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Thermogravimetric Analysis of the Oxidation of Multiwalled Carbon Nanotubes:  Evidence for the Role of Defect Sites in Carbon Nanotube Chemistry

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    Thermogravimetric Analysis of the Oxidation of Multiwalled Carbon Nanotubes:  Evidence for the Role of Defect Sites in Carbon Nanotube Chemistry
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    Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506-0055, and Center for Applied Energy Research, University of Kentucky, Lexington, Kentucky 40511-8410
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    Nano Letters

    Cite this: Nano Letters 2002, 2, 6, 615–619
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    https://doi.org/10.1021/nl020297u
    Published May 3, 2002
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    Thermogravimetric analysis (TGA) has demonstrated that multiwalled nanotubes (MWNTs) annealed at 2200 to 2800 °C are more air stable than as-produced MWNTs, diamond, graphite, and annealed diamond. The annealed MWNTs are similar in stability to annealed graphite. Defect sites along the walls and at the ends of the raw MWNTs facilitate the thermal oxidative destruction of the nanotubes. Thermal annealing removes these defects, thereby providing MWNTs with enhanced air stability.

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    †

     Department of Chemistry.

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     Center for Applied Energy Research.

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     Corresponding author:  [email protected]; 859-257-3484; 859-323-1069 (Fax).

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    Cite this: Nano Letters 2002, 2, 6, 615–619
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