Efficiency Enhancements in Solid-State Hybrid Solar Cells via Reduced Charge Recombination and Increased Light CaptureClick to copy article linkArticle link copied!
Abstract

We compare a series of molecular sensitizers in dye-sensitized solar cells containing the organic hole transporter 2,2‘,7,7‘-tetrakis(N,N-di-p-methoxypheny-amine)-9,9‘-spirobifluorene (spiro-MeOTAD). Charge recombination is reduced by the presence of “ion-coordinating” moieties on the dye, with the longest electron lifetime and highest solar cell efficiency achieved using a novel sensitizer with diblock alkoxy-alkane pendent groups. By further increasing the optical path length in the active layer, we achieve a power conversion efficiency of over 5% under simulated sun light.
*
Corresponding author. E-mail: [email protected].
†
Institut de Chimie Physique, École Polytechnique Fédérale de Lausanne.
‡
Cavendish Laboratory.
§
Institut für Physikalische Chemie.
‖
Current address: Department of Materials Science, UC Davis, Davis, CA 95616.
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