BA2 7AY, U.K.
    * Corresponding authors: E-mails: (A.K.) [email protected]; (M.S.K.) [email protected]; (P.R.R.) [email protected]
    †Cavendish Laboratory, University of Cambridge.
    ‡Department of Physics, University of Bayreuth.
    §Department of Chemistry, College of Science, Sultan Qaboos University.
    ∥The STFC Daresbury Laboratory.
    ⊥Department of Chemistry, University of Bath.
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    Macromolecules

    Cite this: Macromolecules 2009, 42, 4, 1131–1141
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    https://doi.org/10.1021/ma802399a
    Published January 22, 2009
    Copyright © 2009 American Chemical Society
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    Abstract

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    The synthesis and characterization of the thieno[3,2-b]thiophene and dithieno[3,2-b:2′,3′-d]thiophene containing platinum(II) poly-ynes and their molecular precursors is described and the electronic structure is established by absorption, luminescence and photoinduced absorption measurements. A comparison of the electronic structure of the fused and the nonfused oligothiophenes, thieno[3,2-b]thiophene, dithieno[3,2-b:2′,3′-d]thiophene, 2,2′-bithiophene, and 2,2′:5′,2′′-terthiophene incorporated in platinum(II) poly-ynes is reported. We find the singlet S1 and triplet T1 and Tn excited states to be at higher energy in thin films made from the fused systems than from the nonfused systems. For ligands with the same number of rings, we attribute this to the decreased number of double bonds in the fused system and to the presence of an additional sulfur atom in spacers with the same number of double bonds.

    Copyright © 2009 American Chemical Society

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    Macromolecules

    Cite this: Macromolecules 2009, 42, 4, 1131–1141
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ma802399a
    Published January 22, 2009
    Copyright © 2009 American Chemical Society
    Request reuse permissions

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