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Single Molecular Imaging and Spectroscopy of Conjugated Polyelectrolytes Decorated on Stretched Aligned DNA

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Biomolecular and Organic Electronics, Department of Physics, Chemistry and Biology, Linköping University, SE-581 83 Linköping, Sweden, and Department of Chemical Physics, University of Lund, P.O. Box 124, SE-22100, Sweden
Cite this: Nano Lett. 2005, 5, 10, 1948–1953
Publication Date (Web):September 13, 2005
https://doi.org/10.1021/nl051328z
Copyright © 2005 American Chemical Society

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    Abstract

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    DNA is the prototype template for building nanoelectronic devices by self-assembly. The electronic functions are made possible by coordinating electronic polymer chains to DNA. This paper demonstrates two methods for fabrication of aligned and ordered DNA nanowires complexed with conjugated polyelectrolytes (CPEs). The complex can be formed either in solution prior to stretching or after stretching of the bare DNA on a surface. Molecular combing was used to stretch the complexes on surface energy patterned surfaces, and PMMA for the bare DNA. Single molecular spectroscopy, in fluorescence, and microscopy, in atomic force microscopy, give evidence for coordination of the short CPE chains to the aligned DNA.

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     Corresponding author. E-mail:  [email protected]. Phone:  +46 13 282702. Fax:  +46 13 28 89 69.

     Biomolecular and Organic Electronics.

     Department of Chemical Physics.

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    Experimental details describing the PDMS stamp fabrication, an example of stretched bare λ-DNA on a surface-modified substrate, experimental details for the solution fluorescence measurements, and the single molecular spectroscopy setup. This material is available free of charge via the Internet at http://pubs.acs.org.

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